Citation: Xi Fan, Lvbing Yuan, Jian Zhang, Lei Zhang. Phenol-triggered supramolecular transformation of titanium–oxo cluster based coordination capsules[J]. Chinese Chemical Letters, ;2021, 32(8): 2415-2418. doi: 10.1016/j.cclet.2021.01.010 shu

Phenol-triggered supramolecular transformation of titanium–oxo cluster based coordination capsules

Xi Fan ^{a, b} ,
Lvbing Yuan ^a ,
Jian Zhang ^a ,
Lei Zhang ^{a, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

LZhang@fjirsm.ac.cn

Received Date: 7 December 2020
Revised Date: 2 January 2021
Accepted Date: 6 January 2021
Available Online: 9 January 2021

Figures(4)

Supramolecular transformations of coordination cage or capsule have received much attention recently, which help elucidate this natural self-assembly behavior in biological systems. The current study describes the first supramolecular transformation of titanium–organic coordination capsule triggered by phenol (and H₃PO₃). The structural alterations are accompanied by the reconstruction of 5-coordinated Ti centers to 6-coordinated ones. Meanwhile, different amounts of encapsulated phenol guest molecules can be identified, dependent on the sizes of the obtained cavities. In addition, they display much better visible light absorption and air stability than the isopropanol stabilized ones.
- Titanium-oxo clusters,
- Phenol,
- Supramolecular transformation,
- Post-synthesis modulation,
- Coordination capsules
1. [1]
  M. Fujita, M. Tominaga, A. Hori, B. Therrien, Acc. Chem. Res. 38 (2005) 369-378 doi: 10.1021/ar040153h
2. [2]
  T. R. Cook, P. J. Stang, Chem. Rev. 115 (2015) 7001-7045 doi: 10.1021/cr5005666
3. [3]
  D. A. Roberts, B. S. Pilgrim and J. R. Nitschke, Chem. Soc. Rev. 47 (2018) 626-644 doi: 10.3390/w10050626
4. [4]
  K. Byrne, M. Zubair, N. Zhu, et al., Nat. Commun. 8 (2017) 15268 doi: 10.1038/ncomms15268
5. [5]
  J. Jiao, C. Tan, Z. Li, et al., J. Am. Chem. Soc. 140 (2018) 2251-2259 doi: 10.1021/jacs.7b11679
6. [6]
  T. S. Koblenz, J. Wassenaar, J. N. Reek, Chem. Soc. Rev. 37 (2008) 247-262 doi: 10.1039/B614961H
7. [7]
  M. Liu, W. Liao, C. Hu, S. Du, H. Zhang, Angew. Chem. Int. Ed. 51 (2012) 1585-1588 doi: 10.1002/anie.201106732
8. [8]
  Y. T. Zhang, X. L. Wang, S. B. Li, et al., Chem. Commun. 52 (2016) 9632-9635 doi: 10.1039/C6CC04583A
9. [9]
  W. H. Fang, L. Zhang, J. Zhang, G. Y. Yang, Chem. Commun. 52 (2016) 1455-1457 doi: 10.1039/C5CC08702C
10. [10]
  J. M. Breen, W. Schmitt, Angew. Chem. Int. Ed. 47 (2008) 6904-6908 doi: 10.1002/anie.200801770
11. [11]
  S. T. Zheng, J. Zhang, G. Y. Yang, J. Am. Chem. Soc. 132, (2010) 15102–15103 doi: 10.1021/ja105986b
12. [12]
  A. J. McConnell, C. S. Wood, P. P. Neelakandan, J. R. Nitschke, Chem. Rev. 115 (2015) 7729-7793 doi: 10.1021/cr500632f
13. [13]
  W. Wang, Y. X. Wang, H. B. Yang, Chem. Soc. Rev. 45 (2016) 2656-2693 doi: 10.1039/C5CS00301F
