Citation: Jiaqiang Wu, Yanfang Liu, Xuejing Yang, Jinling Wang, Jie Yang. Intercalation modification of FeOCl and its application in dye wastewater treatment[J]. Chinese Chemical Letters, ;2021, 32(8): 2503-2508. doi: 10.1016/j.cclet.2020.12.043 shu

Intercalation modification of FeOCl and its application in dye wastewater treatment

Jiaqiang Wu ^{a, b} ,
Yanfang Liu ^{a, b} ,
Xuejing Yang ^b,, ,
Jinling Wang ^b ,
Jie Yang ^{a, c,,}

a.
School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
b.
School of Mechanical and Power Engineering, East China University of Science and Technology, Shanghai 200237, China
c.
Centre for Environmental Sciences, Hasselt University, Martelarenlaan 42, Hasselt 3500, Belgium

Corresponding author: Xuejing Yang, xj.yang@ecust.edu.cn Jie Yang, wdpz_ygpz@163.com
Received Date: 24 September 2020
Revised Date: 20 November 2020
Accepted Date: 9 December 2020
Available Online: 25 December 2020

Figures(4)

The textile industry spreads globally with the challenges of its wastewater treatment, especially dyes, which are difficult to degrade. To improve coagulation-flocculation process in dye wastewater treatment, an intercalation process was employed to prepare a new efficient coagulant of lithium borohydride-iron oxychloride (LiBH₄_FeOCl) in this study. The layered crystal pristine iron oxychloride (FeOCl) material was prepared by chemical gas phase migration. LiBH₄ was introduced into the layers of two dimensional (2D) FeOCl nanosheets by a simple method of liquid phase insertion. The samples were characterized by a field emitting scanning electron microscopy (SEM), a rotating anode X-ray powder diffractometer (XRD), etc. The cationic dye was employed as the simulated pollutant. A coagulation and decolorization experimental device was built to study the coagulation performance of the new coagulant LiBH₄_FeOCl. It is found that the intercalation modified LiBH₄_FeOCl exhibits the characteristics of crystal structure, and the layered structure of FeOCl is preserved. LiBH₄_FeOCl, as an insoluble inorganic solid coagulant, performs well for dye pollutants of methyl red, basic yellow 1, methylene blue, rhodamine B, ethyl violet and Janus green B. The reaction rate is significantly 68% higher than the current commercial coagulants of Al₂(SO₄)₃. The mechanism analysis reveals that LiBH₄_FeOCl breaks and disperses rapidly in the water environment. Its negatively charged material particles can be electrostatically adsorbed with dye pollutant molecules through electrostatic action. The above collaborative actions of breaking, dispersion and electrostatic adsorption are the main coagulation mechanisms of LiBH₄_FeOCl. The solid inorganic coagulant of LiBH₄_FeOCl provides a competitive alternative for traditional inorganic salts and organic coagulants.
- FeOCl,
- Intercalation modification,
- Coagulation,
- Dye wastewater treatment,
- Ion selectivity
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