Citation: Yingying Zhao, Liuyang Zhou, Xiaobo Wu, Xiaosha Wang, Yungui Li, Yazhou Qi, Lihui Jiang, Guohui Chen, Yingping Zou. Ternary organic solar cells: Improved optical and morphological properties allow an enhanced efficiency[J]. Chinese Chemical Letters, ;2021, 32(4): 1359-1362. doi: 10.1016/j.cclet.2020.09.032 shu

Ternary organic solar cells: Improved optical and morphological properties allow an enhanced efficiency

Yingying Zhao ^{a, 1} ,
Liuyang Zhou ^{b, 1} ,
Xiaobo Wu ^c ,
Xiaosha Wang ^a ,
Yungui Li ^d ,
Yazhou Qi ^a ,
Lihui Jiang ^{a, *,} ,
Guohui Chen ^{a, *,} ,
Yingping Zou ^a

a.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
b.
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
c.
College of Metallurgy and Materials Engineering, Hunan University of Technology, Zhuzhou 412000, China
d.
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

jianglh@csu.edu.cn

gh-ch@163.com

Received Date: 8 July 2020
Revised Date: 28 August 2020
Accepted Date: 21 September 2020
Available Online: 22 September 2020

Figures(4)

The power conversion efficiency (PCE) of OFQx-T: PC₇₁BM blend films reaches 7.59%. On this basis, ternary organic solar cells (OSCs) were fabricated with ITIC or PTB7-Th as the third component. The ternary OSCs with 50 wt% ITIC in acceptors exhibits an enhanced efficiency, from 7.59% to 8.17%. Also, the PCE of ternary OSCs with 50 wt% PTB7-Th in donors achieves 8.72%, which is 13% higher than that of binary OSCs. The PCE improvement of two ternary OSCs is mainly due to the increase of short-circuit current density (J_sc), which can be attributed to the complementary absorption spectra and improved film morphology. This work suggests that the selection of an appropriate third component plays a critical role in improving the PCE of ternary OSCs.
- Ternary OSCs,
- Broaden absorption spectra,
- Morphology optimization,
- Appropriate third component
1. [1]
  Q. Wei, W. Liu, M. Leclerc, et al., Sci. China Chem. 63(2020) 1352-1366. doi: 10.1007/s11426-020-9799-4
2. [2]
  L. Lu, T. Zheng, Q. Wu, et al., Chem. Rev. 115(2015) 12666-12731. doi: 10.1021/acs.chemrev.5b00098
3. [3]
  J. Yuan, Y. Zhang, L. Zhou, et al., Joule 3(2019) 1140-1151. doi: 10.1016/j.joule.2019.01.004
4. [4]
  G. Zhang, J. Zhao, P.C.Y. Chow, et al., Chem. Rev. 118(2018) 3447-3507. doi: 10.1021/acs.chemrev.7b00535
5. [5]
  X. Xu, Z. Bi, W. Ma, et al., Adv. Mater. 29(2017) 1704271. doi: 10.1002/adma.201704271
6. [6]
  Q. Liu, J. Qin, J. Xu, et al., Sci. Bull. 65(2020) 272-275. doi: 10.1016/j.scib.2020.01.001
7. [7]
  W. Huang, P. Cheng, Y.M. Yang, et al., Adv. Mater. 30(2018) 1705706. doi: 10.1002/adma.201705706
8. [8]
  W. Zhao, S. Li, H. Yao, et al., J. Am. Chem. Soc. 139(2017) 7148-7151. doi: 10.1021/jacs.7b02677
9. [9]
  L. Meng, Y. Zhang, X. Wan, et al., Science 361(2018) 1094-1098. doi: 10.1126/science.aat2612
10. [10]
  Y. Cui, B. Gao, Y. Qin, et al., J. Am. Chem. Soc. 139(2017) 7302-7309. doi: 10.1021/jacs.7b01493
11. [11]
  T.Y. Li, T. Meyer, Z. Ma, et al., J. Am. Chem. Soc. 139(2017) 13636-13639. doi: 10.1021/jacs.7b07887
12. [12]
  K. Zhang, K. Gao, R. Xia, et al., Adv. Mater. 28(2016) 4817-4823. doi: 10.1002/adma.201506270
13. [13]
  X. Lia, K. Li, S. Dan, et al., Chin. Chem. Lett. 31(2020) 1243-1247. doi: 10.1016/j.cclet.2019.10.029
14. [14]
  P. Cheng, C. Yan, Y. Wu, et al., Adv. Mater. 28(2016) 8021-8028. doi: 10.1002/adma.201602067
15. [15]
  Q. An, F. Zhang, J. Zhang, et al., Energy Environ. Sci. 9(2016) 281-322. doi: 10.1039/C5EE02641E
16. [16]
  H. Huang, B. Sharma, J. Mater. Chem. A 5(2017) 11501. doi: 10.1039/C7TA00887B
