Citation: Zifang Zhao, Yue Liu, Fang Wan, Shuai Wang, Nannan Zhang, Lili Liu, Anyuan Cao, Zhiqiang Niu. Free-standing nitrogen doped graphene/Co(OH)₂ composite films with superior catalytic activity for aprotic lithium-oxygen batteries[J]. Chinese Chemical Letters, ;2021, 32(2): 594-597. doi: 10.1016/j.cclet.2020.11.047 shu

Free-standing nitrogen doped graphene/Co(OH)₂ composite films with superior catalytic activity for aprotic lithium-oxygen batteries

Zifang Zhao ^{a, b} ,
Yue Liu ^b ,
Fang Wan ^b ,
Shuai Wang ^b ,
Nannan Zhang ^b ,
Lili Liu ^{a, *,} ,
Anyuan Cao ^c ,
Zhiqiang Niu ^{b, *,}

a.
Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
b.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin 300071, China
c.
Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871, China

lililiuhappy@163.com

zqniu@nankai.edu.cn

Received Date: 12 October 2020
Revised Date: 6 November 2020
Accepted Date: 17 November 2020
Available Online: 30 November 2020

Figures(4)

The recent boom in large-scale energy storage system promotes the development of lithium-oxygen batteries because of their high theoretical energy density. However, their applications are still limited by the sluggish kinetic, insoluble discharge product deposition and the undesired parasitic reaction. Herein, the free-standing nitrogen doped reduced graphene oxide/Co(OH)₂ (NRGO/Co(OH)₂) composite films were prepared by a facile hydrothermal method. The NRGO/Co(OH)₂ composite films display interconnected three-dimensional conductive network, which can not only promote the diffusion of O₂ and the transport of electrolyte ions, but also provide abundant storage space for discharge products. Moreover, the introduction of nitrogen-containing functional groups results in improved conductivity and electron adsorption ability, which can facilitate electron transport and enhance the surface catalytic activity. Combining with excellent catalytic performance, the lithium-oxygen batteries with NRGO/Co(OH)₂ composite film cathodes deliver low charge overpotential and excellent cycling performance.
- Free-standing films,
- Nitrogen doping,
- Graphene,
- Co(OH)₂,
- Lithium-oxygen batteries
1. [1]
  Z. Zhao, X. Wang, M. Yao, et al., Chin. Chem. Lett. 30 (2019) 915-918. doi: 10.1016/j.cclet.2019.03.003
2. [2]
  R. Wang, M. Yao, Z. Niu, InfoMat 2 (2019) 113-125.
3. [3]
  F. Wan, J. Zhu, S. Huang, Z. Niu, Batter. Supercaps 3 (2020) 323-330. doi: 10.1002/batt.201900229
4. [4]
  J. Gao, X. Cai, J. Wang, et al., Chem. Eng. J. 352 (2018) 972-995. doi: 10.1016/j.cej.2018.06.014
5. [5]
  Z. Chang, J. Xu, X. Zhang, Adv. Energy Mater. 7 (2017) 1700875. doi: 10.1002/aenm.201700875
6. [6]
  K.N. Jung, J. Kim, Y. Yamauchi, et al., J. Mater. Chem. A 4 (2016) 14050-14068. doi: 10.1039/C6TA04510C
7. [7]
  J.B. Park, S.H. Lee, H.G. Jung, D. Aurbach, Y.K. Sun, Adv. Mater. 30 (2018) 1704162. doi: 10.1002/adma.201704162
8. [8]
  A.C. Luntz, B.D. McCloskey, Chem. Rev. 114 (2014) 11721-11750. doi: 10.1021/cr500054y
9. [9]
  F. Cheng, J. Chen, Chem. Soc. Rev. 41 (2012) 2172-2192. doi: 10.1039/c1cs15228a
10. [10]
  J. Wang, J. Liu, Y. Cai, et al., ChemElectroChem 5 (2018) 1702-1707. doi: 10.1002/celc.201800289
11. [11]
  W. Chen, Y.F. Gong, J.H. Liu, Chin. Chem. Lett. 28 (2017) 709-718. doi: 10.1016/j.cclet.2016.10.023
12. [12]
  Z. Peng, S.A. Freunberger, Y. Chen, P.G. Bruce, Science 337 (2012) 563-566. doi: 10.1126/science.1223985
13. [13]
  Y. Peng, Y. Zhang, J. Huang, et al., Carbon 124 (2017) 23-33. doi: 10.1016/j.carbon.2017.08.035
14. [14]
  Y. Dong, S. Li, S. Hong, L. Wang, B. Wang, Chin. Chem. Lett. 31 (2020) 635-642. doi: 10.1016/j.cclet.2019.08.021
