Citation: Qi Wang, Hanqing Zhao, Boya Li, Chenhui Yang, Mingyang Li, Yanan Li, Peng Han, Miaomiao Wu, Tengyu Li, Ruiping Liu. MOF-derived Co₉S₈ nano-flower cluster array modified separator towards superior lithium sulfur battery[J]. Chinese Chemical Letters, ;2021, 32(3): 1157-1160. doi: 10.1016/j.cclet.2020.09.022 shu

MOF-derived Co₉S₈ nano-flower cluster array modified separator towards superior lithium sulfur battery

Department of Materials Science and Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China

miaomwu@cumtb.edu.cn

lrp@cumtb.edu.cn

Received Date: 16 August 2020
Revised Date: 10 September 2020
Accepted Date: 15 September 2020
Available Online: 16 September 2020

Figures(4)

Lithium sulfur batteries with high energy density are thought to be the most potential energy storage technology that can be commercialized. However, the shuttle effect of polysulfides deteriorates its electrochemical performance. Herein, a novel Co₉S₈ nanostructure derived from metal organic framework material (MOF) was explored by simple liquid phase reaction and heat vulcanization of 2-methylimidazole and Co(NO₃)₂·6H₂O on the surface of the original PP separator. The Co₉S₈ nano-flower cluster array wall was vertically and closely arranged with the thickness of 200 nm, and the polysulfide can be adsorbed by its physical and chemical action to slow down the "shuttle effect". It is found that the cell with the modified separator can achieve an ideal discharge capacity of about 600 mAh/g at 1 C. The specific capacity is maintained at 500 mAh/g after 200 cycles, with only 0.11% of capacity decay per cycle. It provides a new way for the utilization of MOF material derivatives to modify the separator in order to improve the electrochemical performance of lithium-sulfur batteries.
- Lithium-sulfur battery,
- Co₉S₈,
- MOF,
- Separator,
- Electrochemical performance
1. [1]
  S.T. Wang, Y. Yang, Y.H. Dong, Z.T. Zhang, Z.L. Tang, J. Adv. Ceram. 8 (2019) 1-18. doi: 10.1007/s40145-018-0292-2
2. [2]
  D.D. Zhang, J. Li, Z. Su, et al., J. Adv. Ceram. 7 (2018) 246-255. doi: 10.1007/s40145-018-0276-2
3. [3]
  Y. Yang, G.H. Yu, J.J. Cha, et al., ACS Nano 5 (2011) 9187-9193. doi: 10.1021/nn203436j
4. [4]
  R.P. Fang, S.Y. Zhao, Z.H. Sun, et al., Adv. Mater. 29 (2017) 1606823. doi: 10.1002/adma.201606823
5. [5]
  W.M. Kang, N.P. Deng, J.G. Ju, et al., Nanoscale 8 (2016) 16541-16588. doi: 10.1039/C6NR04923K
6. [6]
  A. Manthiram, Y.Z. Fu, Y.S. Su, Acc. Chem. Res. 46 (2013) 1125-1134. doi: 10.1021/ar300179v
7. [7]
  J. Park, S.H. Yu, Y.E. Sung, Nano Today 18 (2018) 35-64. doi: 10.1016/j.nantod.2017.12.010
8. [8]
  X. Liu, J.Q. Huang, Q. Zhang, L.Q. Mai, Adv. Mater. 29 (2017) 1601759. doi: 10.1002/adma.201601759
9. [9]
  M.R. Kaiser, Z.J. Han, J. Liang, S.X. Dou, J.Z. Wang, Energy Storage Mater. 19 (2019) 1-15. doi: 10.1016/j.ensm.2019.04.001
10. [10]
  M. Shaibani, A. Akbari, P. Sheath, et al., ACS Nano 10 (2016) 7768-7779. doi: 10.1021/acsnano.6b03285
11. [11]
  Y.W. Chen, S.Z. Niu, W. Lv, C. Zhang, Q.H. Yang, Chin. Chem. Lett. 30 (2019) 521-524. doi: 10.1016/j.cclet.2018.04.019
12. [12]
  S.K. Liu, X.B. Hong, Y.J. Li, et al., Chin. Chem. Lett. 28 (2017) 412-416. doi: 10.1016/j.cclet.2016.10.038
13. [13]
  T.Y. Wang, K. Kretschmer, S.H. Choi, et al., Small Methods 1 (2017) 11751-11787.
14. [14]
  Z. Li, H.B. Wu, X.W. Lou, Energ. Environ. Sci. 9 (2016) 3061-3070. doi: 10.1039/C6EE02364A
15. [15]
  Y. Zhong, X.H. Xia, S.J. Deng, et al., Adv. Energy Mater. 8 (2018) 1701110. doi: 10.1002/aenm.201701110
16. [16]
  J.L. Qin, H.J. Peng, J.Q. Huang, et al., Small Methods 2 (2018) 1800100. doi: 10.1002/smtd.201800100
17. [17]
  J.L. Qin, B.Q. Li, J.Q. Huang, et al., Mater. Chem. Front. 3 (2019) 615-619. doi: 10.1039/C8QM00645H
18. [18]
  J.Q. Huang, Z.L. Xu, S. Abouali, M.A. Garakani, J.K. Kim, Carbon 99 (2016) 624-632. doi: 10.1016/j.carbon.2015.12.081
19. [19]
  H. Tang, S.S. Yao, S.K. Xue, et al., Electrochim. Acta 263 (2018) 158-167. doi: 10.1016/j.electacta.2018.01.066
20. [20]
  V.C. Hoang, V. Do, I.W. Nah, et al., Electrochim. Acta 210 (2016) 1-6. doi: 10.1016/j.electacta.2016.04.171
21. [21]
  H.B. Lin, L.Q. Yang, X. Jiang, et al., Energ. Environ. Sci. 10 (2017) 1476-1486. doi: 10.1039/C7EE01047H
22. [22]
  G.M. Zhou, Y.B. Zhao, A. Manthiram, Adv. Energy Mater. 5 (2015) 1402263. doi: 10.1002/aenm.201402263
23. [23]
  L. Luo, S.H. Chung, C.H. Chang, A. Manthiram, J. Mater. Chem. A 5 (2017) 15002-15007. doi: 10.1039/C7TA05277D
