Citation: Tian Bai, Kongyin Zhao, Zijie Lu, Xuefang Liu, Ze Lin, Mengmeng Cheng, Ziyi Li, Dunwan Zhu, Linhua Zhang. Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties[J]. Chinese Chemical Letters, ;2021, 32(3): 1051-1054. doi: 10.1016/j.cclet.2020.07.034 shu

Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties

Tian Bai ^a ,
Kongyin Zhao ^{a, *,} ,
Zijie Lu ^a ,
Xuefang Liu ^a ,
Ze Lin ^a ,
Mengmeng Cheng ^a ,
Ziyi Li ^a ,
Dunwan Zhu ^b ,
Linhua Zhang ^b

a.
State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
b.
Tianjin Key Laboratory of Biomedical Materials, Key Laboratory of Biomaterials and Nanotechnology for Cancer Immunotherapy, Institute of Biomedical Engineering, Chinese Academy of Medical Sciences & Peking Union Medical College, Tianjin 300192, China

Received Date: 11 May 2020
Revised Date: 16 July 2020
Accepted Date: 17 July 2020
Available Online: 18 July 2020

Figures(4)

Herein, copper ion doped calcium alginate (Cu²⁺/CaAlg) composite hydrogel filtration membranes were prepared by using natural polymer sodium alginate (NaAlg) as raw material. The thermal stability and structure of the composite membranes were characterized by thermogravimetric analysis and infrared spectroscopy. The mechanical strength, anti-fouling performance, hydrophilicity and filtration performance of the membrane were studied. The results show that Cu²⁺/CaAlg hydrogel membrane has excellent mechanical properties and thermal stability. The anti-swelling ability of the membrane was greatly enhanced by doping Cu²⁺. After three alternate filtration cycles, the flux recovery rate of Cu²⁺/CaAlg hydrogel membrane can still reach 85%, indicating that the membrane has good anti-pollution performance. When the operation pressure was 0.1 MPa, the rejection of coomassie brilliant blue G250 reached 99.8% with a flux of 46.3 L m^-2 h^-1, while the Na₂SO₄ rejectionwas less than 10.0%. The Cu²⁺/CaAlg membrane was recycled after 24 h in the filtration process, and its flux and rejection rate did not decrease significantly, indicating that the hydrogel membrane has long-term application potential. The Cu²⁺/CaAlg membrane has a wide range of applications prospect in dye desalination, fine separation and biopharmaceutical technology fields.
- Calcium alginate,
- Cu²⁺ doped,
- Hydrogel,
- Filtration membrane,
- Antibacterial,
- Anti-fouling
1. [1]
  X. Wang, Y. Pan, H. Yuan, et al., Chin. Chem. Lett. 31(2020) 365-368. doi: 10.1016/j.cclet.2019.07.044
2. [2]
  J. Shan, W. Wei, D. Yonghong, et al., Chin. Chem. Lett. 29(2018) 390-394. doi: 10.1016/j.cclet.2018.01.006
3. [3]
  S. Yuan, G. Zhang, J. Zhu, J. Mater. Chem. A 8(2020) 3238-3245. doi: 10.1039/C9TA12984G
4. [4]
  Q. Nie, F. Ran, C. He, et al., Chin. Chem. Lett. 22(2011) 370-373. doi: 10.1016/j.cclet.2010.10.017
5. [5]
  J. Guo, K. Zhao, X. Zhang, et al., Mater. Lett. 157(2015) 112-115. doi: 10.1016/j.matlet.2015.05.080
6. [6]
  J. Li, S. Li, X. Wang, et al., Chin. Chem. Lett. 30(2019) 239-242. doi: 10.1016/j.cclet.2018.07.016
7. [7]
  J. Zhu, M. Tian, J. Hou, et al., J. Mater. Chem. A 4(2016) 1980-1990. doi: 10.1039/C5TA08024J
8. [8]
  S. Gao, Y. Zhu, Y. Gong, et al., ACS Nano 13(2019) 5278-5290. doi: 10.1021/acsnano.8b09761
9. [9]
  P. Zhong, N. Widjojo, T. Chung, et al., J. Membr. Sci. 417(2012) 52-60.
10. [10]
  J.H. Jhaveri, Z.V.P. Murthy, Desalination 379(2016) 137-154. doi: 10.1016/j.desal.2015.11.009
