Citation: Xiaomeng Liu, Qishun Huang, Jun Wang, Lanling Zhao, Haoran Xu, Qing Xia, Deyuan Li, Lei Qian, Huaisheng Wang, Jintao Zhang. In-situ deposition of Pd/Pd₄S heterostructure on hollow carbon spheres as efficient electrocatalysts for rechargeable Li-O₂ batteries[J]. Chinese Chemical Letters, ;2021, 32(6): 2086-2090. doi: 10.1016/j.cclet.2020.11.003 shu

In-situ deposition of Pd/Pd₄S heterostructure on hollow carbon spheres as efficient electrocatalysts for rechargeable Li-O₂ batteries

Xiaomeng Liu ^a ,
Qishun Huang ^a ,
Jun Wang ^{a, b, **,} ,
Lanling Zhao ^c ,
Haoran Xu ^a ,
Qing Xia ^a ,
Deyuan Li ^a ,
Lei Qian ^a ,
Huaisheng Wang ^d ,
Jintao Zhang ^{b, *,}

a.
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Ji'nan 250061, China
b.
Key Laboratory for Colloid and Interface Chemistry (Ministry of Education), School of Chemistry and Chemical Engineering, Shandong University, Ji'nan 250061, China
c.
School of Physics, Shandong University, Ji'nan 250100, China
d.
School of Chemistry and Chemical Engineering, Liao Cheng University, Liaocheng 252059, China

^**

jw707@sdu.edu.cn

jtzhang@sdu.edu.cn

Received Date: 29 September 2020
Revised Date: 30 October 2020
Accepted Date: 2 November 2020
Available Online: 4 November 2020

Figures(4)

The sluggish kinetics of oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) have always restricted the development of lithium oxygen batteries (LOBs). Herein, hollow carbon spheres loaded with Pd/Pd₄S heterostructure (Pd/Pd₄S@HCS) were successfully prepared via the in-situ deposition to improve the electrocatalytic activities for both ORR and OER in LOBs. With the well-dispersed Pd/Pd₄S nanoparticles, the hierarchical composite with large specific surface area offers favorable transport channels for ions, electron and oxygen. Especially, the Pd/Pd₄S nanoparticles could exhibit excellent electrochemical performance for ORR and OER due to their intrinsic catalytic property and interfacial effect from the heterostructure. Therefore, the LOBs with Pd/Pd₄S@HCS as cathode catalyst show improved specific capacities, good rate ability and stable cycling performance.
- Hierarchical porous carbon sphere,
- Pd/Pd₄S heterostructure,
- In-situ deposition,
- Enhanced electrocatalytic activity,
- Lithium-oxygen batteries
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In-situ deposition of Pd/Pd₄S heterostructure on hollow carbon spheres as efficient electrocatalysts for rechargeable Li-O₂ batteries