Citation: Tianyi Hou, Anran Fan, Xiaohong Sun, Xi Zhang, Zhongkai Xu, Shu Cai, Chunming Zheng. Improving cycling stability of Bi-encapsulated carbon fibers for lithium/sodium-ion batteries by Fe₂O₃ pinning[J]. Chinese Chemical Letters, ;2021, 32(8): 2459-2462. doi: 10.1016/j.cclet.2021.01.049 shu

Improving cycling stability of Bi-encapsulated carbon fibers for lithium/sodium-ion batteries by Fe₂O₃ pinning

Tianyi Hou ^a ,
Anran Fan ^a ,
Xiaohong Sun ^{a, *} ,
Xi Zhang ^a ,
Zhongkai Xu ^a ,
Shu Cai ^a ,
Chunming Zheng ^{b, *}

a.
School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin University, Tianjin 300072, China
b.
School of Chemistry and Chemical Engineering, State Key Laboratory of Hollow-Fiber Membrane Materials and Membrane Processes, Tiangong University, Tianjin 300387, China

sunxh@tju.edu.cn

zhengchunming@tiangong.edu.cn

Received Date: 26 November 2020
Revised Date: 12 January 2021
Accepted Date: 28 January 2021
Available Online: 2 February 2021

Figures(4)

Bi draws increasing attention as anode materials for lithium-ion batteries and sodium-ion batteries due to its unique layered crystal structure, which is in favor of achieving fast ionic diffusion kinetics during cycling. However, the dramatic volume expansion upon lithiation/sodiation and an insufficient theoretical capacity of Bi greatly hinder its practical application. Herein, we report the Fe₂O₃ nanoparticle-pinning Bi-encapsulated carbon fiber composites through the electrospinning technique. The introduction of Fe₂O₃ nanoparticles can prevent the growth and aggregation of Bi nanoparticles during synthetic and cycling processes, respectively. Fe₂O₃ with high specific capacity also contributes to the specific capacity of the composites. Consequently, the as-prepared Bi-Fe₂O₃/carbon fiber composite exhibits outstanding long-term stability, which delivers reversible capacities 504 and 175 mAh/g after 1000 cycles at 1 A/g for lithium-ion and sodium-ion batteries, respectively.
- Bismuth,
- Iron oxide,
- Pinning effect,
- Lithium-ion batteries,
- Sodium-ion batteries
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沈阳化工大学材料科学与工程学院沈阳 110142

Improving cycling stability of Bi-encapsulated carbon fibers for lithium/sodium-ion batteries by Fe2O3 pinning

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通讯作者: 陈斌, bchen63@163.com

Improving cycling stability of Bi-encapsulated carbon fibers for lithium/sodium-ion batteries by Fe₂O₃ pinning