17. [17]
  X. Ma, M. Luo, W. Gao, et al., J. Mater. Chem. A 7(2019) 7843-7851. doi: 10.1039/C9TA01497G
18. [18]
  M. Luo, C. Zhu, J. Yuan, et al., Chin. Chem. Lett. 30(2019) 2343-2346. doi: 10.1016/j.cclet.2019.07.023
19. [19]
  A. Wadsworth, M. Moser, A. Marks, et al., Chem. Soc. Rev. 48(2019) 1596-1625. doi: 10.1039/C7CS00892A
20. [20]
  L. Zhan, S. Li, T.K. Lau, et al., Energy Environ. Sci. 13(2020) 635-645. doi: 10.1039/C9EE03710A
21. [21]
  R. Yu, H. Yao, Y. Cui, et al., Adv. Mater. 31(2019) 1902302. doi: 10.1002/adma.201902302
22. [22]
  W. Gao, C. Zhong, G. Zhang, et al., ACS Energy Lett. 3(2018) 1760-1768. doi: 10.1021/acsenergylett.8b00825
23. [23]
  Y. Xie, F. Yang, Y. Li, et al., Adv. Mater. 30(2018) 1803045. doi: 10.1002/adma.201803045
24. [24]
  K. Weng, P. Bi, H. Ryu, et al., J. Mater. Chem. A 7(2019) 3552. doi: 10.1039/C8TA12034J
25. [25]
  X. Ma, Y. Mi, F. Zhang, et al., Adv. Energy Mater. 8(2018) 1702854. doi: 10.1002/aenm.201702854
26. [26]
  H. Hu, L. Ye, M. Ghasemi, et al., Adv. Mater. 31(2019) 1808279. doi: 10.1002/adma.201808279
27. [27]
  J. Wang, W. Gao, Q. An, et al., J. Mater. Chem. A 6(2018) 11751-11758. doi: 10.1039/C8TA03453B
28. [28]
  Y. Cho, S. Jeong, S. Lee, et al., Nano Energy 75(2020) 104896. doi: 10.1016/j.nanoen.2020.104896
29. [29]
  X. Du, L. Zhou, H. Lin, et al., Adv. Funct. Mater. 30(2020) 1909837. doi: 10.1002/adfm.201909837
30. [30]
  S. Xu, L. Feng, J. Yuan, et al., Org. Electron. 50(2017) 7-15. doi: 10.1016/j.orgel.2017.07.005
31. [31]
  S. Xie, J. Wang, R. Wang, et al., Chin. Chem. Lett. 30(2019) 217-221. doi: 10.1016/j.cclet.2018.04.001
32. [32]
  M. Zhang, F. Zhang, Q. An, et al., Nano Energy 22(2016) 241-254. doi: 10.1016/j.nanoen.2016.02.032
33. [33]
  L. Huo, T. Liu, X. Sun, et al., Adv. Mater. 27(2015) 2938-2944. doi: 10.1002/adma.201500647
34. [34]
  D.F. Barbe, J. Phys. D: Appl. Phys. 4(1971) 1812. doi: 10.1088/0022-3727/4/11/427
35. [35]
  S.S.M. Stolterfoht, A. Armin, H. Jin, et al., Adv. Mater. 7(2017) 1601379.
36. [36]
  Y. Zhong, M.T. Trinh, R. Chen, et al., Nat. Commun. 6(2015) 8242. doi: 10.1038/ncomms9242
1. [1]
  Zhongjie Li , Xiangyue Kong , Yuhao Liu , Huayu Qiu , Lingling Zhan , Shouchun Yin . Progress of additives for morphology control in organic photovoltaics. Chinese Chemical Letters, 2024, 35(6): 109378-. doi: 10.1016/j.cclet.2023.109378
2. [2]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
3. [3]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
4. [4]
  Chuyuan Lin , Hui Lin , Lingxing Zeng . Optimization strategy for rechargeable Zn metal batteries over wide-pH aqueous electrolytes. Chinese Journal of Structural Chemistry, 2025, 44(1): 100407-100407. doi: 10.1016/j.cjsc.2024.100407
5. [5]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
6. [6]
  Xin Lu , Haoran Sun , Xiaomeng Li , Chunrui Li , Jinfeng Wang , Dandan Zhou . C14-HSL limits the mycelial morphology of pathogen Trichosporon cells but enhances their aggregation: Mechanisms and implications. Chinese Chemical Letters, 2024, 35(6): 108936-. doi: 10.1016/j.cclet.2023.108936
7. [7]
  Yun Wei , Lei Zhou , Wenbin Hu , Liming Yang , Guang Yang , Chaoqiang Wang , Hui Shi , Fei Han , Yufa Feng , Xuan Ding , Penghui Shao , Xubiao Luo . Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries: Process analysis and evaluation. Chinese Chemical Letters, 2024, 35(7): 109172-. doi: 10.1016/j.cclet.2023.109172
8. [8]
