Citation: Feng Su, Shuanghao Zheng, Fangyan Liu, Xiong Zhang, Fangyuan Su, Zhong-Shuai Wu. Nitrogen-doped holey graphene nanoscrolls for high-energy and high-power supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(2): 914-917. doi: 10.1016/j.cclet.2020.07.025 shu

Nitrogen-doped holey graphene nanoscrolls for high-energy and high-power supercapacitors

Feng Su ^{a, b} ,
Shuanghao Zheng ^a ,
Fangyan Liu ^a ,
Xiong Zhang ^{c, e} ,
Fangyuan Su ^{d, e} ,
Zhong-Shuai Wu ^{a, *,}

a.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
d.
CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
e.
Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, China

wuzs@dicp.ac.cn

Received Date: 3 June 2020
Revised Date: 8 July 2020
Accepted Date: 9 July 2020
Available Online: 15 July 2020

Figures(4)

Porous structure and heteroatom doping are two key parameters for significantly boosting the capacitive performance of graphene-based materials. Herein, we report a facile approach to prepare one-dimensional (1D) nitrogen-doped holey graphene nanoscrolls (NHGNSs) through cold quenching treatment of two-dimensional graphene oxide sheets, followed by thermal annealing in the successive atmosphere of NH₃ and air. Benefiting from the synergy of the unique 1D tubular morphology, abundant nanoholes and nitrogen doping, the NHGNSs exhibit a high specific capacitance of 126 F/g at 1 A/g in ionic liquid electrolyte and excellent rate capability with 81% of the capacitance retained at 20 A/g. Furthermore, the fabricated symmetric supercapacitors based on NHGNSs achieve both high energy density of 53.5 Wh/kg at 875 W/kg and high power density of 17.5 kW/kg at 43.4 Wh/kg. The simple synthetic process and superior electrochemical performance suggest the great potential of NHGNSs for supercapacitor application.
- Graphene nanoscrolls,
- Nitrogen doping,
- Holey grapheme,
- Supercapacitors,
- Ionic liquid
1. [1]
  A. Noori, M.F. El-Kady, M.S. Rahmanifar, R.B. Kaner, M.F. Mousavi, Chem. Soc. Rev. 48 (2019) 1272-1341. doi: 10.1039/C8CS00581H
2. [2]
  J. Qin, Z.S. Wu, F. Zhou, et al., Chin. Chem. Lett. 29 (2018) 582-586. doi: 10.1016/j.cclet.2017.08.007
3. [3]
  L.M. Da Silva, R. Cesar, C.M.R. Moreira, et al., Energy Storage Mater. 27 (2020) 555-590. doi: 10.1016/j.ensm.2019.12.015
4. [4]
  H. Huang, H. Shi, P. Das, et al., Adv. Funct. Mater. 30 (2020) 1909035. doi: 10.1002/adfm.201909035
5. [5]
  X. Shi, S. Zheng, Z.S. Wu, X. Bao, J. Energy Chem. 27 (2018) 25-42. doi: 10.1016/j.jechem.2017.09.034
6. [6]
  C. Peng, J. Yu, S. Chen, L. Wang, Chin. Chem. Lett. 30 (2019) 1137-1140. doi: 10.1016/j.cclet.2019.02.007
7. [7]
  K. Zhang, X. Yang, D. Li, J. Energy Chem. 27 (2018) 1-5. doi: 10.1016/j.jechem.2017.11.027
8. [8]
  Z. Xu, B. Zheng, J. Chen, C. Gao, Chem. Mater. 26 (2014) 6811-6818. doi: 10.1021/cm503418h
9. [9]
  C.A. Amadei, I.Y. Stein, G.J. Silverberg, B.L. Wardle, C.D. Vecitis, Nanoscale 8 (2016) 6783-6791. doi: 10.1039/C5NR07983G
10. [10]
  H. Li, J. Wu, X. Qi, et al., Small 9 (2013) 382-386. doi: 10.1002/smll.201202358
11. [11]
  T. Sharifi, E. Gracia-Espino, H.R. Barzegar, et al., Nat. Commun. 4 (2013) 2319. doi: 10.1038/ncomms3319
12. [12]
  J. Zhao, B. Yang, Z. Yang, et al., Carbon 79 (2014) 470-477. doi: 10.1016/j.carbon.2014.08.006
13. [13]
  Z. Zhang, J. Zhao, J. Zhou, et al., Energy Storage Mater. 8 (2017) 35-41. doi: 10.1016/j.ensm.2017.03.003
14. [14]
  B. Zheng, Z. Xu, C. Gao, Nanoscale 8 (2016) 1413-1420. doi: 10.1039/C5NR07067H
15. [15]
  F. Zhou, H. Huang, C. Xiao, et al., J. Am. Chem. Soc. 140 (2018) 8198-8205. doi: 10.1021/jacs.8b03235
16. [16]
  Z.S. Wu, Y.Z. Tan, S. Zheng, et al., J. Am. Chem. Soc. 139 (2017) 4506-4512. doi: 10.1021/jacs.7b00805
17. [17]
  X. Yu, C. Pei, L. Feng, Chin. Chem. Lett. 30 (2019) 1121-1125. doi: 10.1016/j.cclet.2019.01.009
18. [18]
  H. Guo, L. Liu, Q. Dou, et al., Energy Storage Mater. 19 (2019) 338-345. doi: 10.1016/j.ensm.2018.10.008
19. [19]
  Y. Lin, X. Han, C.J. Campbell, et al., Adv. Funct. Mater. 25 (2015) 2920-2927. doi: 10.1002/adfm.201500321
20. [20]
  H. Xu, L. Ma, Z. Jin, J. Energy Chem. 27 (2018) 146-160. doi: 10.1016/j.jechem.2017.12.006
21. [21]
  Y. Zhang, Q. Wan, N. Yang, Small 15 (2019) 1903780. doi: 10.1002/smll.201903780
22. [22]
  W. Qian, F. Sun, Y. Xu, et al., Energy Environ. Sci. 7 (2014) 379-386. doi: 10.1039/C3EE43111H
23. [23]
  X. Lin, H. Lou, W. Lu, et al., Chin. Chem. Lett. 29 (2018) 633-636. doi: 10.1016/j.cclet.2017.11.024
24. [24]
  H.K. Kim, A.R. Kamali, K.C. Roh, K.B. Kim, D.J. Fray, Energy Environ. Sci. 9 (2016) 2249-2256. doi: 10.1039/C6EE00815A
25. [25]
  J. Tian, C. Cui, C. Zheng, W. Qian, Chin. Chem. Lett. 29 (2018) 599-602. doi: 10.1016/j.cclet.2018.01.027
26. [26]
  A.G. Kannan, A. Samuthirapandian, D.W. Kim, J. PowerSources 337 (2017) 65-72.
27. [27]
  A. Xiang, S. Xie, F. Pan, et al., Chin. Chem. Lett. (2020), doi: http://dx.doi.org/10.1016/j.cclet.2020.04.058.
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