14. [14]
  Y. Lu, H.N. Zhang, G.X. Jin, Acc. Chem. Res. 51 (2018) 2148-2158 doi: 10.1021/acs.accounts.8b00220
15. [15]
  I. A. Riddell, M. M. J. Smulders, J. K. Clegg, et al., Nat. Chem. 4 (2012) 860-860 doi: 10.1038/nchem.1456
16. [16]
  J. Park, L. B. Sun, Y. P. Chen, Z. Perry, H. C. Zhou, Angew. Chem. Int. Ed. 53 (2014) 5842-5846 doi: 10.1002/anie.201310211
17. [17]
  T. Murase, S. Sato, M. Fujita, Angew. Chem. Int. Ed. 46 (2007) 5133-5136 doi: 10.1002/anie.200700793
18. [18]
  K. Su, M. Wu, D. Yuan, M. Hong, Nat. Commun. 9 (2018) 4941 doi: 10.1038/s41467-018-07427-z
19. [19]
  P. Coppens, Y. Chen, E. Trzop, Chem. Rev. 114 (2014) 9645-9661 doi: 10.1021/cr400724e
20. [20]
  W. H. Fang, L. Zhang, J. Zhang, Chem. Soc. Rev. 47 (2018) 404-421 doi: 10.1039/C7CS00511C
21. [21]
  L. Rozes and C. Sanchez, Chem. Soc. Rev. 40 (2011) 1006-1030 doi: 10.1039/c0cs00137f
22. [22]
  P. D. Matthews, T. C. King and D. S. Wright, Chem. Commun. 50 (2014) 12815-12823 doi: 10.1039/C4CC04421E
23. [23]
  X. Fan, J. Wang, K. Wu, L. Zhang, J. Zhang, Angew. Chem. Int. Ed. 58 (2019) 1320-1323 doi: 10.1002/anie.201809961
24. [24]
  S. Yuan, J. S. Qin, C. T. Lollar, H. C. Zhou, ACS Cent. Sci. 4 (2018) 440-450 doi: 10.1021/acscentsci.8b00073
25. [25]
  M. Dan-Hardi, C. Serre, T. Frot, et al., J. Am. Chem. Soc. 131 (2009) 10857-10859 doi: 10.1021/ja903726m
26. [26]
  N. M. Padial, J. Castells-Gil, N. Almora-Barrios, et al., J. Am. Chem. Soc. 141 (2019) 13124-13133 doi: 10.1021/jacs.9b04915
27. [27]
  X. Fan, N. Narayanam, M. Gao, L. Zhang, J. Zhang, Dalton Trans. 47 (2018) 663–665
28. [28]
  Y. Huang, G.D. Zou, H.M. Li, Y. Cui, Y. Fan, New J. Chem. 42 (2018) 14079-14082 doi: 10.1039/C8NJ02992J
29. [29]
  C. Breckner, R. E. Powers, K. N. Raymond, Angew. Chem. Int. Ed. 37 (1998) 1837 –1839 doi: 10.1002/(SICI)1521-3773(19980803)37:13/14<1837::AID-ANIE1837>3.0.CO;2-A
30. [30]
  A. V. Davis, K. N. Raymond, J. Am. Chem. Soc. 127 (2005) 7912– 7919 doi: 10.1021/ja051037s
31. [31]
  Y. P. He, L. B. Yuan, G. H. Chen, et al., J. Am. Chem. Soc. 139 (2017) 16845– 16851 doi: 10.1021/jacs.7b09463
32. [32]
  B. C. Zhu, W. H. Fang, J. Wang, et al., Chem. Eur. J. 24 (2018) 14358 – 14362 doi: 10.1002/chem.201802930
33. [33]
  Y. Keum, S. Park, Y. P. Chen, J. Park, Angew. Chem. Int. Ed. 57 (2018) 14852-14856 doi: 10.1002/anie.201809762
34. [34]
  P. Ji, Y. Song, T. Drake, et al., J. Am. Chem. Soc. 140 (2018) 433-440 doi: 10.1021/jacs.7b11241
35. [35]
  X. Fan, H. Fu, M. Y. Gao, L. Zhang, J. Zhang, Inorg. Chem. 58 (2019) 13353-13359 doi: 10.1021/acs.inorgchem.9b02238
36. [36]
  M. Y. Gao, X. Fan, L. Zhang, J. Zhang, Inorg. Chem. 57 (2018) 5642–5647 doi: 10.1021/acs.inorgchem.8b00586
37. [37]
  J. B. Benedict and P. Coppens, J. Am. Chem. Soc. 132 (2010) 2938−2944 doi: 10.1021/ja909600w
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