Citation: Xiong Sun, Congqing Zhu. Synthesis, characterization and reactivity of a neutral antimony(III) complex[J]. Chinese Chemical Letters, ;2021, 32(2): 717-720. doi: 10.1016/j.cclet.2020.07.006 shu

Synthesis, characterization and reactivity of a neutral antimony(III) complex

Xiong Sun ,
Congqing Zhu ^*,

State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China

zcq@nju.edu.cn

Received Date: 18 May 2020
Revised Date: 29 June 2020
Accepted Date: 4 July 2020
Available Online: 4 July 2020

Figures(8)

Pincer complexes are widely used in organometallic and coordination chemistry. The role of antimony as a central donor atom in pincer ligands has been extensively explored in recent years. Although phenylenediamine derived PXP (X = B, Al, C, Si, Ge, Sn, N) type ligands exhibit diverse reactivity, analogues species based on antimony have been reported less frequently. Herein, we report a new PSbP complex and evaluate its reactivity. These species will broaden the family of phenylenediamine derived pincer complexes.
- Pincer ligand,
- Antimony,
- Phenylenediamine,
- Coordination
1. [1]
  (a) C.J. Moulton, B.L. Shaw, J. Chem. Soc. Dalton Trans. (1976) 1020-1024;
  (b) G. Van Koten, K. Timmer, J.G. Noltes, A.L. Spek, J. Chem. Soc. Chem. Commun. (1978) 250-252.
2. [2]
  (a) J. Choi, A.H.R. MacArthur, M. Brookhart, A.S. Goldman, Chem. Rev. 111 (2011) 1761-1779;
  (b) E. Peris, R.H. Crabtree, Chem. Soc. Rev. 47 (2018) 1959-1968;
  (c) H.A. Younus, N. Ahmad, W. Su, F. Verpoort, Coord. Chem. Rev. 276 (2014) 112-152.
3. [3]
  (a) D. Morales-Morales, C.M. Jensen, The Chemistry of Pincer Compounds, Elsevier, Amsterdam, 2007;
  (b) G. van Koten, D. Milstein, Organometallic Pincer Chemistry, SpringerVerlag, Berlin-Heidelberg, 2013;
  (c) G.R. Freeman, J.A.G. Williams, Metal complexes of pincer ligands: excited states, photochemistry, and luminescence, in: G. van Koten, D. Milstein (Eds. ), Organometallic Pincer Chemistry, Springer, Berlin, 2013, pp. 89-129;
  (d) C. Gunanathan, D. Milstein, Chem. Rev. 114 (2014) 12024-12087;
  (e) H. Valdes, L. Gonzalez-Sebastian, D. Morales-Morales, J. Organomet, Chem. 845 (2017) 229-257.
4. [4]
  (a) H.M. Lee, J.Y. Zeng, C.H. Hu, M.T. Lee, Inorg. Chem. 43 (2004) 6822-6829;
  (b) T. Steinke, B.K. Shaw, H. Jong, et al., J. Am. Chem. Soc. 131 (2009) 10461-10466;
  (c) B.K. Shaw, B.O. Patrick, M.D. Fryzuk, Organometallics 31 (2012) 783-786.
5. [5]
  A. Plikhta, A. Pothig, E. Herdtweck, B. Rieger, Inorg. Chem. 54 (2015) 9517-9528.
6. [6]
  A. Eizawa, K. Arashiba, H. Tanaka, et al., Nat. Commun. 8 (2017) 1-12.
7. [7]
  Y. Segawa, M. Yamashita, K. Nozaki, J. Am. Chem. Soc. 131 (2009) 9201-9203.
8. [8]
  (a) M. Hasegawa, Y. Segawa, M. Yamashita, K. Nozaki, Angew. Chem. Int. Ed. 51 (2012) 6956-6960;
  (b) M. Yamashita, Bull. Chem. Soc. Japan. 89 (2016) 269-281;
  (c) E.H. Kwan, H. Ogawa, M. Yamashita, ChemCatChem 9 (2017) 2457-2462.
9. [9]
  T.P. Lin, J.C. Peters, J. Am. Chem. Soc. 135 (2013) 15310-15313.
10. [10]
  T.P. Lin, J.C. Peters, J. Am. Chem. Soc. 136 (2014) 13672-13683. doi: 10.1021/ja504667f
11. [11]
  (a) L.S. Dixon, A.F. Hill, A. Sinha, J.S. Ward, Organometallics 33 (2014) 653-658;
  (b) Z. Xiong, X. Li, S. Zhang, Y. Shi, H. Sun, Organometallics 35 (2016) 357-363;
  (c) B.J. Frogley, A.F. Hill, M. Sharma, A. Sinha, J.S. Ward, Chem. Commun. 56 (2020) 3532-3535.
12. [12]
  (a) L. Álvarez-Rodríguez, J. Brugos, J.A. Cabeza, et al., Chem. Commun. 53 (2017) 893-896;
