Citation: Wei-Chao Xing, Ji-Min An, Jing Lv, Faisal Irshad, Yu-Jun Zhao, Sheng-Ping Wang, Xin-Bin Ma. Highly active Pd-Fe/α-Al₂O₃ catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate[J]. Chinese Chemical Letters, ;2021, 32(2): 796-800. doi: 10.1016/j.cclet.2020.07.038 shu

Highly active Pd-Fe/α-Al₂O₃ catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate

Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

muddylj@tju.edu.cn

spwang@tju.edu.cn

Received Date: 19 May 2020
Revised Date: 23 June 2020
Accepted Date: 24 July 2020
Available Online: 25 July 2020

Figures(5)

A novel Pd-Fe/α-Al₂O₃ catalyst was synthesized by incipient-wetness impregnation method with bayberry tannin as chelating promoter and commercial hollow column Raschig ring α-Al₂O₃ as support for the synthesis of diethyl oxalate from CO and ethyl nitrite. A variety of characterization techniques including N₂ physical adsorption, optical microscopy, scanning electron microscopy and energy dispersive system (SEM-EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), were employed to explore the relationship between the physicochemical properties and activity of catalysts. It indicated that a large number of phenolic hydroxyl groups in bayberry tannin can efficiently anchor the active component Pd, reduce the particle size and make the active Pd as a multi-ring distribution on the commercial α-Al₂O₃ support, which were beneficial to improve the catalytic activity for the production of diethyl oxalate from CO and ethyl nitrite. 0.3 wt% Pd-Fe/α-Al₂O₃ showed excellent catalytic activity and selectivity in a continuous flow, fixed-bed reactor with the loading amount of 10 mL catalysts. Under the mild reaction conditions, the space-time yield of diethyl oxalate was 978 g L^-1 h^-1 and CO conversion was 44% with the selectivity to diethyl oxalate of 95.5%.
- Bayberry tannin,
- Diethyl oxalate,
- Phenolic hydroxyl groups,
- Ethyl nitrite,
- Pd-Fe/α-Al₂O₃
1. [1]
  H.Y. Song, R.H. Jin, M. Kang, et al., Chin. J. Catal. 34 (2013) 1035-1050. doi: 10.1016/S1872-2067(12)60529-4
2. [2]
  B.Y. Yu, I.L. Chien, Chem. Eng. Res. Des. 121 (2017) 173-190. doi: 10.1016/j.cherd.2017.03.012
3. [3]
  Y.T. Liu, J. Ding, J.Y. Yang, et al., Catal. Commun. 98 (2017) 43-46. doi: 10.1016/j.catcom.2017.05.007
4. [4]
  Y.J. Zhao, H.H. Zhang, Y. Xu, et al., J. Energy Chem. 49 (2020) 148-256.
5. [5]
  X.B. Yu, T.A. Vest, N.G. Boure, et al., J. Catal. 380 (2019) 289-296. doi: 10.1016/j.jcat.2019.10.001
6. [6]
  C.C. Zhang, F. Yu, B. Dai, et al., Catal. Commun. 102 (2017) 31-34. doi: 10.1016/j.catcom.2017.06.042
7. [7]
  J. Ding, T. Popa, J. Tang, et al., Appl. Catal. B: Environ. 209 (2017) 530-542. doi: 10.1016/j.apcatb.2017.02.072
8. [8]
  J. Ding, M.H. Fang, Q. Zhong, et al., Appl. Catal. B: Environ. 232 (2018) 348-354. doi: 10.1016/j.apcatb.2018.03.058
9. [9]
  D. M. Fenton, P. J. Steinwand, PCT/US1967/3393136, 1967.
10. [10]
  H. Miyazaki, Y. Shiomi, S. Fujitus et al., PCT/US1983/4410722, 1983.
11. [11]
  S.Y. Peng, Z.N. Xu, Q.S. Chen, et al., ACS Catal. 5 (2015) 4410-4417. doi: 10.1021/acscatal.5b00365
12. [12]
  S. Peng, Z. Xu, Q. Chen, et al., Chem. Commun. 49 (2013) 5718-5720. doi: 10.1039/c3cc00219e
13. [13]
  E. Leino, N. Kumar, P. Arvela, et al., Catal. Today 306 (2018) 128-137. doi: 10.1016/j.cattod.2017.01.016
14. [14]
