Citation: Yanhao Zhang, Yi-Jie Chen, Yuanyuan Song, Chuan Dong, Zongwei Cai. Atmospheric pressure gas chromatography-tandem mass spectrometry analysis of fourteen emerging polycyclic aromatic sulfur heterocycles in PM_2.5[J]. Chinese Chemical Letters, ;2021, 32(2): 801-804. doi: 10.1016/j.cclet.2020.07.022 shu

Atmospheric pressure gas chromatography-tandem mass spectrometry analysis of fourteen emerging polycyclic aromatic sulfur heterocycles in PM_2.5

Yanhao Zhang ^a ,
Yi-Jie Chen ^{a, b} ,
Yuanyuan Song ^a ,
Chuan Dong ^c ,
Zongwei Cai ^{a, b, *,}

a.
State Key Laboratory of Environmental and Biological Analysis, Department of Chemistry, Hong Kong Baptist University, Hong Kong SAR, China
b.
Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, School of Environmental Science and Engineering, Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006, China
c.
Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

zwcai@hkbu.edu.hk

Received Date: 4 June 2020
Revised Date: 3 July 2020
Accepted Date: 10 July 2020
Available Online: 11 July 2020

Figures(1)

Research on pollution characteristics and toxicities of emerging polycyclic aromatic sulfur heterocycles (PASHs) in PM_2.5 has not been reported due to the lack of analytical method with the needed performance. In the present study, a novel method for the determination of 14 PASHs in PM_2.5 was developed using atmospheric pressure gas chromatography-tandem mass spectrometry (APGC-MS/MS). Atmospheric pressure chemical ionization was operated with multiple reaction monitoring in positive ionization mode. High sensitivity (method detection limit < 1.673 pg/m³), acceptable recoveries (67.6%–120.8%) and precisions (RSD of 2.2%–15.4%) were obtained. The method was successfully applied for analyzing PASHs in 10 PM_2.5 samples collected from Taiyuan, a typical industrial city in China, in 2016. The total concentrations were from 929 pg/m³ to 14,593 pg/m³. The determined levels indicated that further investigations on environmental fate and toxicities of PM_2.5-bound PASHs may be needed.
1. [1]
  X. Han, Y. Liu, H. Gao, et al., Sci. Total Environ. 607-608 (2017) 1009-1017. doi: 10.1016/j.scitotenv.2017.07.061
2. [2]
  S. Taghvaee, M.H. Sowlat, M.S. Hassanvand, et al., Environ. Int. 120 (2018) 321-332. doi: 10.1016/j.envint.2018.08.003
3. [3]
  W. Hu, G.S. Downward, B. Reiss, etal., Environ. Sci. Technol. 48 (2014) 8456-8464. doi: 10.1021/es502201s
4. [4]
  C.A. Pope III, R.T. Burnett, M.C. Turner, et al., Environ. Health Perspect. 119 (2011) 1616-1621. doi: 10.1289/ehp.1103639
5. [5]
  S. Heft-Neal, J. Burney, E. Bendavid, M. Burke, Nature 559 (2018) 254-258. doi: 10.1038/s41586-018-0263-3
6. [6]
  X. Wang, X. Bi, G. Sheng, J. Fu, Environ. Monit. Assess. 119 (2006) 425-439. doi: 10.1007/s10661-005-9034-3
7. [7]
  Q. Chen, X.S. Luo, Y. Chen, et al., Chemosphere 230 (2019) 424-431. doi: 10.1016/j.chemosphere.2019.04.226
8. [8]
  D. Huang, G. Xiu, M. Li, X. Hua, Y. Long, Atmos. Environ. 148 (2017) 175-181. doi: 10.1016/j.atmosenv.2016.10.036
9. [9]
  J. Lang, Y. Zhang, Y. Zhou, et al., Aerosol Air Qual. Res. 17 (2017) 412-425. doi: 10.4209/aaqr.2016.07.0307
10. [10]
  V. Martins, T. Moreno, M.C. Minguillon, etal., Environ. Pollut. 208 (2016) 125-136. doi: 10.1016/j.envpol.2015.07.004
11. [11]
  W. Wen, X. Ma, P. Wei, et al., Aerosol Air Qual. Res. 18 (2018) 1720-1733. doi: 10.4209/aaqr.2017.10.0406
12. [12]
  Y. Zhang, Z. Yang, Q. Zhang, et al., Chin. Chem. Lett. 26 (2015) 157-159. doi: 10.1016/j.cclet.2014.08.004
13. [13]
  L. Zhang, T. Xu, Z. Pi, Chin. Chem. Lett. 30 (2019) 90-94. doi: 10.1016/j.cclet.2017.11.019
14. [14]
  M. He, T. Ichinose, M. Kobayashi, et al., Toxicol. Appl. Pharmacol. 297 (2016) 41-55. doi: 10.1016/j.taap.2016.02.017
15. [15]
  A. MohseniBandpi, A. Eslami, A. Shahsavani, F. Khodagholi, A. Alinejad, Sci. Total Environ. 593-594 (2017) 182-190. doi: 10.1016/j.scitotenv.2017.03.150