11. [11]
  M. Min, Y. Liu, C. Song, et al., ACS Appl. Mater. Inter. 10(2018) 21246-21253. doi: 10.1021/acsami.8b03411
12. [12]
  X. Deng, N. Chao, W. Ding, et al., J. Biomed. Nanotechnol. 15(2019) 756-768. doi: 10.1166/jbn.2019.2713
13. [13]
  Y. Cai, J. Zhang, Y. He, et al., Int. J. Biomed. Nanotechnol. 14(2018) 257-266. doi: 10.1166/jbn.2018.2483
14. [14]
  S. Gao, S.Y. Zhu, J. Wang, et al., Adv. Funct. Mater. 28(2018) 1801944. doi: 10.1002/adfm.201801944
15. [15]
  E.G. Deze, S.K. Papageorgiou, E.P. Favvas, et al., Chem. Eng. J. 209(2012) 537-546. doi: 10.1016/j.cej.2012.07.133
16. [16]
  K. Zhao, X. Zhang, J. Wei, et al., J. Membr. Sci. 492(2015) 536-546. doi: 10.1016/j.memsci.2015.05.075
17. [17]
  Y.N. Mata, M.L. Blázquez, A. Ballester, et al., J. Hazard. Mater. 163(2009) 555-562. doi: 10.1016/j.jhazmat.2008.07.015
18. [18]
  L.D. Nghiem, A.I. Schäfer, M. Elimelech, et al., J. Membr. Sci. 286(2006) 52-59. doi: 10.1016/j.memsci.2006.09.011
19. [19]
  W. Ye, K. Ye, F. Lin, et al., Chem. Eng. J. 379(2020) 122321. doi: 10.1016/j.cej.2019.122321
20. [20]
  N. Wang, X. Li, L. Wang, et al., ACS Appl. Mater. Interfaces 8(2016) 21979-21983. doi: 10.1021/acsami.6b08581
1. [1]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
2. [2]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
3. [3]
  Xicheng Li , Dong Mo , Shoushan Hu , Meng Pan , Meng Wang , Tingyu Yang , Changxing Qu , Yujia Wei , Jianan Li , Hanzhi Deng , Zhongwu Bei , Tianying Luo , Qingya Liu , Yun Yang , Jun Liu , Jun Wang , Zhiyong Qian . A Pt@ZIF-8/ALN-ac/GelMA composite hydrogel with antibacterial, antioxidant, and osteogenesis for periodontitis. Chinese Chemical Letters, 2025, 36(9): 110674-. doi: 10.1016/j.cclet.2024.110674
4. [4]
  Ruijun Song , Huixu Xie , Guiting Liu . Advances of MXene-based hydrogels for chronic wound healing. Chinese Chemical Letters, 2025, 36(7): 110442-. doi: 10.1016/j.cclet.2024.110442
5. [5]
  Zhiqi Hu , Lingling Wu , Duo Zhang , Yixue An , Jiao Wang , Binbin Zhao , Robert Chunhua Zhao , Rong Cao , Xue Yang . Ultrathin transparent metal-organic framework-based nanocomposite membranes for antibacterial wound healing. Chinese Journal of Structural Chemistry, 2025, 44(12): 100749-100749. doi: 10.1016/j.cjsc.2025.100749
6. [6]
  Xiangrong Pan , Xixi Hou , Yuhang Du , Zhixin Pang , Shiyang He , Lan Wang , Jianxue Yang , Longfei Mao , Jianhua Qin , Haixia Wu , Baozhong Liu , Zhan Zhou , Lufang Ma , Chaoliang Tan . Solvent-mediated synthesis of 2D In-TCPP MOF nanosheets for enhanced photodynamic antibacterial therapy. Chinese Chemical Letters, 2025, 36(12): 110536-. doi: 10.1016/j.cclet.2024.110536
7. [7]
  Xiaoyu Hou , Mingyang Liu , Hu Wu , Nan Wang , Xu Zhao , Xifeng Qin , Xiaomin Su , Hanwei Huang , Zihan Ma , Jiahao Liu , Onder Ergonul , Füsun Can , Wei Liu , Zhiqing Pang , Funan Liu . Differential releasing hydrogel loaded with oncolytic viruses and anti-CAFs drug to enhance oncology therapeutic efficacy. Chinese Chemical Letters, 2025, 36(5): 110106-. doi: 10.1016/j.cclet.2024.110106
8. [8]
  Lina Xie , Xiaohe Zhang , Xiaobo Wang , Zhen Zhang , Tianqi Nie , Jun Wu , Xiaojun Xu . Multifunctional GelMA hydrogel doped with spermidine-ferrocene polymeric nanoparticles for accelerative diabetic wound healing. Chinese Chemical Letters, 2025, 36(11): 110848-. doi: 10.1016/j.cclet.2025.110848
9. [9]
  Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518
