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Citation: Yongqi Yu, Zhen Xia, Qianlong Wu, Da Liu, Lin Yu, Yuanjiu Xiao, Ze Tan, Wei Deng, Gangguo Zhu. Direct synthesis of benzoxazinones via Cp*Co(Ⅲ)-catalyzed C–H activation and annulation of sulfoxonium ylides with dioxazolones[J]. Chinese Chemical Letters, ;2021, 32(3): 1263-1266. doi: 10.1016/j.cclet.2020.09.020 shu

Direct synthesis of benzoxazinones via Cp*Co(Ⅲ)-catalyzed C–H activation and annulation of sulfoxonium ylides with dioxazolones

  • a.

    State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

  • b.

    Department of Chemistry, Zhejiang Normal University, Jinhua 321004, China

    * Corresponding authors.
    E-mail addresses: ztanze@gmail.com (Z. Tan), weideng@hnu.edu.cn (W. Deng).
  • Received Date: 19 July 2020
    Revised Date: 14 September 2020
    Accepted Date: 15 September 2020
    Available Online: 16 September 2020

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  • A highly novel and direct synthesis of benzoxazinones was developed via Cp*Co(Ⅲ)-catalyzed C–H activation and [3+3] annulation between sulfoxonium ylides and dioxazolones. The reaction is conducted under base-free conditions and tolerates various functional groups. Starting from diverse readily available sulfoxonium ylides and dioxazolones, a variety of benzoxazinones could be synthesized in one step in 32%-75% yields.
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