Citation: Tian Du, Biwen Wang, Chao Wang, Jianliang Xiao, Weijun Tang. Cobalt-catalyzed asymmetric hydrogenation of ketones: A remarkable additive effect on enantioselectivity[J]. Chinese Chemical Letters, ;2021, 32(3): 1241-1244. doi: 10.1016/j.cclet.2020.09.011 shu

Cobalt-catalyzed asymmetric hydrogenation of ketones: A remarkable additive effect on enantioselectivity

Tian Du ^a ,
Biwen Wang ^a ,
Chao Wang ^a ,
Jianliang Xiao ^b ,
Weijun Tang ^{a, *,}

a.
Key Laboratory of Applied Surface and Colloid Chemistry of Ministry of Education, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an 710062, China
b.
Department of Chemistry, University of Liverpool, Liverpool, L69 7ZD, UK

tangwj@snnu.edu.cn

Received Date: 31 July 2020
Revised Date: 22 August 2020
Accepted Date: 8 September 2020
Available Online: 10 September 2020

Figures(4)

A chiral cobalt pincer complex, when combined with an achiral electron-rich mono-phosphine ligand, catalyzes efficient asymmetric hydrogenation of a wide range of aryl ketones, affording chiral alcohols with high yields and moderate to excellent enantioselectivities (29 examples, up to 93% ee). Notably, the achiral mono-phosphine ligand shows a remarkable effect on the enantioselectivity of the reaction.
- Cobalt,
- Asymmetric hydrogenation,
- Ketones,
- Additive effect,
- Pincer complex
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