Citation: Tian Bai, Kongyin Zhao, Zijie Lu, Xuefang Liu, Ze Lin, Mengmeng Cheng, Ziyi Li, Dunwan Zhu, Linhua Zhang. Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties[J]. Chinese Chemical Letters, ;2021, 32(3): 1051-1054. doi: 10.1016/j.cclet.2020.07.034 shu

Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties

Tian Bai ^a ,
Kongyin Zhao ^{a, *,} ,
Zijie Lu ^a ,
Xuefang Liu ^a ,
Ze Lin ^a ,
Mengmeng Cheng ^a ,
Ziyi Li ^a ,
Dunwan Zhu ^b ,
Linhua Zhang ^b

a.
State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
b.
Tianjin Key Laboratory of Biomedical Materials, Key Laboratory of Biomaterials and Nanotechnology for Cancer Immunotherapy, Institute of Biomedical Engineering, Chinese Academy of Medical Sciences & Peking Union Medical College, Tianjin 300192, China

Received Date: 11 May 2020
Revised Date: 16 July 2020
Accepted Date: 17 July 2020
Available Online: 18 July 2020

Figures(4)

Herein, copper ion doped calcium alginate (Cu²⁺/CaAlg) composite hydrogel filtration membranes were prepared by using natural polymer sodium alginate (NaAlg) as raw material. The thermal stability and structure of the composite membranes were characterized by thermogravimetric analysis and infrared spectroscopy. The mechanical strength, anti-fouling performance, hydrophilicity and filtration performance of the membrane were studied. The results show that Cu²⁺/CaAlg hydrogel membrane has excellent mechanical properties and thermal stability. The anti-swelling ability of the membrane was greatly enhanced by doping Cu²⁺. After three alternate filtration cycles, the flux recovery rate of Cu²⁺/CaAlg hydrogel membrane can still reach 85%, indicating that the membrane has good anti-pollution performance. When the operation pressure was 0.1 MPa, the rejection of coomassie brilliant blue G250 reached 99.8% with a flux of 46.3 L m^-2 h^-1, while the Na₂SO₄ rejectionwas less than 10.0%. The Cu²⁺/CaAlg membrane was recycled after 24 h in the filtration process, and its flux and rejection rate did not decrease significantly, indicating that the hydrogel membrane has long-term application potential. The Cu²⁺/CaAlg membrane has a wide range of applications prospect in dye desalination, fine separation and biopharmaceutical technology fields.
- Calcium alginate,
- Cu²⁺ doped,
- Hydrogel,
- Filtration membrane,
- Antibacterial,
- Anti-fouling
1. [1]
  X. Wang, Y. Pan, H. Yuan, et al., Chin. Chem. Lett. 31(2020) 365-368. doi: 10.1016/j.cclet.2019.07.044
2. [2]
  J. Shan, W. Wei, D. Yonghong, et al., Chin. Chem. Lett. 29(2018) 390-394. doi: 10.1016/j.cclet.2018.01.006
3. [3]
  S. Yuan, G. Zhang, J. Zhu, J. Mater. Chem. A 8(2020) 3238-3245. doi: 10.1039/C9TA12984G
4. [4]
  Q. Nie, F. Ran, C. He, et al., Chin. Chem. Lett. 22(2011) 370-373. doi: 10.1016/j.cclet.2010.10.017
5. [5]
  J. Guo, K. Zhao, X. Zhang, et al., Mater. Lett. 157(2015) 112-115. doi: 10.1016/j.matlet.2015.05.080
6. [6]
  J. Li, S. Li, X. Wang, et al., Chin. Chem. Lett. 30(2019) 239-242. doi: 10.1016/j.cclet.2018.07.016
7. [7]
  J. Zhu, M. Tian, J. Hou, et al., J. Mater. Chem. A 4(2016) 1980-1990. doi: 10.1039/C5TA08024J
8. [8]
  S. Gao, Y. Zhu, Y. Gong, et al., ACS Nano 13(2019) 5278-5290. doi: 10.1021/acsnano.8b09761
9. [9]
  P. Zhong, N. Widjojo, T. Chung, et al., J. Membr. Sci. 417(2012) 52-60.
10. [10]
