Citation: Yanshu Zhang, Gongke Li, Yufei Hu. Fabrication of bimetallic nanoparticles modified hollow nanoporous carbons derived from covalent organic framework for efficient degradation of 2, 4-dichlorophenol[J]. Chinese Chemical Letters, ;2021, 32(8): 2529-2533. doi: 10.1016/j.cclet.2021.01.031 shu

Fabrication of bimetallic nanoparticles modified hollow nanoporous carbons derived from covalent organic framework for efficient degradation of 2, 4-dichlorophenol

School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China

cesgkl@mail.sysu.edu.cn

huyufei@mail.sysu.edu.cn

Received Date: 11 September 2020
Revised Date: 6 December 2020
Accepted Date: 19 January 2021
Available Online: 27 January 2021

Figures(4)

Bimetallic nanoparticles modified hollow-structured nanoporous carbons (NPCs) have been fabricated via a convenient one-step carbonizing strategy derived from covalent organic framework. The Pd/Fe/NPCs, Pt/Fe/NPCs and Rh/Fe/NPCs were obtained and can be used as Fenton-like catalysts with good stability and reusability. The catalytic activity was evaluated by the degradation of 2, 4-dichlorophenl (2, 4-DCP). These fabricated bimetallic catalysts exhibited much higher catalytic activity than Fe/NPCs at room temperature. The enhancement of catalytic ability was benefited from synergetic catalytic effect of bimetallic nanoparticles and accelerated mass transfer of hollow structure. Additionally, the enhanced catalytic mechanism of bimetallic catalysts was studied in detail and the reasonable reaction pathway was proposed. Besides, the bimetallic catalysts were successfully used for degradation of 2, 4-DCP in actual industrial wastewater and the removal efficiency could reach 74.3% within 120 min, which demonstrated the promising potential application of bimetallic catalysts in the removal of pollutants in environment.
- Covalent organic framework,
- Hollow structure,
- N-doped carbon,
- Bimetallic nanoparticles,
- 2, 4-Dichlorophenol,
- Degradation
1. [1]
  J.J. Wei, X.H. Xu, Y. Liu, D.H. Wang, Water Res. 40 (2006) 348-354 doi: 10.1016/j.watres.2005.10.017
2. [2]
  H. Zhang, Q.Q. Ji, L.D. Lai, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019)1129-1132 doi: 10.1016/j.cclet.2019.01.025
3. [3]
  J. Xu, L.S. Tan, S.A. Baig, et al., Chem. Eng. J. 231 (2013) 26-35 doi: 10.1016/j.cej.2013.07.018
4. [4]
  Y.Y. Zhou, L. Tang, G.D. Yang, et al., Catal. Sci. Technol. 6 (2016) 1930-1939 doi: 10.1039/C5CY01514F
5. [5]
  X.J. Chen, Y.Z. Dai, X.Y. Wang, et al., J. Hazard. Mater. 292 (2015) 9-18 doi: 10.14355/ff.2015.01.002
6. [6]
  J. Xu, X.S. Lv, J.D. Li, et al., J. Hazard. Mater. 225-226 (2012) 36-45 doi: 10.1016/j.jhazmat.2012.04.061
7. [7]
  R. Yang, Y. Lin, B.Y. Liu, et al., Anal. Chem. 92 (2020) 3528-3534 doi: 10.1021/acs.analchem.9b05475
8. [8]
  R.M. Frizzarin, C.P. Cabello, M.M. Bauza, et al., Anal. Chem. 88 (2016) 6990-6995 doi: 10.1021/acs.analchem.6b02065
9. [9]
  X.J. Zhang, G. Zhu, M. Wang, et al., Carbon 116 (2017) 686-694 doi: 10.1016/j.carbon.2017.02.057
10. [10]
  X.J. Zhao, P. Pachfule, S. Li, et al., Chem. Mater. 31 (2019) 3274-3280 doi: 10.1021/acs.chemmater.9b00204
11. [11]
  X.W. Hu, Y. Long, M.Y. Fan, et al., Appl. Catal. B-Environ. 244 (2019) 25–35 doi: 10.1016/j.apcatb.2018.11.028
12. [12]
  Z.L. Du, Q.Q. Dang, X.M. Zhang, Ind. Eng. Chem. Res. 56 (2017) 4275-4280 doi: 10.1021/acs.iecr.6b05039
13. [13]
  X.F. Han, J. Chen, Z, Li, H.D. Qiu, Anal. Chim. Acta 1078 (2019) 78-89 doi: 10.1016/j.aca.2019.06.022
14. [14]
  X.X. Yang, Y.J. He, L.Y. Li, et al., Chem. Eur. J. 26 (2020) 1864-1870 doi: 10.1002/chem.201904731