  G. Zhang, D. Zhao, J. Yan, et al., Appl. Catal. A: Gen. 579 (2019) 18-29. doi: 10.1016/j.apcata.2019.04.012
15. [15]
  C. Murugan, H.C. Bajaj, Fuel Process. Technol. 92 (2011) 77-82. doi: 10.1016/j.fuproc.2010.08.023
16. [16]
  X. Gao, Y. Zhao, S. Wang, et al., Chem. Eng. Sci. 66 (2011) 3513-3522. doi: 10.1016/j.ces.2011.04.012
17. [17]
  X. Jiang, Y. Su, B. Lee, et al., Appl. Catal. A: Gen. 211 (2001) 47-51. doi: 10.1016/S0926-860X(00)00837-1
18. [18]
  X. Huang, H. Mao, X. Liao, et al., Catal. Commun. 12 (2011) 1000-1004. doi: 10.1016/j.catcom.2011.03.008
19. [19]
  H. Bai, X. Fang, C. Peng, ACS Sustain. Chem. Eng. 7 (2019) 7700-7707.
20. [20]
  X. Zou, Z. Rui, H. Ji, ACS Catal. 7 (2017) 1615-1625. doi: 10.1021/acscatal.6b03105
21. [21]
  Y. Xiang, X. Li, C. Lu, et al., Appl. Catal. A: Gen. 375 (2010) 289-294. doi: 10.1016/j.apcata.2010.01.004
22. [22]
  J.F. Yang, S.S. Li, L.L. Zhang, et al., Appl. Catal. B: Environ. 201 (2017) 266-277. doi: 10.1016/j.apcatb.2016.08.045
23. [23]
  I. Khalilov, I. Ilyasov, V. Shatilov, et al., Catal. Use Indium 5 (2013) 318-326. doi: 10.1134/S2070050413040053
24. [24]
  W. Yu, M.D. Porosoff, J.G. Chen, Chem. Rev. 112 (2012) 5780-5817. doi: 10.1021/cr300096b
25. [25]
  M. Lesiak, M. Binczarski, S. Karski, et al., J. Mol. Catal. A: Chem. 395 (2014)337-348. doi: 10.1016/j.molcata.2014.08.041
26. [26]
  X. Feng, L. Ling, Y. Cao, et al., J. Phys. Chem. C 122 (2018) 1169-1179.
27. [27]
  Z.H. Gao, Z.C. Liu, F. He, et al., J. Mole. Catal. A: Chem. 235 (2005) 143-149. doi: 10.1016/j.molcata.2005.03.003
1. [1]
  Hongwei Ding , Jingjing Yang , Yongchen Shuai , Di Wei , Xueliang Liu , Guiying Li , Lin Jin , Jianliang Shen . In situ preparation of tannin-mediated CeO₂@CuS nanocomposites for multimodal wound therapy. Chinese Chemical Letters, 2025, 36(6): 110286-. doi: 10.1016/j.cclet.2024.110286
2. [2]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
3. [3]
  Xiaorui Chen , Xuan Luo , Tongming Su , Xinling Xie , Liuyun Chen , Yuejing Bin , Zuzeng Qin , Hongbing Ji . Ga-doped Cu/γ-Al₂O₃ bifunctional interface sites promote the direct hydrogenation of CO₂ to DME. Acta Physico-Chimica Sinica, 2025, 41(10): 100126-0. doi: 10.1016/j.actphy.2025.100126
4. [4]
  Jiang Gong , Fengling Zheng , Hanqing Zhang , Weihan Shu , Hao Wang , Ni Zhang , Pengbing Huang , Chuancai Zhang , Bin Dai . The interfacial effect of SiO₂-Ni₃Mo₃N efficiently catalyzes the low-temperature hydrogenation of dimethyl oxalate to ethanol. Chinese Chemical Letters, 2025, 36(8): 111122-. doi: 10.1016/j.cclet.2025.111122
5. [5]
  Haotian Zhang , Shengfa Feng , Mufan Cao , Xiong Xiong Liu , Pengcheng Yuan , Yaping Wang , Min Gao , Long Pan , Zhengming Sun . Al₂O₃ coated polyimide porous films enable thin yet strong polymer-in-salt solid-state electrolytes for dendrite-free lithium metal batteries. Chinese Chemical Letters, 2025, 36(8): 111096-. doi: 10.1016/j.cclet.2025.111096
6. [6]
  Ze-Yuan Ma , Mei Xiao , Cheng-Kun Li , Adedamola Shoberu , Jian-Ping Zou . S-(1,3-Dioxoisoindolin-2-yl)O,O-diethyl phosphorothioate (SDDP): A practical electrophilic reagent for the phosphorothiolation of electron-rich compounds. Chinese Chemical Letters, 2024, 35(5): 109076-. doi: 10.1016/j.cclet.2023.109076
7. [7]
  Jingtai Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation. Chinese Chemical Letters, 2024, 35(11): 109639-. doi: 10.1016/j.cclet.2024.109639
8. [8]