  Yuhao Ma , Yufei Zhou , Mingchuan Yu , Cheng Fang , Shaoxia Yang , Junfeng Niu . Covalently bonded ternary photocatalyst comprising MoSe₂/black phosphorus nanosheet/graphitic carbon nitride for efficient moxifloxacin degradation. Chinese Chemical Letters, 2024, 35(9): 109453-. doi: 10.1016/j.cclet.2023.109453
9. [9]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
10. [10]
  Linghui Zou , Meng Cheng , Kaili Hu , Jianfang Feng , Liangxing Tu . Vesicular drug delivery systems for oral absorption enhancement. Chinese Chemical Letters, 2024, 35(7): 109129-. doi: 10.1016/j.cclet.2023.109129
11. [11]
  Feihu Wu , Gengwen Chen , Kaitao Lai , Shiqing Zhang , Yingchao Liu , Ruijian Luo , Xiaocong Wang , Pinzhi Cao , Yi Ye , Jiarong Lian , Junle Qu , Zhigang Yang , Xiaojun Peng . Non-specific/specific SERS spectra concatenation for precise bacteria classifications with few samples using a residual neural network. Chinese Chemical Letters, 2025, 36(1): 109884-. doi: 10.1016/j.cclet.2024.109884
12. [12]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
13. [13]
  Shan Jiang , Lingchen Meng , Wenyue Ma , Qingkai Qi , Wei Zhang , Bin Xu , Leijing Liu , Wenjing Tian . Corrigendum to 'Morphology controllable conjugated network polymers based on AIE-active building block for TNP detection' [Chin. Chem. Lett. 32 (2021) 1037-1040]. Chinese Chemical Letters, 2024, 35(12): 108998-. doi: 10.1016/j.cclet.2023.108998
14. [14]
  Kang Wang , Qinglin Zhou , Weijin Li . Conductive metal-organic frameworks for electromagnetic wave absorption. Chinese Journal of Structural Chemistry, 2024, 43(10): 100325-100325. doi: 10.1016/j.cjsc.2024.100325
15. [15]
  Bowen Wang , Longwu Sun , Qianqian Cao , Xinzhi Li , Jianai Chen , Shizhao Wang , Miaolin Ke , Fener Chen . Cu-catalyzed three-component CSP coupling for the synthesis of trisubstituted allenyl phosphorothioates. Chinese Chemical Letters, 2024, 35(12): 109617-. doi: 10.1016/j.cclet.2024.109617
16. [16]
  Tianze Wang , Junyi Ren , Dongxiang Zhang , Huan Wang , Jianjun Du , Xin-Dong Jiang , Guiling Wang . Development of functional dye with redshifted absorption based on Knoevenagel condensation at 1-site in phenyl[b]-fused BODIPY. Chinese Chemical Letters, 2024, 35(6): 108862-. doi: 10.1016/j.cclet.2023.108862
17. [17]
  Lu Li , Suticha Chunta , Xianzi Zheng , Haisheng He , Wei Wu , Yi Lu . β-Lactoglobulin stabilized lipid nanoparticles enhance oral absorption of insulin by slowing down lipolysis. Chinese Chemical Letters, 2024, 35(4): 108662-. doi: 10.1016/j.cclet.2023.108662
18. [18]
  Wenkai Liu , Yanxian Hou , Weijian Liu , Ran Wang , Shan He , Xiang Xia , Chengyuan Lv , Hua Gu , Qichao Yao , Qingze Pan , Zehou Su , Danhong Zhou , Wen Sun , Jiangli Fan , Xiaojun Peng . Se-substituted pentamethine cyanine for anticancer photodynamic therapy mediated using the hot band absorption process. Chinese Chemical Letters, 2024, 35(12): 109631-. doi: 10.1016/j.cclet.2024.109631
19. [19]
  Manyu Zhu , Fei Liang , Lie Wu , Zihao Li , Chen Wang , Shule Liu , Xiue Jiang . Revealing the difference of Stark tuning rate between interface and bulk by surface-enhanced infrared absorption spectroscopy. Chinese Chemical Letters, 2025, 36(2): 109962-. doi: 10.1016/j.cclet.2024.109962
20. [20]
  Yikun Wang , Qiaomei Chen , Shijie Liang , Dongdong Xia , Chaowei Zhao , Christopher R. McNeill , Weiwei Li . Near-infrared double-cable conjugated polymers based on alkyl linkers with tunable length for single-component organic solar cells. Chinese Chemical Letters, 2024, 35(4): 109164-. doi: 10.1016/j.cclet.2023.109164

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(505)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142