Citation: Dongxu Yang, Jialiang Liang, Liang Luo, Ruoyu Deng, Guo Li, Qiang He, Yi Chen. Facile defect engineering in ZnIn₂S₄ coupled with carbon dots for rapid diclofenac degradation[J]. Chinese Chemical Letters, ;2021, 32(8): 2534-2538. doi: 10.1016/j.cclet.2020.12.049 shu

Facile defect engineering in ZnIn₂S₄ coupled with carbon dots for rapid diclofenac degradation

Dongxu Yang ^{a, b} ,
Jialiang Liang ^{a, b} ,
Liang Luo ^{a, b} ,
Ruoyu Deng ^{a, b} ,
Guo Li ^{a, b} ,
Qiang He ^{a, b} ,
Yi Chen ^{a, b, *,}

a.
Key Laboratory of the Three Gorges Reservoir Region's Eco-Environment, Ministry of Education, Chongqing University, Chongqing 400045, China
b.
College of Environment and Ecology, Chongqing University, Chongqing 400045, China

chenyi8574@cqu.edu.cn

Received Date: 31 August 2020
Revised Date: 2 December 2020
Accepted Date: 26 December 2020
Available Online: 31 December 2020

Figures(4)

Semiconductor-mediated photocatalysis is a promising photochemical process for harvesting inexhaustible solar energy to address the energy crisis and environmental issues. However, the low solar-light response and poor carrier migration are severe drawbacks that limit its practical application. Herein, we propose a convenient pathway for improving electron-hole separation and solar energy utilisation by engineering defective ZnIn₂S₄ with doping of carbon dots. The optimum ZnIn₂S₄/CD200 nanosheet exhibited 100% diclofenac (DCF) degradation within 12 min under visible-light. The estimated photocatalytic efficiency under natural sunlight was 98.2%. Scavenging experiments and electron spin resonance (ESR) analysis indicated that the superoxide radical (O₂^∙⁻), photoelectron (e⁻), hole (h⁺) and hydroxyl radical (^∙OH) were the predominant contributions in the ZnIn₂S₄/CD200/DCF/visible light system. Furthermore, ZnIn₂S₄/CD200 exhibited excellent reusability and stability after 4 times recycling. The photodegradation routes mainly involved hydroxylation, decarboxylation, CN bond cleavage, dechlorination, ring closure, and ring-opening. The ecological risk assessment and total organic carbon (TOC) tests exhibited desirable toxicity reduction and mineralization results. These observations not only offer a facile strategy for the construction of defective ZnIn₂S₄, but also pioneer the direct utilisation of natural light for highly efficient environmental remediation.
- Photocatalysis,
- Diclofenac degradation,
- Defect engineering,
- ZnIn₂S₄nanosheet,
- Carbon dots
1. [1]
  M. Patel, R. Kumar, K. Kishor, et al., Chem. Rev. 119 (2019) 3510-3673 doi: 10.1021/acs.chemrev.8b00299
2. [2]
  M. Cai, R. Li, Z. Xie, et al., Appl. Catal. B 259 (2019) 118033 doi: 10.1016/j.apcatb.2019.118033