15. [15]
  J. Xu, Z. Wang, D. Xu, L. Zhang, X. Zhang, Nat. Commum. 4 (2013) 2438. doi: 10.1038/ncomms3438
16. [16]
  F. Li, T. Zhang, H. Zhou, Energy Environ. Sci. 6 (2013) 1125-1141. doi: 10.1039/c3ee00053b
17. [17]
  D. Aurbach, B.D. McCloskey, L.F. Nazar, P.G. Bruce, Nat. Energy 1 (2016) 16128. doi: 10.1038/nenergy.2016.128
18. [18]
  P. Tan, M. Liu, Z. Shao, M. Ni, Adv. Energy Mater. 7 (2017) 1602674. doi: 10.1002/aenm.201602674
19. [19]
  Z. Huang, H. Zeng, M. Xie, et al., Angew. Chem. Int. Ed. 58 (2019) 2345-2349. doi: 10.1002/anie.201812983
20. [20]
  S. Bae, Y.G. Yoo, J. Park, et al., Chem. Commun. 53 (2017) 11767-11770. doi: 10.1039/C7CC05459A
21. [21]
  D.A. Agyeman, M. Park, Y.M. Kang, J. Mater. Chem. A 5 (2017) 22234-22241. doi: 10.1039/C7TA05391F
22. [22]
  R. Liu, Y. Lei, W. Yu, et al., ACS Energy Lett. 2 (2017) 313-318. doi: 10.1021/acsenergylett.6b00581
23. [23]
  C. Zhu, Y. Wang, L. Shuai, et al., Chin. Chem. Lett. 31 (2020) 1997-2002. doi: 10.1016/j.cclet.2019.11.046
24. [24]
  Z. Wang, D. Xu, J. Xu, X. Zhang, Chem. Soc. Rev. 43 (2014) 7746-7786. doi: 10.1039/C3CS60248F
25. [25]
  J. Long, Z. Hou, C. Shu, et al., ACS Appl. Mater. Interfaces 11 (2019) 3834-3842. doi: 10.1021/acsami.8b15699
26. [26]
  R. Bi, G. Liu, C. Zeng, et al., Small 15 (2019)1804958. doi: 10.1002/smll.201804958
27. [27]
  X. Li, C. Wen, H. Li, G. Sun, J. Energy Chem. 47 (2020) 272-280. doi: 10.1016/j.jechem.2020.02.016
28. [28]
  G. Liu, L. Zhang, S. Wang, L.X. Ding, H. Wang, J. Mater, Chem. A 5 (2017) 14530-14536.
29. [29]
  H. Gong, H. Xue, T. Wang, et al., ACS Appl. Mater. Interfaces 8 (2016) 18060-18068. doi: 10.1021/acsami.6b04810
30. [30]
  Y. Ren, S. Zhao, H. Li, et al., J. Energy Chem. 30 (2019) 63-70. doi: 10.1016/j.jechem.2018.03.012
31. [31]
  Q. Liu, J. Xu, Z. Chang, X. Zhang, J. Mater. Chem. A 2 (2014) 6081-6085. doi: 10.1039/C3TA14011C
32. [32]
  L. Shang, H. Yu, X. Huang, et al., Adv. Mater. 28 (2016) 1668-1674. doi: 10.1002/adma.201505045
33. [33]
  Y. Tu, H. Li, D. Deng, et al., Nano Energy 30 (2016) 877-884. doi: 10.1016/j.nanoen.2016.08.066
34. [34]
  Z. Sun, L. Lin, M. Yuan, et al., Electrochim. Acta 281 (2018) 420-428. doi: 10.1016/j.electacta.2018.05.201
35. [35]
  J. Zhang, C. Dong, Z. Wang, et al., Electrochim. Acta 284 (2018) 495-503. doi: 10.1016/j.electacta.2018.07.182
36. [36]
  B.R. Jia, M.L. Qin, S.M. Li, et al., ACS Appl. Mater. Interfaces 8 (2016) 15582-15590. doi: 10.1021/acsami.6b02768
37. [37]
  M. He, P. Zhang, L. Liu, B. Liu, S. Xu, Electrochim. Acta 191 (2016) 90-97. doi: 10.1016/j.electacta.2016.01.026
38. [38]
  W.B. Luo, S.L. Chou, J.Z. Wang, Y.C. Zhai, H.K. Liu, Small 11 (2015) 2817-2824. doi: 10.1002/smll.201403535
39. [39]
  T. Zhu, X. Li, Y. Zhang, et al., J. Electroanal. Chem. 136 (2014) 16481-16484.
40. [40]
  F. Song, X. Hu, J. Am. Chem. Soc. 136 (2014) 16481-16484. doi: 10.1021/ja5096733
41. [41]
  L.J. Zhang, R. Zheng, S. Li, et al., ACS Appl. Mater. Interfaces 6 (2014) 13406-13412. doi: 10.1021/am501216b
42. [42]
  S.U. Lee, R.V. Belosludov, H. Mizuseki, Y. Kawazoe, Small 5 (2009) 1769-1775. doi: 10.1002/smll.200801938
43. [43]
  Q. Li, P. Xu, W. Gao, et al., Adv. Mater. 26 (2014) 1378-1386. doi: 10.1002/adma.201304218
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沈阳化工大学材料科学与工程学院沈阳 110142

Free-standing nitrogen doped graphene/Co(OH)2 composite films with superior catalytic activity for aprotic lithium-oxygen batteries

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通讯作者: 陈斌, bchen63@163.com

Free-standing nitrogen doped graphene/Co(OH)₂ composite films with superior catalytic activity for aprotic lithium-oxygen batteries