Citation: Kaiyang Zhang, Yazhou Xu, Yingchun Lin, Yushuai Xiong, Jun Huang, Li Wang, Mengke Peng, Ting Hu, Kai Yuan, Yiwang Chen. Enriching redox active sites by interconnected nanowalls-like nickel cobalt phospho-sulfide nanosheets for high performance supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(11): 3553-3557. doi: 10.1016/j.cclet.2021.02.034 shu

Enriching redox active sites by interconnected nanowalls-like nickel cobalt phospho-sulfide nanosheets for high performance supercapacitors

Kaiyang Zhang ^{a, 1} ,
Yazhou Xu ^{a, 1} ,
Yingchun Lin ^{a, 1} ,
Yushuai Xiong ^a ,
Jun Huang ^a ,
Li Wang ^a ,
Mengke Peng ^a ,
Ting Hu ^b ,
Kai Yuan ^{a, *,} ,
Yiwang Chen ^{a, c, **,}

a.
Institute of Polymers and Energy Chemistry (IPEC), College of Chemistry, Nanchang University, Nanchang 330031, China
b.
School of Materials Science and Engineering, Nanchang University, Nanchang 330031, China
c.
Institute of Advanced Scientific Research (iASR), Jiangxi Normal University, Nanchang 330022, China

kai.yuan@ncu.edu.cn

ywchen@ncu.edu.cn

Received Date: 27 January 2021
Revised Date: 10 February 2021
Accepted Date: 17 February 2021
Available Online: 19 February 2021

Figures(4)

Although transition metal phospho-sulfides deliver outstanding electrochemical performance, complex preparation methods hindered their further development. Herein, we report a facile one-step electrodeposition approach to deposit interconnected nanowalls-like nickel cobalt phospho-sulfide (Ni-Co-P-S) nanosheets onto the surface of carbon cloth. The thin Ni-Co-P-S nanosheets with multi-components and synergetic effects delivered rich active sites, further enhancing reversible capacitance. Therefore, the as-prepared Ni-Co-P-S electrode materials exhibit excellent electrochemical performance in a three-electrode system, showcasing a high specific capacitance of 2744 F/g at 4 A/g. The full supercapacitors based on Ni-Co-P-S as positive electrode and active carbon as negative electrode showcase a high specific capacitance of 110.9 F/g at 1 A/g, impressive energy density of 39.4 Wh/kg at a power density of 797.5 W/kg in terms of excellent cycling stability (91.87% retention after 10, 000 cycles). This simple electrode position strategy for synthesizing Ni-Co-P-S can be extended to prepare electrode materials for various sustainable electrochemical energy storage/conversion technologies.
- Nickel cobalt phospho-sulfide,
- Electrodeposition,
- Specific capacitance,
- Asymmetric supercapacitors,
- Energy density
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