Citation: Du Mengmeng, Yi Qiuying, Ji Jiahui, Zhu Qiaohong, Duan Huan, Xing Mingyang, Zhang Jinlong. Sustainable activation of peroxymonosulfate by the Mo(IV) in MoS₂ for the remediation of aromatic organic pollutants[J]. Chinese Chemical Letters, ;2020, 31(10): 2803-2808. doi: 10.1016/j.cclet.2020.08.002 shu

Sustainable activation of peroxymonosulfate by the Mo(IV) in MoS₂ for the remediation of aromatic organic pollutants

Du Mengmeng ^a,1 ,
Yi Qiuying ^a,1 ,
Ji Jiahui ^a ,
Zhu Qiaohong ^a ,
Duan Huan ^b ,
Xing Mingyang ^a,*, ,
Zhang Jinlong ^a,*,

a.
Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, Key Laboratory for Advanced Materials and Institute of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science & Technology, Shanghai 200237, China
b.
School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China

mingyangxing@ecust.edu.cn

jlzhang@ecust.edu.cn

Received Date: 29 May 2020
Revised Date: 13 July 2020
Accepted Date: 4 August 2020
Available Online: 7 August 2020

Figures(4)

Although MoS₂ has been proved to be a very ideal cocatalyst in advanced oxidation process (AOPs), the activation process of peroxymonosulfate (PMS) is still inseparable from metal ions which inevitably brings the risk of secondary pollution and it is not conducive to large-scale industrial application. In this study, the commercial MoS₂, as a durable and efficient catalyst, was used for directly activating PMS to degrade aromatic organic pollutant. The commercial MoS₂/PMS catalytic system demonstrated excellent removal efficiency of phenol and the total organic carbon (TOC) residual rate reach to 25%. The degradation rate was significantly reduced if the used MoS₂ was directly carried out the next cycle experiment without any post-treatment. Interestingly, the commercial MoS₂ after post-treated with H₂O₂ can exhibit good stability and recyclability for cyclic degradation of phenol. Furthermore, the mechanism for the activation of PMS had been investigated by density functional theory (DFT) calculation. The renewable Mo⁴⁺ exposed on the surface of MoS₂ was deduced as the primary active site, which realized the direct activation of PMS and avoided secondary pollution. Taking into account the reaction cost and efficient activity, the development of commercial MoS₂ catalytic system is expected to be applied in industrial wastewater.
- Peroxymoosulfate,
- Molybdenum disulfide,
- Surface reaction,
- Recyclability,
- Sulfur vacancies,
- Density functional theory
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沈阳化工大学材料科学与工程学院沈阳 110142

Sustainable activation of peroxymonosulfate by the Mo(IV) in MoS2 for the remediation of aromatic organic pollutants

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通讯作者: 陈斌, bchen63@163.com

Sustainable activation of peroxymonosulfate by the Mo(IV) in MoS₂ for the remediation of aromatic organic pollutants