Citation: Wei-Chao Xing, Ji-Min An, Jing Lv, Faisal Irshad, Yu-Jun Zhao, Sheng-Ping Wang, Xin-Bin Ma. Highly active Pd-Fe/α-Al₂O₃ catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate[J]. Chinese Chemical Letters, ;2021, 32(2): 796-800. doi: 10.1016/j.cclet.2020.07.038 shu

Highly active Pd-Fe/α-Al₂O₃ catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate

Key Laboratory for Green Chemical Technology, School of Chemical Engineering and Technology, Tianjin University, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China

muddylj@tju.edu.cn

spwang@tju.edu.cn

Received Date: 19 May 2020
Revised Date: 23 June 2020
Accepted Date: 24 July 2020
Available Online: 25 July 2020

Figures(5)

A novel Pd-Fe/α-Al₂O₃ catalyst was synthesized by incipient-wetness impregnation method with bayberry tannin as chelating promoter and commercial hollow column Raschig ring α-Al₂O₃ as support for the synthesis of diethyl oxalate from CO and ethyl nitrite. A variety of characterization techniques including N₂ physical adsorption, optical microscopy, scanning electron microscopy and energy dispersive system (SEM-EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), were employed to explore the relationship between the physicochemical properties and activity of catalysts. It indicated that a large number of phenolic hydroxyl groups in bayberry tannin can efficiently anchor the active component Pd, reduce the particle size and make the active Pd as a multi-ring distribution on the commercial α-Al₂O₃ support, which were beneficial to improve the catalytic activity for the production of diethyl oxalate from CO and ethyl nitrite. 0.3 wt% Pd-Fe/α-Al₂O₃ showed excellent catalytic activity and selectivity in a continuous flow, fixed-bed reactor with the loading amount of 10 mL catalysts. Under the mild reaction conditions, the space-time yield of diethyl oxalate was 978 g L^-1 h^-1 and CO conversion was 44% with the selectivity to diethyl oxalate of 95.5%.
- Bayberry tannin,
- Diethyl oxalate,
- Phenolic hydroxyl groups,
- Ethyl nitrite,
- Pd-Fe/α-Al₂O₃
1. [1]
  H.Y. Song, R.H. Jin, M. Kang, et al., Chin. J. Catal. 34 (2013) 1035-1050. doi: 10.1016/S1872-2067(12)60529-4
2. [2]
  B.Y. Yu, I.L. Chien, Chem. Eng. Res. Des. 121 (2017) 173-190. doi: 10.1016/j.cherd.2017.03.012
3. [3]
  Y.T. Liu, J. Ding, J.Y. Yang, et al., Catal. Commun. 98 (2017) 43-46. doi: 10.1016/j.catcom.2017.05.007
4. [4]
  Y.J. Zhao, H.H. Zhang, Y. Xu, et al., J. Energy Chem. 49 (2020) 148-256.
5. [5]
  X.B. Yu, T.A. Vest, N.G. Boure, et al., J. Catal. 380 (2019) 289-296. doi: 10.1016/j.jcat.2019.10.001
6. [6]
  C.C. Zhang, F. Yu, B. Dai, et al., Catal. Commun. 102 (2017) 31-34. doi: 10.1016/j.catcom.2017.06.042
7. [7]
  J. Ding, T. Popa, J. Tang, et al., Appl. Catal. B: Environ. 209 (2017) 530-542. doi: 10.1016/j.apcatb.2017.02.072
8. [8]
  J. Ding, M.H. Fang, Q. Zhong, et al., Appl. Catal. B: Environ. 232 (2018) 348-354. doi: 10.1016/j.apcatb.2018.03.058
9. [9]
  D. M. Fenton, P. J. Steinwand, PCT/US1967/3393136, 1967.
10. [10]
  H. Miyazaki, Y. Shiomi, S. Fujitus et al., PCT/US1983/4410722, 1983.
11. [11]
  S.Y. Peng, Z.N. Xu, Q.S. Chen, et al., ACS Catal. 5 (2015) 4410-4417. doi: 10.1021/acscatal.5b00365
12. [12]
  S. Peng, Z. Xu, Q. Chen, et al., Chem. Commun. 49 (2013) 5718-5720. doi: 10.1039/c3cc00219e
13. [13]
  E. Leino, N. Kumar, P. Arvela, et al., Catal. Today 306 (2018) 128-137. doi: 10.1016/j.cattod.2017.01.016
14. [14]
  G. Zhang, D. Zhao, J. Yan, et al., Appl. Catal. A: Gen. 579 (2019) 18-29. doi: 10.1016/j.apcata.2019.04.012
15. [15]
  C. Murugan, H.C. Bajaj, Fuel Process. Technol. 92 (2011) 77-82. doi: 10.1016/j.fuproc.2010.08.023
16. [16]
  X. Gao, Y. Zhao, S. Wang, et al., Chem. Eng. Sci. 66 (2011) 3513-3522. doi: 10.1016/j.ces.2011.04.012
17. [17]
  X. Jiang, Y. Su, B. Lee, et al., Appl. Catal. A: Gen. 211 (2001) 47-51. doi: 10.1016/S0926-860X(00)00837-1
18. [18]
  X. Huang, H. Mao, X. Liao, et al., Catal. Commun. 12 (2011) 1000-1004. doi: 10.1016/j.catcom.2011.03.008
19. [19]
  H. Bai, X. Fang, C. Peng, ACS Sustain. Chem. Eng. 7 (2019) 7700-7707.
20. [20]
  X. Zou, Z. Rui, H. Ji, ACS Catal. 7 (2017) 1615-1625. doi: 10.1021/acscatal.6b03105
21. [21]
  Y. Xiang, X. Li, C. Lu, et al., Appl. Catal. A: Gen. 375 (2010) 289-294. doi: 10.1016/j.apcata.2010.01.004
22. [22]
  J.F. Yang, S.S. Li, L.L. Zhang, et al., Appl. Catal. B: Environ. 201 (2017) 266-277. doi: 10.1016/j.apcatb.2016.08.045
23. [23]
  I. Khalilov, I. Ilyasov, V. Shatilov, et al., Catal. Use Indium 5 (2013) 318-326. doi: 10.1134/S2070050413040053
24. [24]
  W. Yu, M.D. Porosoff, J.G. Chen, Chem. Rev. 112 (2012) 5780-5817. doi: 10.1021/cr300096b
25. [25]
  M. Lesiak, M. Binczarski, S. Karski, et al., J. Mol. Catal. A: Chem. 395 (2014)337-348. doi: 10.1016/j.molcata.2014.08.041
26. [26]
  X. Feng, L. Ling, Y. Cao, et al., J. Phys. Chem. C 122 (2018) 1169-1179.
27. [27]
  Z.H. Gao, Z.C. Liu, F. He, et al., J. Mole. Catal. A: Chem. 235 (2005) 143-149. doi: 10.1016/j.molcata.2005.03.003
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Highly active Pd-Fe/α-Al2O3 catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate

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通讯作者: 陈斌, bchen63@163.com

Highly active Pd-Fe/α-Al₂O₃ catalyst with the bayberry tannin as chelating promoter for CO oxidative coupling to diethyl oxalate