16. [16]
  R. Li, X. Kou, H. Geng, C. Dong, Z. Cai, Chin. Chem. Lett. 25 (2014) 663-666. doi: 10.1016/j.cclet.2014.03.032
17. [17]
  L. Alves, S.M. Paixao, Bioresour. Technol. 102 (2011) 9162-9166. doi: 10.1016/j.biortech.2011.06.070
18. [18]
  R.A. Pelroy, D.L. Stewart, Y. Tominaga, et al., Mutat. Res. 117 (1983) 31-40. doi: 10.1016/0165-1218(83)90150-7
19. [19]
  C. Yu, Z. Yao, B. Hu, Anal. Chim. Acta 641 (2009) 75-82. doi: 10.1016/j.aca.2009.03.031
20. [20]
  W.B. Studabaker, K.J. Puckett, K.E. Percy, M.S. Landis, J. Chromatogr. A 1492 (2017) 106-116. doi: 10.1016/j.chroma.2017.02.051
21. [21]
  G. Becker, A. Colmsjo, C. Ostman, Environ. Sci. Technol. 33 (1999) 1321-1327. doi: 10.1021/es981151t
22. [22]
  M. Grung, A. Kringstad, K. Baek, et al., J. Hazard. Mater. 323 (2017) 36-44. doi: 10.1016/j.jhazmat.2016.05.036
23. [23]
  Y. Zhang, Y. Chen, R. Li, et al., Talanta 195 (2019) 757-763. doi: 10.1016/j.talanta.2018.12.006
24. [24]
  Y. Zhang, R. Li, J. Fang, C. Wang, Z. Cai, Chemosphere 198 (2018) 303-310. doi: 10.1016/j.chemosphere.2018.01.131
25. [25]
  W. Zhang, Y. Zhang, Q. Jiang, et al., Anal. Chem. 88 (2016) 10523-10532. doi: 10.1021/acs.analchem.6b02583
26. [26]
  Y. Pan, Z. Deng, Y. Chen, et al., Anal. Methods 9 (2017) 5763-5768. doi: 10.1039/C7AY01421J
27. [27]
  B. Yang, W. Hou, K. Zhang, X. Wang, J. Sep. Sci. 36 (2013) 2646-2655. doi: 10.1002/jssc.201300184
28. [28]
  W.B. Wilson, H.V. Hayes, A.D. Campiglia, S.A. Wise, Anal. Bioanal. Chem. 410 (2018) 4177-4188. doi: 10.1007/s00216-018-1065-z
29. [29]
  Y. Chen, Y. Chen, Y. Zhang, et al., Talanta 194 (2019) 320-328. doi: 10.1016/j.talanta.2018.10.025
1. [1]
  Donghui PAN , Yuping XU , Xinyu WANG , Lizhen WANG , Junjie YAN , Dongjian SHI , Min YANG , Mingqing CHEN . Preparation and in vivo tracing of ⁶⁸Ga-labeled PM_2.5 mimetic particles for positron emission tomography imaging. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 669-676. doi: 10.11862/CJIC.20230468
2. [2]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
3. [3]
  Lu Huang , Jiang Wang , Hong Jiang , Lanfang Chen , Huanwen Chen . On-line determination of selenium compounds in tea infusion by extractive electrospray ionization mass spectrometry combined with a heating reaction device. Chinese Chemical Letters, 2025, 36(1): 109896-. doi: 10.1016/j.cclet.2024.109896
4. [4]
  Tian Feng , Yun-Ling Gao , Di Hu , Ke-Yu Yuan , Shu-Yi Gu , Yao-Hua Gu , Si-Yu Yu , Jun Xiong , Yu-Qi Feng , Jie Wang , Bi-Feng Yuan . Chronic sleep deprivation induces alterations in DNA and RNA modifications by liquid chromatography-mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(8): 109259-. doi: 10.1016/j.cclet.2023.109259
5. [5]
  Feng-Qing Huang , Yu Wang , Ji-Wen Wang , Dai Yang , Shi-Lei Wang , Yuan-Ming Fan , Raphael N. Alolga , Lian-Wen Qi . Chemical isotope labeling-assisted liquid chromatography-mass spectrometry enables sensitive and accurate determination of dipeptides and tripeptides in complex biological samples. Chinese Chemical Letters, 2024, 35(11): 109670-. doi: 10.1016/j.cclet.2024.109670
6. [6]
  Tingting Huang , Zhuanlong Ding , Hao Liu , Ping-An Chen , Longfeng Zhao , Yuanyuan Hu , Yifan Yao , Kun Yang , Zebing Zeng . Electron-transporting boron-doped polycyclic aromatic hydrocarbons: Facile synthesis and heteroatom doping positions-modulated optoelectronic properties. Chinese Chemical Letters, 2024, 35(4): 109117-. doi: 10.1016/j.cclet.2023.109117
7. [7]
  Ying Chen , Xingyuan Xia , Lei Tian , Mengying Yin , Ling-Ling Zheng , Qian Fu , Daishe Wu , Jian-Ping Zou . Constructing built-in electric field via CuO/NiO heterojunction for electrocatalytic reduction of nitrate at low concentrations to ammonia. Chinese Chemical Letters, 2024, 35(12): 109789-. doi: 10.1016/j.cclet.2024.109789