  J.H. Jhaveri, Z.V.P. Murthy, Desalination 379(2016) 137-154. doi: 10.1016/j.desal.2015.11.009
11. [11]
  M. Min, Y. Liu, C. Song, et al., ACS Appl. Mater. Inter. 10(2018) 21246-21253. doi: 10.1021/acsami.8b03411
12. [12]
  X. Deng, N. Chao, W. Ding, et al., J. Biomed. Nanotechnol. 15(2019) 756-768. doi: 10.1166/jbn.2019.2713
13. [13]
  Y. Cai, J. Zhang, Y. He, et al., Int. J. Biomed. Nanotechnol. 14(2018) 257-266. doi: 10.1166/jbn.2018.2483
14. [14]
  S. Gao, S.Y. Zhu, J. Wang, et al., Adv. Funct. Mater. 28(2018) 1801944. doi: 10.1002/adfm.201801944
15. [15]
  E.G. Deze, S.K. Papageorgiou, E.P. Favvas, et al., Chem. Eng. J. 209(2012) 537-546. doi: 10.1016/j.cej.2012.07.133
16. [16]
  K. Zhao, X. Zhang, J. Wei, et al., J. Membr. Sci. 492(2015) 536-546. doi: 10.1016/j.memsci.2015.05.075
17. [17]
  Y.N. Mata, M.L. Blázquez, A. Ballester, et al., J. Hazard. Mater. 163(2009) 555-562. doi: 10.1016/j.jhazmat.2008.07.015
18. [18]
  L.D. Nghiem, A.I. Schäfer, M. Elimelech, et al., J. Membr. Sci. 286(2006) 52-59. doi: 10.1016/j.memsci.2006.09.011
19. [19]
  W. Ye, K. Ye, F. Lin, et al., Chem. Eng. J. 379(2020) 122321. doi: 10.1016/j.cej.2019.122321
20. [20]
  N. Wang, X. Li, L. Wang, et al., ACS Appl. Mater. Interfaces 8(2016) 21979-21983. doi: 10.1021/acsami.6b08581
1. [1]
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2. [2]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
  Jianwen Zhao , Shuai Wang , Shanshan Zhao , Liwei Chen , Fangang Meng , Xuelin Tian . A non-fluorinated liquid-like membrane with excellent anti-scaling performance for membrane distillation. Chinese Chemical Letters, 2025, 36(1): 109883-. doi: 10.1016/j.cclet.2024.109883
14. [14]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
15. [15]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
16. [16]
  Yuan ZHU , Xiaoda ZHANG , Shasha WANG , Peng WEI , Tao YI . Conditionally restricted fluorescent probe for Fe³⁺ and Cu²⁺ based on the naphthalimide structure. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232
17. [17]
  Jinjie Lu , Qikai Liu , Yuting Zhang , Yi Zhou , Yanbo Zhou . Antibacterial performance of cationic quaternary phosphonium-modified chitosan polymer in water. Chinese Chemical Letters, 2024, 35(9): 109406-. doi: 10.1016/j.cclet.2023.109406
18. [18]
  Wei Su , Xiaoyan Luo , Peiyuan Li , Ying Zhang , Chenxiang Lin , Kang Wang , Jianzhuang Jiang . Phthalocyanine self-assembled nanoparticles for type Ⅰ photodynamic antibacterial therapy. Chinese Chemical Letters, 2024, 35(12): 109522-. doi: 10.1016/j.cclet.2024.109522
19. [19]
  Qihang Wu , Hui Wen , Wenhai Lin , Tingting Sun , Zhigang Xie . Alkyl chain engineering of boron dipyrromethenes for efficient photodynamic antibacterial treatment. Chinese Chemical Letters, 2024, 35(12): 109692-. doi: 10.1016/j.cclet.2024.109692
20. [20]
  Fangping Yang , Jin Shi , Yuansong Wei , Qing Gao , Jingrui Shen , Lichen Yin , Haoyu Tang . Mixed-charge glycopolypeptides as antibacterial coatings with long-term activity. Chinese Chemical Letters, 2025, 36(2): 109746-. doi: 10.1016/j.cclet.2024.109746

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沈阳化工大学材料科学与工程学院沈阳 110142

Simple fabrication of Cu2+ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties

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通讯作者: 陈斌, bchen63@163.com

Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties