Citation: Wenxin Hou, Shuhui Wang, Xiuru Bi, Xu Meng, Peiqing Zhao, Xiang Liu. Compared catalytic properties of OMS-2-based nanocomposites for the degradation of organic pollutants[J]. Chinese Chemical Letters, ;2021, 32(8): 2513-2518. doi: 10.1016/j.cclet.2021.01.023 shu

Compared catalytic properties of OMS-2-based nanocomposites for the degradation of organic pollutants

Wenxin Hou ^{a, 1} ,
Shuhui Wang ^{a, 1} ,
Xiuru Bi ^{b, 1} ,
Xu Meng ^{b, **,} ,
Peiqing Zhao ^b ,
Xiang Liu ^{a, c, *,}

a.
College of Materials and Chemical Engineering, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, Analysis and Testing Center, China Three Gorges University, Yichang 443002, China
b.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, China
c.
Engineering Research Center of Eco-Environment in Three Gorges Reservoir Region, Ministry of Education, China Three Gorges University, Yichang 443002, China

^**

xumeng@licp.cas.cn

xiangliu@ctgu.edu.cn

Received Date: 25 October 2020
Revised Date: 8 December 2020
Accepted Date: 12 January 2021
Available Online: 27 January 2021

Figures(4)

In this study, Mn catalysts have been designed based on manganese oxide octahedral molecular sieve (OMS-2) supports to optimize the catalytic activity in the degradation of organic pollutants. Herein, two different synthetic strategies: Pre-incorporation vs. wet-impregnation have been employed to synthesize [PW]-OMS-2 and [PW]/OMS-2. For [PW]-OMS-2, energy dispersive X-ray spectroscopy (EDX) confirmed that dispersed granular phosphotungstic acid attached and located at the surface of OMS-2, meanwhile some W atoms have been doped into frameworks of OMS-2. However, for [PW]/OMS-2, the W atoms cannot enter the OMS-2 frameworks. A correlation has been established between the different synthetic strategies and catalytic activities. The [PW]-OMS-2 is the most highly effective and stable over than [PW]/OMS-2 and OMS-2 itself for the organic pollutants removal. This may be caused not only by the synergetic effect of [PW] and OMS-2, but also by doping W into frameworks of OMS-2. Therefore, this work provides a new environmentally-friendly and heterogeneous PMS activator and it may be put into practice to degrade organic pollutants.
- OMS-2,
- Phosphotungstic acid,
- Organic pollutants,
- Degradation,
- Tungsten
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