Citation: Xixi Zhang, Guangmeng Qu, Zonghua Wang, Guotao Xiang, Shuhua Hao, Xiaoke Wang, Xijin Xu, Wenxuan Ma, Gang Zhao. Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)₂ for high performance supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(8): 2453-2458. doi: 10.1016/j.cclet.2021.01.042 shu

Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)₂ for high performance supercapacitors

School of Physics and Technology, University of Jinan, Ji'nan 250022, China

sps_xuxj@ujn.edu.cn

sps_zhaog@ujn.edu.cn

Received Date: 19 December 2020
Revised Date: 17 January 2021
Accepted Date: 19 January 2021
Available Online: 27 January 2021

Figures(4)

In power storage technology, ion exchange is widely used to modify the electronic structures of electrode materials to stimulate their electrochemical properties. Here, we proposed a multistep ion exchange (cation exchange and anion exchange) strategy to synthesize amorphous Ni-Co-S and β-Co(OH)₂ hybrid nanomaterials with a hollow polyhedron structures. The synergistic effects of different components and the remarkable superiorities of hollow structure endow Ni-Co-S/Co(OH)₂ electrode with outstanding electrochemical performance, including ultra-high specific capacity (1440.0 C/g at 1 A/g), superior capacitance retention rate (79.1% retention at 20 A/g) and long operating lifespan (81.4% retention after 5000 cycles). Moreover, the corresponding hybrid supercapacitor enjoys a high energy density of 58.4 Wh/kg at the power density of 0.8 kW/kg, and a decent cyclability that the capacitances are maintained at 80.8% compared with the initial capacitance. This research presents a high-performance electrode material and provides a promising route for the construction of electrode materials for supercapacitors with both structural and component advantages.
- Ion exchange,
- Amorphous,
- β-Co(OH)₂,
- Hollow polyhedron,
- Supercapacitor
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沈阳化工大学材料科学与工程学院沈阳 110142

Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)2 for high performance supercapacitors

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通讯作者: 陈斌, bchen63@163.com

Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)₂ for high performance supercapacitors