Citation: Xiaokang Wang, Yutong Wang, Kebin Lu, Weifeng Jiang, Fangna Dai. A 3D Ba-MOF for selective adsorption of CO₂/CH₄ and CO₂/N₂[J]. Chinese Chemical Letters, ;2021, 32(3): 1169-1172. doi: 10.1016/j.cclet.2020.09.036 shu

A 3D Ba-MOF for selective adsorption of CO₂/CH₄ and CO₂/N₂

College of Science, School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China

fndai@upc.edu.cn

Received Date: 12 August 2020
Revised Date: 18 September 2020
Accepted Date: 22 September 2020
Available Online: 24 September 2020

Figures(4)

An unexpected in-situ hydrolysis reaction occurred during the solvothermal reaction of N, N'-bis(4-carboxy-2-methylphenyl)pyromellitic di-imide) and Ba(NO₃)₂, and a novel porous Ba-MOF, [H₂N(CH₃)₂]_0.5[Ba_1.5(L)(DMA)]·1.5DMA·1.5H₂O (UPC-70, H₃L = 2-(4-carboxy-2-methylphenyl)-1, 3-dioxoisoin-doline-5, 6-dicarboxylic acid, DMA = N, N-dimethylacetamide), was obtained on the basis of the partial hydrolysate. The as-synthesized 3D network with 1D open channels of different sizes (24 Å and 10 Å) contains abundant open metal sites after removal of solvents, which is conducive to the preferential adsorption of CO₂. The subsequent gas sorption measurement reveals the high separation selectivity of UPC-70 for CO₂/CH₄ (15) and CO₂/N₂ (32) at ambient conditions, and GCMC theoretical simulation provides good verification of the experimental results, indicating that UPC-70 is a potential candidate for CO₂ capture from flue gas and natural gas.
- Metal-organic framework,
- In-situ hydrolysis,
- Selective adsorption,
- CO₂ capture,
- GCMC simulation
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沈阳化工大学材料科学与工程学院沈阳 110142

A 3D Ba-MOF for selective adsorption of CO2/CH4 and CO2/N2

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通讯作者: 陈斌, bchen63@163.com

A 3D Ba-MOF for selective adsorption of CO₂/CH₄ and CO₂/N₂