8. [8]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
9. [9]
  Yue Zhang , Xiaoya Fan , Xun He , Tingyu Yan , Yongchao Yao , Dongdong Zheng , Jingxiang Zhao , Qinghai Cai , Qian Liu , Luming Li , Wei Chu , Shengjun Sun , Xuping Sun . Ambient electrosynthesis of urea from carbon dioxide and nitrate over Mo₂C nanosheet. Chinese Chemical Letters, 2024, 35(8): 109806-. doi: 10.1016/j.cclet.2024.109806
10. [10]
  Chao-Long Chen , Rong Chen , La-Sheng Long , Lan-Sun Zheng , Xiang-Jian Kong . Anchoring heterometallic cluster on P-doped carbon nitride for efficient photocatalytic nitrogen fixation in water and air ambient. Chinese Chemical Letters, 2024, 35(4): 108795-. doi: 10.1016/j.cclet.2023.108795
11. [11]
  Haoyang Wang , Ronghao Zhang , Yanlun Ren , Li Zhang . A convenient method for measuring gas-liquid volumetric mass transfer coefficient in micro reactors. Chinese Chemical Letters, 2024, 35(4): 108833-. doi: 10.1016/j.cclet.2023.108833
12. [12]
  Junmeng Luo , Qiongqiong Wan , Suming Chen . Chemistry-driven mass spectrometry for structural lipidomics at the C=C bond isomer level. Chinese Chemical Letters, 2025, 36(1): 109836-. doi: 10.1016/j.cclet.2024.109836
13. [13]
  Yanhua Chen , Xian Ding , Jun Zhou , Zhaoying Wang , Yunhai Bo , Ying Hu , Qingce Zang , Jing Xu , Ruiping Zhang , Jiuming He , Fen Yang , Zeper Abliz . Plasma metabolomics combined with mass spectrometry imaging reveals crosstalk between tumor and plasma in gastric cancer genesis and metastasis. Chinese Chemical Letters, 2025, 36(1): 110351-. doi: 10.1016/j.cclet.2024.110351
14. [14]
  Haiyan Lu , Jiayue Ye , Yiping Wei , Hua Zhang , Konstantin Chingin , Vladimir Frankevich , Huanwen Chen . Tracing molecular margins of lung cancer by internal extractive electrospray ionization mass spectrometry. Chinese Chemical Letters, 2025, 36(2): 110077-. doi: 10.1016/j.cclet.2024.110077
15. [15]
  Uttam Pandurang Patil . Porous carbon catalysis in sustainable synthesis of functional heterocycles: An overview. Chinese Chemical Letters, 2024, 35(8): 109472-. doi: 10.1016/j.cclet.2023.109472
16. [16]
  Ying Xu , Chengying Shen , Hailong Yuan , Wei Wu . Mapping multiple phases in curcumin binary solid dispersions by fluorescence contrasting. Chinese Chemical Letters, 2024, 35(9): 109324-. doi: 10.1016/j.cclet.2023.109324
17. [17]
  Yajun Hou , Chuanzheng Zhu , Qiang Wang , Xiaomeng Zhao , Kun Luo , Zongshuai Gong , Zhihao Yuan . ~2.5 nm pores in carbon-based cathode promise better zinc-iodine batteries. Chinese Chemical Letters, 2024, 35(5): 108697-. doi: 10.1016/j.cclet.2023.108697
18. [18]
  Bei Li , Zhaoke Zheng . In situ monitoring of the spatial distribution of oxygen vacancies at the single-particle level. Chinese Journal of Structural Chemistry, 2024, 43(10): 100331-100331. doi: 10.1016/j.cjsc.2024.100331
19. [19]
  Jingyuan Yang , Xinyu Tian , Liuzhong Yuan , Yu Liu , Yue Wang , Chuandong Dou . Enhancing stability of diradical polycyclic hydrocarbons via P=O-attaching. Chinese Chemical Letters, 2024, 35(8): 109745-. doi: 10.1016/j.cclet.2024.109745
20. [20]
  Xianping Du , Ying Huang , Chen Chen , Zhenhe Feng , Meng Zong . Encapsulating Si particles in multiple carbon shells with pore-rich for constructing free-standing anodes of lithium storage. Chinese Chemical Letters, 2024, 35(12): 109990-. doi: 10.1016/j.cclet.2024.109990

Get Citation

PDF

XML

Metrics

PDF Downloads(17)
Abstract views(1173)
HTML views(190)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Atmospheric pressure gas chromatography-tandem mass spectrometry analysis of fourteen emerging polycyclic aromatic sulfur heterocycles in PM2.5

Metrics

通讯作者: 陈斌, bchen63@163.com

Atmospheric pressure gas chromatography-tandem mass spectrometry analysis of fourteen emerging polycyclic aromatic sulfur heterocycles in PM_2.5