Citation: Yang Xia, Wei Jin, Yanyuan Qi, Hang Li, Zelang Jian, Wen Chen. Low-coordination water Prussian white as cathode for high-performance potassium-ion batteries[J]. Chinese Chemical Letters, ;2021, 32(8): 2433-2437. doi: 10.1016/j.cclet.2021.01.025 shu

Low-coordination water Prussian white as cathode for high-performance potassium-ion batteries

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China

zelangjian@whut.edu.cn

Received Date: 2 December 2020
Revised Date: 11 January 2021
Accepted Date: 14 January 2021
Available Online: 27 January 2021

Figures(4)

Prussian whites (PWs) with a three-dimensional framework can accommodate the insertion and extraction of ions with large radius, which have been widely used in potassium ion batteries. However, PWs show the poor cycling performance and inferior rate ability because of high coordinated water. In this work, PWs with different water content were synthesized via a coprecipitation method by controlling the reaction temperature. The sample with low-coordination water prohibits the best electrochemical performance. It shows a high capacity of 120.5 mAh/g at 100 mA/g for potassium-ion batteries (KIBs). It also exhibits a good rate performance, displaying a capacity of 73.2 mAh/g at 500 mA/g.
- Prussian white,
- Potassium ion batteries,
- Low-coordinated water,
- Cathode,
- Reaction temperature
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