Citation: Xiaoqi Fei, Shuang Cao, Weilong Ouyang, Haiqiang Wang, Zhongbiao Wu. Comparative study of Co₃O₄-ZSM-5 catalysts synthesized by different hydrothermal methods for the catalytic oxidation of dichloromethane[J]. Chinese Chemical Letters, ;2021, 32(3): 1224-1228. doi: 10.1016/j.cclet.2020.09.031 shu

Comparative study of Co₃O₄-ZSM-5 catalysts synthesized by different hydrothermal methods for the catalytic oxidation of dichloromethane

Xiaoqi Fei ^{a, b} ,
Shuang Cao ^{c, **,} ,
Weilong Ouyang ^{a, b} ,
Haiqiang Wang ^{a, b, *,} ,
Zhongbiao Wu ^{a, b}

a.
Key Laboratory of Environment Remediation and Ecological Health, Ministry of Education, College of Environmental & Resources Science, Zhejiang University, Hangzhou 310058, China
b.
Zhejiang Provincial Engineering Research Center of Industrial Boiler & Furnace Flue Gas Pollution Control, Hangzhou 310058, China
c.
Department of Environmental Engineering, China Jiliang University, Hangzhou 310018, China

caoshuang@cjlu.edu.cn

haiqiangwang@zju.edu.cn

Received Date: 25 June 2020
Revised Date: 17 August 2020
Accepted Date: 20 September 2020
Available Online: 22 September 2020

Figures(6)

In this work, various Co₃O₄-ZSM-5 catalysts were prepared by the microwave hydrothermal method (MH-Co₃O₄@ZSM-5), dynamic hydrothermal method (DH-Co₃O₄@ZSM-5), and conventional hydrothermal method (CH-Co₃O₄/ZSM-5). Their catalytic oxidation of dichloromethane (DCM) was analyzed. Detailed characterizations such as X-ray diffractometer (XRD), scanning microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET), H₂ temperature-programmed reduction (H₂-TPR), temperature-programmed desorption of O₂ (O₂-TPD), temperature-programmed desorption of NH₃ (NH₃-TPD), diffuse reflectance infrared Fourier-transform spectra with NH₃ molecules (NH₃-DRIFT), and temperature-programmed surface reaction (TPSR) were performed. Results showed that with the assistance of microwave, MH-Co₃O₄@ZSM-5 formed a uniform core-shell structure, while the other two samples did not. MH-Co₃O₄@ZSM-5 possessed rich surface adsorbed oxygen species, higher ratio of Co³⁺/Co²⁺, strong acidity, high reducibility, and oxygen mobility among the three Co₃O₄-ZSM-5 catalysts, which was beneficial for the improvement of DCM oxidation. In the oxidation of dichloromethane, MH-Co₃O₄@ZSM-5 presented the best activity and mineralization, which was consistent with the characterizations results. Meanwhile, according to the TPSR test, HCl or Cl₂ removal from the catalyst surface was also promoted in MH-Co₃O₄@ZSM-5 by their abundant Brønsted acid sites and the promotion of Deacon reaction by Co₃O₄ or the synergistic effect of Co₃O₄ and ZSM-5. According to the results of in situ DRIFT studies, a possible reaction pathway of DCM oxidation was proposed over the MH-Co₃O₄@ZSM-5 catalysts.
- Dichloromethane,
- Catalytic oxidation,
- Co₃O₄,
- ZSM-5,
- Core-shell structure,
- Microwave hydrothermal method
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Comparative study of Co3O4-ZSM-5 catalysts synthesized by different hydrothermal methods for the catalytic oxidation of dichloromethane

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通讯作者: 陈斌, bchen63@163.com

Comparative study of Co₃O₄-ZSM-5 catalysts synthesized by different hydrothermal methods for the catalytic oxidation of dichloromethane