3. [3]
  W. Liu, Y. Li, F. Liu, et al., Water Res. 151 (2019) 8-19 doi: 10.15302/j-laf-1-010002
4. [4]
  P. Chen, Q. Zhang, Y. Su, et al., Chem. Eng. J., 332 (2018) 737-748 doi: 10.1016/j.cej.2017.09.118
5. [5]
  M.O. Barbosa, N.F. Moreira, A.R. Ribeiro, M.F. Pereira, A.M. Silva, Water Res. 94 (2016) 257-279 doi: 10.1016/j.watres.2016.02.047
6. [6]
  Z. Hu, X. Cai, Z. Wang, et al., J. Hazard. Mater. 380 (2019) 120812 doi: 10.1016/j.jhazmat.2019.120812
7. [7]
  F. Wang, Y. Wu, Y. Wang, et al., Chem. Eng. J. 356 (2019) 857-868 doi: 10.3390/electronics8080857
8. [8]
  Y. Su, D. Jassby, S. Song, et al., Environ. Sci. Technol. 52 (2018) 6466-6475 doi: 10.1021/acs.est.8b00231
9. [9]
  H. Kohay, A. Izbitski, Y.G. Mishael, Environ. Sci. Technol. 49 (2015) 9280-9288 doi: 10.1021/acs.est.5b01530
10. [10]
  B.N. Bhadra, I. Ahmed, S. Kim, S.H. Jhung, Chem. Eng. J. 314 (2017) 50-58 doi: 10.1016/j.cej.2016.12.127
11. [11]
  R. Deng, Q. He, D. Yang, et al., Chem. Eng. J. 406 (2021) 126884 doi: 10.1016/j.cej.2020.126884
12. [12]
  Y. Cui, Q. Ma, X. Deng, et al., Appl. Catal. B 206 (2017) 136-145 doi: 10.1016/j.apcatb.2017.01.014
13. [13]
  B. Dong, T. Liu, C. Li, F. Zhang, Chin. Chem. Lett. 29 (2018) 671-680 doi: 10.1016/j.cclet.2017.12.002
14. [14]
  B. Li, L. Nengzi, R. Guo, et al., Chin. Chem. Lett. 31 (2020) 2705–2711. doi: 10.1016/j.cclet.2020.04.026
15. [15]
  P. Wang, Y. Mao, L. Li, et al., Angew. Chem. Int. Ed. 131 (2019) 11451-11456
16. [16]
  W. Li, R. Yu, M. Li, et al., Chemosphere 218 (2019) 966-973 doi: 10.1016/j.chemosphere.2018.11.185
17. [17]
  Y. Pan, X. Yuan, L. Jiang, et al., Chem. Eng. J. 354 (2018) 407-431 doi: 10.1016/j.cej.2018.08.028
18. [18]
  H. Yang, R. Cao, P. Sun, et al., Appl. Catal. B 256 (2019) 117862 doi: 10.1016/j.apcatb.2019.117862
19. [19]
  B. Weng, M.Y. Qi, C. Han, Z.R. Tang, Y.J. Xu, ACS Catal. 9 (2019) 4642-4687 doi: 10.1021/acscatal.9b00313
20. [20]
  X. Jiao, Z. Chen, X. Li, et al., J. Am. Chem. Soc. 139 (2017) 7586-7594 doi: 10.1021/jacs.7b02290
21. [21]
  S. Zhang, X. Liu, C. Liu, et al., ACS Nano 12 (2017) 751-758
22. [22]
  C. Du, Q. Zhang, Z. Lin, et al., Appl. Catal. B 248 (2019) 193-201 doi: 10.1016/j.apcatb.2019.02.027
23. [23]
  Z. Li, J. Hou, B. Zhang, et al., Nano Energy 59 (2019) 537-544 doi: 10.1016/j.nanoen.2019.03.004
24. [24]
  Y. He, H. Rao, K. Song, et al., Adv. Funct. Mater. 29 (2019) 1905153 doi: 10.1002/adfm.201905153
25. [25]
  F. Wang, P. Chen, Y. Feng, et al., Appl. Catal. B 207 (2017) 103-113 doi: 10.1016/j.apcatb.2017.02.024
26. [26]
  J. Zhang, J. Liu, X. Wang, et al., Appl. Catal. B 259 (2019) 118063 doi: 10.1016/j.apcatb.2019.118063
27. [27]
  Y. Huang, Y. Liang, Y. Rao, et al., Environ. Sci. Technol., 51 (2017) 2924-2933 doi: 10.1021/acs.est.6b04460
