Citation: Lei Dai, Song Ye. Recent advances in N-heterocyclic carbene-catalyzed radical reactions[J]. Chinese Chemical Letters, ;2021, 32(2): 660-667. doi: 10.1016/j.cclet.2020.08.027 shu

Recent advances in N-heterocyclic carbene-catalyzed radical reactions

Lei Dai ^{a, b} ,
Song Ye ^{a, b, *,}

a.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China

songye@iccas.ac.cn

Received Date: 16 July 2020
Revised Date: 4 August 2020
Accepted Date: 17 August 2020
Available Online: 19 August 2020

Figures(27)

The N-heterocyclic carbene (NHC)-catalyzed reactions involving two-electron reaction pathway have been well-established. However, the development of NHC-catalyzed radical reactions is still in its infancy in terms of reaction types and enantioselectivity. In the past decade, several elegant NHC-catalyzed radical reactions have been developed, including NHC-catalyzed oxidation of aldehydes to esters, reductive coupling reactions using Breslow intermediate as SET reductant and NHC-catalyzed reactions via radical homoenolates, dienoaltes and trienolates. This review summarizes the recent advances in NHC-catalyzed reactions involving radical intermediates.
- N-Heterocyclic carbene,
- Radical,
- Photocatalysis,
- Organocatalysis,
- SET
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