Citation: Ran Li, Can-Can Zhang, Dan Wang, Yan-Fang Hu, Yong-Long Li, Wei Xie. Reaction pathway change on plasmonic Au nanoparticles studied by surface-enhanced Raman spectroscopy[J]. Chinese Chemical Letters, ;2021, 32(9): 2846-2850. doi: 10.1016/j.cclet.2021.02.014 shu

Reaction pathway change on plasmonic Au nanoparticles studied by surface-enhanced Raman spectroscopy

Key Lab of Advanced Energy Materials Chemistry (Ministry of Education), Tianjin Key Lab Mol Recognit & Biosensing, Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin 300071, China

wei.xie@nankai.edu.cn

Received Date: 1 December 2020
Revised Date: 30 December 2020
Accepted Date: 6 February 2021
Available Online: 10 February 2021

Figures(5)

Gold nanoparticles (Au NPs) are nanoscale sources of light and electrons, which are highly relevant for their extensive applications in the field of photocatalysis. Although a number of research works have been carried out on chemical reactions accelerated by the energetic hot electrons/holes, the possibility of reaction pathway change on the plasmonic Au surfaces has not been reported so far. In this proof-of-concept study, we find that Au NPs change the reaction pathway in photooxidation of alkyne under visible light irradiation. This reaction produces benzil (-CO-CO-) without the presence of Au NPs. In contrast, as indicated by surface-enhanced Raman spectroscopic (SERS) results, the C-C triple bonds (-C≡C-) adsorbed on Au NPs are converted into carboxyl (-COOH) and acyl chloride (-COCl) groups. The plasmonic Au NPs not only provide energetic charge carriers but also activate the reactant molecules as conventional heterogeneous catalysts. This study discloses the second role of plasmonic NPs in photocatalysis and bridges the gap between plasmon-driven and conventional heterogeneous catalysis.
- Surface-enhanced Raman spectroscopy,
- Surface plasmon,
- Au nanoparticles,
- Photocatalysis,
- Reaction pathway
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