28. [28]
  Q. Zhang, P. Chen, M. Zhuo, et al., Appl. Catal. B 221 (2018) 129-139 doi: 10.1016/j.apcatb.2017.09.008
29. [29]
  X. Peng, L. Ye, Y. Ding, et al., Appl. Catal. B 260 (2020) 118152 doi: 10.1016/j.apcatb.2019.118152
30. [30]
  J. Li, C. Zhong, J. Huang, et al., J. Colloid Interf. Sci. 553 (2019) 758-767 doi: 10.3390/s19040758
31. [31]
  Y. Chen, J. Li, P. Liao, et al., Chin. Chem. Lett. 31 (2020) 1516-1519 doi: 10.1016/j.cclet.2019.12.013
32. [32]
  G. Yang, D. Chen, H. Ding, et al., Appl. Catal. B 219 (2017) 611-618 doi: 10.1016/j.apcatb.2017.08.016
33. [33]
  W. Yang, L. Zhang, J. Xie, et al., Angew. Chem., Int. Ed. 55 (2016) 6716-6720 doi: 10.1002/anie.201602543
34. [34]
  Q. Zhu, Y. Sun, S. Xu, et al., J. Hazard. Mater. 382 (2020) 121098 doi: 10.1016/j.jhazmat.2019.121098
35. [35]
  D. Yang, J. Li, L. Luo, et al., Chem. Eng. J. 387 (2020) 124103 doi: 10.1016/j.cej.2020.124103
36. [36]
  B. Gao, L. Liu, J. Liu, F. Yang, Appl. Catal. B 129 (2013) 89-97 doi: 10.3901/JME.2013.04.089
37. [37]
  F. Wang, Y. Wang, Y. Feng, et al., Appl. Catal. B 221 (2018) 510-520 doi: 10.1016/j.apcatb.2017.09.055
38. [38]
  Z. Xie, Y. Feng, F. Wang, et al., Appl. Catal. B 229 (2018) 96-104 doi: 10.1016/j.apcatb.2018.02.011
39. [39]
  C. Chang, H. Yang, W. Mu, et al., Appl. Catal. B 254 (2019) 647-658 doi: 10.1016/j.apcatb.2019.05.030
40. [40]
  S. He, C. Yan, X. Chen, et al., Appl. Catal. B 276 (2020) 119138 doi: 10.1016/j.apcatb.2020.119138
41. [41]
  M. Yang, Y. Xu, W. Lu, et al., Nat. Commun. 8 (2017) 14224 doi: 10.1038/ncomms14224
42. [42]
  P. Chen, F. Wang, Z. Chen, et al., Appl. Catal. B 204 (2017) 250-259 doi: 10.1016/j.apcatb.2016.11.040
43. [43]
  C. Yi, Q. Liao, W. Deng, et al., Sci. Total. Environ. 684 (2019) 527-536 doi: 10.1016/j.scitotenv.2019.05.338
44. [44]
  H. Yu, E. Nie, J. Xu, et al., Water Res., 47 (2013) 1909-1918 doi: 10.1016/j.watres.2013.01.016
45. [45]
  S. Salaeh, D. Juretic Perisic, M. Biosic, et al., Chem. Eng. J. 304 (2016) 289-302 doi: 10.1016/j.cej.2016.06.083
46. [46]
  C. Martínez, M. Canle L, M.I. Fernández, J.A. Santaballa, J. Faria, Appl. Catal. B 107 (2011) 110-118 doi: 10.1016/j.apcatb.2010.12.039
47. [47]
  S. Li, Z. Wang, X. Zhang, et al., Chem. Eng. J., 378 (2019) 122169
48. [48]
  Z. Cai, X. Hao, X. Sun, et al., Water Res. 162 (2019) 369-382 doi: 10.1016/j.watres.2019.06.017
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Facile defect engineering in ZnIn2S4 coupled with carbon dots for rapid diclofenac degradation

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通讯作者: 陈斌, bchen63@163.com

Facile defect engineering in ZnIn₂S₄ coupled with carbon dots for rapid diclofenac degradation