  Simin Wei , Yaqing Yang , Junjie Li , Jialin Wang , Jinlu Tang , Ningning Wang , Zhaohui Li . The Mn/Yb/Er triple-doped CeO₂ nanozyme with enhanced oxidase-like activity for highly sensitive ratiometric detection of nitrite. Chinese Chemical Letters, 2024, 35(6): 109114-. doi: 10.1016/j.cclet.2023.109114
9. [9]
  Xiao Xiao , Biao Chen , Jia-Wei Li , Jun-Bo Zheng , Xu Wang , Hang Zhao , Fen-Er Chen . Nitrite-catalyzed economic and sustainable bromocyclization of tryptamines/tryptophols to access hexahydropyrrolo[2,3-b]indoles/tetrahydrofuroindolines in batch and flow. Chinese Chemical Letters, 2024, 35(7): 109280-. doi: 10.1016/j.cclet.2023.109280
10. [10]
  Sikai Wu , Xuefei Wang , Huogen Yu . Hydroxyl-enriched hydrous tin dioxide-coated BiVO4 with boosted photocatalytic H2O2 production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100457-100457. doi: 10.1016/j.cjsc.2024.100457
11. [11]
  Gang Lang , Jing Feng , Bo Feng , Junlan Hu , Zhiling Ran , Zhiting Zhou , Zhenju Jiang , Yunxiang He , Junling Guo . Supramolecular phenolic network-engineered C–CeO₂ nanofibers for simultaneous determination of isoniazid and hydrazine in biological fluids. Chinese Chemical Letters, 2024, 35(6): 109113-. doi: 10.1016/j.cclet.2023.109113
12. [12]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
13. [13]
  Jingtao Bi , Yupeng Cheng , Mengmeng Sun , Xiaofu Guo , Shizhao Wang , Yingying Zhao . Corrigendum to “Efficient and selective photocatalytic nitrite reduction to N₂ through CO₂ anion radical by eco-friendly tartaric acid activation” [Chinese Chemical Letters 35 (2024) 109639]. Chinese Chemical Letters, 2025, 36(7): 110867-. doi: 10.1016/j.cclet.2025.110867
14. [14]
  Huan Ye , Ying Yang , Lirong Jiang , Taotao Zhe , Junchao Xu , Lintao Zeng . An intelligent sensing platform for discrimination of formaldehyde and nitrite in food. Chinese Chemical Letters, 2025, 36(11): 110840-. doi: 10.1016/j.cclet.2025.110840
15. [15]
  Hui-Xian Jiang , Zhi-Tao Liu , Pei Xu , Xu Zhu . Synthetic application of oxalate salts for visible-light-induced radical transformations. Chinese Chemical Letters, 2025, 36(12): 111224-. doi: 10.1016/j.cclet.2025.111224
16. [16]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
17. [17]
  Beitong Zhu , Xiaorui Yang , Lirong Jiang , Tianhong Chen , Shuangfei Wang , Lintao Zeng . A portable and versatile fluorescent platform for high-throughput screening of toxic phosgene, diethyl chlorophosphate and volatile acyl chlorides. Chinese Chemical Letters, 2025, 36(1): 110222-. doi: 10.1016/j.cclet.2024.110222
18. [18]
  Chengkai Li , Guoqiang Fan , Gang Zheng , Rong Gao , Li Liu . Groups 3 and 4 single-site catalysts for olefin-polar monomer copolymerization. Chinese Chemical Letters, 2025, 36(9): 111297-. doi: 10.1016/j.cclet.2025.111297
19. [19]
  Shuhao FENG , Feibing XIONG , Yaqing LIN , Han SU , Xu HAN . Preparation and luminescent properties of alkaline metal doped Cd₃Al₂Ge₃O₁₂: Pr³⁺ orange phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 284-296. doi: 10.11862/CJIC.20250171
20. [20]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(2192)
HTML views(220)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Highly active Pd-Fe/α-Al2O3 catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate

Metrics

通讯作者: 陈斌, bchen63@163.com

Highly active Pd-Fe/α-Al₂O₃ catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate