Citation: Pengxiang Zhang, Jiajia Li, Juanjuan Feng, Yu Wang, Aili Xu, Tingting Chen, Lingwen Zhao, Feng Dang, Xihua Zhang, Hongchao Wang. MOF-template derived hollow CeO₂/Co₃O₄ polyhedrons with efficient cathode catalytic capability in Li-O₂ batteries[J]. Chinese Chemical Letters, ;2021, 32(8): 2438-2442. doi: 10.1016/j.cclet.2021.02.010 shu

MOF-template derived hollow CeO₂/Co₃O₄ polyhedrons with efficient cathode catalytic capability in Li-O₂ batteries

Pengxiang Zhang ^{a, b, 1} ,
Jiajia Li ^{b, 1} ,
Juanjuan Feng ^a ,
Yu Wang ^b ,
Aili Xu ^b ,
Tingting Chen ^a ,
Lingwen Zhao ^a ,
Feng Dang ^b ,
Xihua Zhang ^{b, *,} ,
Hongchao Wang ^{a, *,}

a.
School of Physics, State Key Laboratory of Crystal Materials, Shandong University, Ji'nan 250100, China
b.
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Ji'nan 250061, China

zhangxh@sdu.edu.cn

wanghc@sdu.edu.cn

Received Date: 30 December 2020
Revised Date: 2 February 2021
Accepted Date: 2 February 2021
Available Online: 9 February 2021

Figures(5)

Li-O₂ batteries (LOBs) have been perceived as the most potential clean energy system for fast-growing electric vehicles by reason of their environmentally friendlier, high energy density and high reversibility. However, there are still some issues limiting the practical application of LOBs, such as the large gap between the actual capacity level and the theoretical capacity, low rate performance as well as short cycle life. Herein, hollow CeO₂/Co₃O₄ polyhedrons have been synthesized by MOF template with a simple method. And it is was further served as a cathode catalyst in Li-O₂ batteries. By means of the synergistic effect of two different transition metal oxides, nano-sized hollow porous CeO₂/Co₃O₄ cathode obtained better capacity and cycle performance. As a result, excellent cyclability of exceeding 140 and 90 cycles are achieved at a fixed capacity of 600 and 1000 mAh/g, respectively. The successful application of this catalyst in LOBs offers a novel route in the aspect of the synthesis of other hollow porous composite oxides as catalysts for cathodes in LOBs systems by the MOF template method.
- Li-O₂ batteries,
- Co₃O₄,
- CeO₂,
- Hollow nanostructure,
- Cathode catalyst
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

MOF-template derived hollow CeO2/Co3O4 polyhedrons with efficient cathode catalytic capability in Li-O2 batteries

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通讯作者: 陈斌, bchen63@163.com

MOF-template derived hollow CeO₂/Co₃O₄ polyhedrons with efficient cathode catalytic capability in Li-O₂ batteries