10. [10]
  Xiaoliu Liang , Chunliu Huang , Hui Liu , Hu Chen , Jiabao Shou , Hongwei Cheng , Gang Liu . Natural hydrogel dressings in wound care: Design, advances, and perspectives. Chinese Chemical Letters, 2024, 35(10): 109442-. doi: 10.1016/j.cclet.2023.109442
11. [11]
  Haijun Shen , Yi Qiao , Chun Zhang , Yane Ma , Jialing Chen , Yingying Cao , Wenna Zheng . A matrix metalloproteinase-sensitive hydrogel combined with photothermal therapy for transdermal delivery of deferoxamine to accelerate diabetic pressure ulcer healing. Chinese Chemical Letters, 2024, 35(12): 110283-. doi: 10.1016/j.cclet.2024.110283
12. [12]
  Yuyao Guan , Baoting Yu , Jun Ding , Tingting Sun , Zhigang Xie . BODIPY photosensitizers for antibacterial photodynamic therapy. Chinese Chemical Letters, 2025, 36(8): 110645-. doi: 10.1016/j.cclet.2024.110645
13. [13]
  Hongwei Ding , Jingjing Yang , Yongchen Shuai , Di Wei , Xueliang Liu , Guiying Li , Lin Jin , Jianliang Shen . In situ preparation of tannin-mediated CeO₂@CuS nanocomposites for multimodal wound therapy. Chinese Chemical Letters, 2025, 36(6): 110286-. doi: 10.1016/j.cclet.2024.110286
14. [14]
  Shaobo Wang , Honggui Yang , Chunni Zhao , Deyu Hu , Baoan Song . Antibacterial agrochemicals: Recent research progress and outlook. Chinese Chemical Letters, 2026, 37(1): 111543-. doi: 10.1016/j.cclet.2025.111543
15. [15]
  Xi Chen , Xue Zhang , Shuai Yang , Jie Wang , Tian Tang , Maling Gou . An adhesive hydrogel for the treatment of oral ulcers. Chinese Chemical Letters, 2025, 36(3): 110021-. doi: 10.1016/j.cclet.2024.110021
16. [16]
  Yue Ren , Kang Li , Yi-Zi Wang , Shao-Peng Zhao , Shu-Min Pan , Haojie Fu , Mengfan Jing , Yaming Wang , Fengyuan Yang , Chuntai Liu . Swelling and erosion assisted sustained release of tea polyphenol from antibacterial ultrahigh molecular weight polyethylene for joint replacement. Chinese Chemical Letters, 2025, 36(2): 110468-. doi: 10.1016/j.cclet.2024.110468
17. [17]
  Mengyao Gao , Shan Sun , Hengwei Lin , Cheng Yang . A multifunctional carbon dot-based nanoplatform for antibacterial therapy: Integrating photodynamic, photothermal, and gas treatments. Chinese Chemical Letters, 2026, 37(2): 111055-. doi: 10.1016/j.cclet.2025.111055
18. [18]
  Zhuan Chen , Bo Yang , Jun Li , Kun Du , Jiangchen Fu , Xiao Wu , Jiazhen Cao , Mingyang Xing . Environmentally safe storage and sustained release of hydrogen peroxide utilizing commercial hydrogel. Chinese Chemical Letters, 2025, 36(6): 110320-. doi: 10.1016/j.cclet.2024.110320
19. [19]
  Zeyang Yao , Xinru You , Xudong Wang , Yunze Kang , Liying Wang , Ziji Zhang . Stem cell-based hydrogel for the repair and regeneration of cartilage. Chinese Chemical Letters, 2025, 36(8): 110607-. doi: 10.1016/j.cclet.2024.110607
20. [20]
  Yingqiang Liang , Shilun Li , Yixiao Pan , Weiyu Zhang , Shupeng Liu , Yiwen Chen , Jiangfeng Hu , Xueliang Zhang , Jun Zhao , Zhigang Zheng . Exosome-hybridized hydrogel acts as a foamy protective coat for the liver. Chinese Chemical Letters, 2025, 36(11): 110841-. doi: 10.1016/j.cclet.2025.110841

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1787)
HTML views(178)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Simple fabrication of Cu2+ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties

Metrics

通讯作者: 陈斌, bchen63@163.com

Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties