Citation: Guang-Ya Zhang, Sun-Hong Ruan, Yan-Yun Li, Jing-Xing Gao. Manganese catalyzed asymmetric transfer hydrogenation of ketones[J]. Chinese Chemical Letters, ;2021, 32(4): 1415-1418. doi: 10.1016/j.cclet.2020.10.023 shu

Manganese catalyzed asymmetric transfer hydrogenation of ketones

Department of Chemistry, College of Chemistry and Chemical Engineering, National Engineering Laboratory for Green Chemical Production of Alcohols-Ethers-Esters, Xiamen University, Xiamen 361005, China

yanyunli@xmu.edu.cn

Received Date: 15 August 2020
Revised Date: 15 October 2020
Accepted Date: 19 October 2020
Available Online: 21 October 2020

Figures(3)

The asymmetric transfer hydrogenation (ATH) of a wide range of ketones catalyzed by manganese complex as well as chiral P_xN_y-type ligand under mild conditions was investigated. Using 2-propanol as hydrogen source, various ketones could be enantioselectively hydrogenated by combining cheap, readily available [MnBr(CO)₅] with chiral, 22-membered macrocyclic ligand (R, R, R', R')-CyP₂N₄ (L5) with 2 mol% of catalyst loading, affording highly valuable chiral alcohols with up to 95% ee.
- Asymmetric catalysis,
- Manganese,
- Ketones,
- Macrocyclic ligand,
- Asymmetric transfer hydrogenation
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