24. [24]
  X.L. Ji, K.T. Lee, L.F. Nazar, Nat. Mater. 8 (2009) 500-506. doi: 10.1038/nmat2460
25. [25]
  Z. Zhang, L.L. Kong, S. Liu, G.R. Li, X.P. Gao, Adv. Energy Mater. 7 (2017) 1602543. doi: 10.1002/aenm.201602543
26. [26]
  S.Q. Chen, B. Sun, X.Q. Xie, et al., Nano Energy 16 (2015) 268-280. doi: 10.1016/j.nanoen.2015.05.034
27. [27]
  P.C. Shi, Y. Wang, X. Liang, et al., ACS Sustain. Chem. Eng. 6 (2018) 9661-9670. doi: 10.1021/acssuschemeng.8b00378
28. [28]
  C. Deng, Z.W. Wang, S.P. Wang, J.X. Yu, J. Mater. Chem. A 7 (2019) 12381-12413. doi: 10.1039/C9TA00535H
29. [29]
  Y.Y. Geng, Z.P. Ma, L. Su, et al., J. Alloys. Compd. 815 (2020) 152189. doi: 10.1016/j.jallcom.2019.152189
30. [30]
  M. Rana, M. Li, X. Huang, et al., J. Mater. Chem. A 7 (2019) 6596-6615. doi: 10.1039/C8TA12066H
31. [31]
  H.W. Wu, Y. Huang, W.C. Zhang, et al., J. Alloys. Compd. 708 (2017) 743-750. doi: 10.1016/j.jallcom.2017.03.047
32. [32]
  J.Q. Huang, T.Z. Zhuang, Q. Zhang, et al., ACS Nano 9 (2015) 3002-3011. doi: 10.1021/nn507178a
33. [33]
  Z.L. Xu, J.K. Kim, K. Kang, Nano Today 19 (2018) 84-107. doi: 10.1016/j.nantod.2018.02.006
34. [34]
  Q.P. Wu, X.J. Zhou, J. Xu, F.H. Cao, C.L. Li, J. Energy Chem. 38 (2019) 94-113. doi: 10.1016/j.jechem.2019.01.005
35. [35]
  Q.F. Zhang, Y.P. Wang, Z.W. Seh, et al., Nano Lett. 15 (2015) 3780-3786. doi: 10.1021/acs.nanolett.5b00367
36. [36]
  Y. Chen, S.T. Lu, J. Zhou, et al., J. Mater. Chem. A 5 (2017) 102-112. doi: 10.1039/C6TA08039A
37. [37]
  M. Zhao, H.J. Peng, B.Q. Li, et al., Angew. Chem. Int. Ed. 59 (2020) 9011-9017. doi: 10.1002/anie.202003136
38. [38]
  J. Xie, B.Q. Li, H.J. Peng, et al., Adv. Mater. 31 (2019) 1903813. doi: 10.1002/adma.201903813
39. [39]
  B.Q. Li, H.J. Peng, X. Chen, et al., CCS Chem. (2019) 128-137. doi: 10.31635/ccschem.019.20180016
40. [40]
  B.Q. Li, L. Kong, C.X. Zhao, et al., InfoMat 1 (2019) 533-541. doi: 10.1002/inf2.12056
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2. [2]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
3. [3]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
4. [4]
  Manoj Kumar Sarangi , L․D Patel , Goutam Rath , Sitansu Sekhar Nanda , Dong Kee Yi . Metal organic framework modulated nanozymes tailored with their biomedical approaches. Chinese Chemical Letters, 2024, 35(11): 109381-. doi: 10.1016/j.cclet.2023.109381
5. [5]
  Fangling Cui , Zongjie Hu , Jiayu Huang , Xiaoju Li , Ruihu Wang . MXene-based materials for separator modification of lithium-sulfur batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100337-100337. doi: 10.1016/j.cjsc.2024.100337
6. [6]
  Yu ZHANG , Fangfang ZHAO , Cong PAN , Peng WANG , Liangming WEI . Application of double-side modified separator with hollow carbon material in high-performance Li-S battery. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1218-1232. doi: 10.11862/CJIC.20230412
7. [7]
  Jun Jiang , Tong Guo , Wuxin Bai , Mingliang Liu , Shujun Liu , Zhijie Qi , Jingwen Sun , Shugang Pan , Aleksandr L. Vasiliev , Zhiyuan Ma , Xin Wang , Junwu Zhu , Yongsheng Fu . Modularized sulfur storage achieved by 100% space utilization host for high performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(4): 108565-. doi: 10.1016/j.cclet.2023.108565
8. [8]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
9. [9]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
10. [10]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
11. [11]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
12. [12]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
13. [13]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
14. [14]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
15. [15]
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16. [16]
  Ting Hu , Yuxuan Guo , Yixuan Meng , Ze Zhang , Ji Yu , Jianxin Cai , Zhenyu Yang . Uniform lithium deposition induced by copper phthalocyanine additive for durable lithium anode in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108603-. doi: 10.1016/j.cclet.2023.108603
17. [17]
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18. [18]
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19. [19]
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20. [20]
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通讯作者: 陈斌, bchen63@163.com

MOF-derived Co₉S₈ nano-flower cluster array modified separator towards superior lithium sulfur battery