Citation: Qin Li, Jin Niu, Meiling Dou, Zhengping Zhang, Feng Wang. Porous microtubes of nickel-cobalt double oxides as non-enzymatic hydrogen peroxide sensors[J]. Chinese Chemical Letters, ;2021, 32(3): 1181-1185. doi: 10.1016/j.cclet.2020.07.045 shu

Porous microtubes of nickel-cobalt double oxides as non-enzymatic hydrogen peroxide sensors

Qin Li ^{a, b} ,
Jin Niu ^{a, b} ,
Meiling Dou ^{a, b} ,
Zhengping Zhang ^{a, b, *,} ,
Feng Wang ^{a, b, *,}

a.
State Key Laboratory of Chemical Resource Engineering, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China
b.
Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

zhangzhengping@mail.buct.edu.cn

wangf@mail.buct.edu.cn

Received Date: 15 May 2020
Revised Date: 10 June 2020
Accepted Date: 26 July 2020
Available Online: 29 July 2020

Figures(5)

Non-enzymatic electrochemical sensors for the determination of hydrogen peroxide (H₂O₂) have attracted more and more concerns. A series of nickel and cobalt double oxides (Ni_xCo_y-DO) with the different ratios of Ni/Co have been prepared by a polyol-mediated solvothermal method for H₂O₂ detection. The obtained products exhibit honeycomb-like open porous microtubes constituted with the low-dimensional nanostructured Ni_xCo_y-DO blocks after the calcination treatment. Compared with nickel oxides, the introduced Co ions in Ni_xCo_y-DO can induce the production of surficial oxygen vacancies, and further enhance the electrode surface activity. In particular, the NiCo-DO sample (with an atomic ratio of Ni/Co = 4:3) shows the richest surficial oxygen vacancies and presents the highest H₂O₂ detection activity among all the as-prepared samples, demonstrating an excellent sensitivity of 698.60 μA L mmol^-1 cm^-2 (0 ~ 0.4 mmol/L), low detection limit (0.28 μmol/L, S/N = 3), as well as long stability, high selectivity and good reproducibility. This work lends a new impetus to the potential application of double metal oxides for the next generation of non-enzymatic sensors.
- Double metal oxides,
- Porous microtubes,
- Oxygen vacancies,
- Hydrogen peroxide detection,
- Electrochemical sensors
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