Citation: Qiang Ma, Yu Dai, Hongrui Wang, Guozhu Ma, Hui Guo, Xianxiang Zeng, Naimei Tu, Xiongwei Wu, Mingtao Xiao. Directly conversion the biomass-waste to Si/C composite anode materials for advanced lithium ion batteries[J]. Chinese Chemical Letters, ;2021, 32(1): 5-8. doi: 10.1016/j.cclet.2020.11.007 shu

Directly conversion the biomass-waste to Si/C composite anode materials for advanced lithium ion batteries

College of Agronomy, School of Chemistry and Materials Science, School of Mechanical and Electrical Engineering, Hunan Agricultural University, Changsha 410128, China

tnm505@163.com

wxwcsu05@aliyun.com

xiaomentor@163.com

Received Date: 23 September 2020
Revised Date: 1 November 2020
Accepted Date: 3 November 2020
Available Online: 4 November 2020

Figures(5)

The necessity to explore high-efficiency and high-value utilization strategy for biomass-waste is desirable. Herein, the strategy for direct conversion biomass-waste (rice husks) to Si/C composite structure anode was built. The Si/C composite materials were successfully obtained via the typical thermal reduction with magnesium, and the Si nanoparticle was uniformly embedded in carbon frame, as revealed by Raman, X-ray diffraction (XRD) and transmission electron microscope (TEM) measurement. The carbon structure among rice husks was effectively used as a protective layer to accommodate the volume variation of Si anode during the repeated lithiation/delithiation process. Benefitting from the structure design, the batteries show a superior electrochemical stability with the capacity retention rate above 90% after 150 cycles at the charge/discharge rate of 0.5 C (1 C = 600 mAh/g), and hold a high charge capacity of 420.7 mAh/g at the rate of 3 C. Therefore, our finding not only provides a promising design strategy for directly conversion biomass-waste to electrochemical storage materials but broadens the high-efficiency utilization method for other biomass by-products.
- Biomass-waste,
- Rice husks,
- Composite anode,
- Lithium ion batteries,
- High energy density
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