15. [15]
  M.Y. Fan, Y. Long, Y.Y. Zhu, X.W. Hu, Z.P. Dong, Appl. Cata. A: Gen. 568 (2018) 130-138 doi: 10.1016/j.apcata.2018.09.028
16. [16]
  L.J. Song, H.J. Zhang, T.P. Cai, et al., Chin. Chem. Lett. 30 (2019) 863-866 doi: 10.1016/j.cclet.2018.10.040
17. [17]
  L.Y. Chen, L. Zhang, Z.J. Chen, et al., Chem. Sci. 7 (2016) 6015-6020 doi: 10.1039/C6SC01659F
18. [18]
  S.Y. Ding, J. Gao, Q. Wang, et al., J. Am. Chem. Soc. 133 (2011) 19816-19822 doi: 10.1021/ja206846p
19. [19]
  X.B. Wang, Y.L. Qin, L.H. Zhu, H.Q. Tang, Environ. Sci. Technol. 49 (2015) 6855-6864 doi: 10.1021/acs.est.5b01059
20. [20]
  Y.M. Zhang, F. Wang, P. Ou, et al., J. Hazard. Mater. 360 (2018) 223-232 doi: 10.4236/gep.2018.69017
21. [21]
  Z.Y. Lu, Z.X. Shi, S.M. Huang, et al., Talanta 214 (2020) 120864 doi: 10.1016/j.talanta.2020.120864
22. [22]
  X.Y. Yang, X.W. Cheng, A.A. Elzatahry, et al., Chin. Chem. Lett. 30 (2019) 324-330 doi: 10.1016/j.cclet.2018.06.026
23. [23]
  L.J. Xu, J.L. Wang, Appl. Catal. B: Environ. 123-124 (2012) 117-126 doi: 10.1016/j.apcatb.2012.04.028
24. [24]
  R.C. Li, Y. Gao, X.Y. Jin, et al., J. Colloid Interface Sci. 438 (2015) 87-93 doi: 10.1016/j.jcis.2014.09.082
25. [25]
  K. Chen, G.H. Wang, W.B. Li, et al., Chin. Chem. Lett. 25 (2014) 1455-1460 doi: 10.1016/j.cclet.2014.06.014
26. [26]
  B. Shen, C.C. Dong, J.H. Ji, M.Y. Xing, J.L. Zhang, Chin. Chem. Lett. 30 (2019) 2205-2210 doi: 10.1016/j.cclet.2019.09.052
27. [27]
  J. Xu, J. Tang, S.A. Baig, X.S. Lv, X.H. Xu, J. Hazard. Mater. 244 (2013) 628-636 doi: 10.1016/j.jhazmat.2012.10.051
28. [28]
  D.M. Zhao, Y.Y. Zheng, M. Li, et al., Ultrason. Sonochem. 21 (2014) 1714-1721 doi: 10.1016/j.ultsonch.2014.03.002
29. [29]
  L. Liu, W.K. Meng, L, Li, et al., Chem. Eng. J. 369 (2019) 920-927 doi: 10.1016/j.cej.2019.03.148
30. [30]
  L. Tang, Y.N. Liu, J.J. Wang, et al.,Appl. Catal. B: Environ. 231 (2018) 1-10 doi: 10.1117/1.oe.58.4.041606
31. [31]
  S. Pothaya, J.R. Regalbuto, J.R. Monnier, K. Punyawudho, Int. J. Hydrogen Energy. 44 (2019) 26361-26372 doi: 10.1016/j.ijhydene.2019.08.110
32. [32]
  J.Y. Zhu, S. Chen, Q. Xue, et al., Appl. Catal. B: Environ. 264 (2020) 118520 doi: 10.1016/j.apcatb.2019.118520
33. [33]
  Y.H. Zhong, Z.F. Chen, S.C. Yan, et al., Environ. Sci: Nano 6 (2019) 2986-2999 doi: 10.1039/c9en00673g
34. [34]
  P. Zhang, R. Li, Y.M. Huang, Q.W. Chen,ACS Appl. Mater. Interfaces. 6 (2014) 2671-2678 doi: 10.1021/am405167h
35. [35]
  J. Liu, J.Q. Li, J.F. Rong, et al., Appl. Surf. Sci. 464 (2019) 146-152 doi: 10.1016/j.apsusc.2018.08.260
36. [36]
  A. Serrano-Maldonado, S.S. Rozenel, J.L. Jimenez-Santiago, I. Guerrero-Ríos, E. Martin, Catal. Sci. Technol. 8 (2018) 4373-4382 doi: 10.1039/c8cy00227d
37. [37]
  C. Zhang, M.H. Zhou, G.B. Ren, et al., Water Res. 70 (2015) 414-424 doi: 10.1016/j.watres.2014.12.022
38. [38]
  J. Xu, Z. Cao, X. Liu, et al., J. Hazard. Mater. 317 (2016) 656-666 doi: 10.1016/j.jhazmat.2016.04.063
39. [39]
  L.P. Fang, C.H. Xu, W.B. Zhang, L.Z. Huang, Appl. Surf. Sci. 435 (2018) 55-64 doi: 10.1016/j.apsusc.2017.11.084
40. [40]
  L. Wan, H.Y. Song, J.H. Ma, et al., ACS Appl. Mater. Interfaces. 10 (2018) 13028-13039 doi: 10.1021/acsami.8b02063
41. [41]
  C.Q. Tan, Y.J. Dong, D. F. Fu, et al., Chem. Eng. J. 334 (2018) 1006-1015 doi: 10.1016/j.cej.2017.10.020
42. [42]
  M.N. Zhang, J. Jia, K. Huang, X.D. Hou, C.B. Zheng, Chin. Chem. Lett. 29 (2017) 456-460
43. [43]
  R. Zhou, N.F. Shen, J. Zhao, Y. Su, H.J. Ren, J. Mater. Chem. A 6 (2018) 1275-1283 doi: 10.1039/C7TA09685B
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