  (b) J. Brugos, J.A. Cabeza, P. Garcia-Alvarez, E. Pe'rez-Carreño, Organometallics 37 (2018) 1507-1514;
  (c) J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño, D. Polo, Dalton Trans. 47 (2018) 4534-4544.
13. [13]
  (a) Y. Tulchinsky, M.A. Iron, M. Botoshansky, M. Gandelman, Nat. Chem. 3 (2011) 525-531;
  (b) Y. Tulchinsky, S. Kozuch, P. Saha, et al., Chem. Sci. 5 (2014) 1305-1311.
14. [14]
  (a) G.S. Day, B. Pan, D.L. Kellenberger, B.M. Foxman, C.M. Thomas, Chem. Commun. 47 (2011) 3634-3636;
  (b) A.M. Poitras, S.E. Knight, M.W. Bezpalko, B.M. Foxman, C.M. Thomas, Angew. Chem. Int. Ed. 57 (2018) 1497-1500.
15. [15]
  S. Morisako, S. Watanabe, S. Ikemoto, et al., Angew. Chem. Int. Ed. 58 (2019) 15031-15035.
16. [16]
  (a) S. Kobayashi, T. Busujima, S. Nagayama, Chem. Eur. J. 6 (2000) 3491-3494;
  (b) S. Thibaudeau, A. Martin-Mingot, M.P. Jouannetaud, O. Karam, F. Zunino, Chem. Commun. (2007) 3198-3200;
  (c) A. Saito, M. Umakoshi, N. Yagyu, Y. Hanzawa, Org. Lett. 10 (2008) 1783-1785;
  (d) A. Saito, J. Kasai, Y. Odaira, H. Fukaya, Y. Hanzawa, J. Org. Chem. 74 (2009) 5644-5647;
  (e) F. Liu, A. Martin-Mingot, M.P. Jouannetaud, F. Zunino, S. Thibaudeau, Org. Lett. 12 (2010) 868-871.
17. [17]
  (a) J.S. Jones, F.P. Gabbai, Acc. Chem. Res. 49 (2016) 857-867;
  (b) D. You, F.P. Gabbaï, Trends in Chemistry 1 (2019) 485-496.
18. [18]
  (a) C.R. Wade, F.P. Gabbaï, Angew. Chem. Int. Ed. 50 (2011) 7369-7372;
  (b) C.R. Wade, I.S. Ke, F.P. Gabbaï, Angew. Chem. Int. Ed. 51 (2012) 478-481;
  (c) I.S. Ke, F.P. Gabbaï, Inorg. Chem. 52 (2013) 7145-7151;
  (d) I.S. Ke, J.S. Jones, F.P. Gabbaï, Angew. Chem. Int. Ed. 53 (2014) 2633-2637;
  (e) J.S. Jones, C.R. Wade, F.P. Gabbaï, Angew. Chem. Int. Ed. 53 (2014) 8876-8879;
  (f) H. Yang, F.P. Gabbaï, J. Am. Chem. Soc. 137 (2015) 13425-13432;
  (g) J.S. Jones, C.R. Wade, F.P. Gabbaï, Organometallics 34 (2015) 2647-2654;
  (h) J.S. Jones, F.P. Gabbai, Chem. Eur. J. 23 (2017) 1136-1144;
  (i) D. You, F.P. Gabbaï, J. Am. Chem. Soc. 139 (2017) 6843-6846.
19. [19]
  N.K. Srungavruksham, Y.H. Liu, M.K. Tsai, C.W. Chiu, Inorg. Chem. 59 (2020) 4468-4474.
20. [20]
  (a) X. Sun, Q. Zhu, Z. Xie, et al., Chem. Eur. J. 25 (2019) 14295-14299;
  (b) X. Sun, W. Su, K. Shi, Z. Xie, C. Zhu, Chem. Eur. J. 26 (2020) 5354-5359.
21. [21]
  (a) G. Feng, M. Zhang, D. Shao, et al., Nat. Chem. 11 (2019) 248-253;
  (b) G. Feng, M. Zhang, P. Wang, et al., Proc. Natl. Acad. Sci. U. S. A. 116 (2019) 17654-17658;
  (c) X. Xin, C. Zhu, Dalton Trans. 49 (2020) 603-607;
  (d) G. Feng, K.N. McCabe, S. Wang, L. Maron, C. Zhu, Chem. Sci. (2020), doi: http://dx.doi.org/10.1039/D0SC00389A.
22. [22]
  D. Gudat, T. Gans-Eichler, M. Nieger, Chem. Commun. (2004) 2434-2435.
23. [23]
  P. Pyykkö, M. Atsumi, Chem. Eur. J. 15 (2009) 186-197.
24. [24]
  (a) D. Gudat, A. Haghverdi, M. Nieger, Angew. Chem. Int. Ed. 39 (2000) 3084-3086;
  (b) S. Harder, J. Brettar, Angew. Chem. Int. Ed. 45 (2006) 3474-3478;
  (c) J. Spielmann, D. Piesik, B. Wittkamp, G. Jansen, S. Harder, Chem. Commun. (2009) 3455-3456;
  (d) M. Arrowsmith, T.J. Hadlington, M.S. Hill, G. Kociok-Köhn, Chem. Commun. 48 (2012) 4567-4569;
  (e) S. Schnitzler, T.P. Spaniol, L. Maron, J. Okuda, Chem. Eur. J. 21 (2015) 11330-11334;
  (f) C.C. Chong, H. Hirao, R. Kinjo, Angew. Chem. Int. Ed. 53 (2014) 3342-3346;
  (g) C.C. Chong, H. Hirao, R. Kinjo, Angew. Chem. Int. Ed. 54 (2015) 190-194;
  (h) C.C. Chong, R. Kinjo, Angew. Chem. Int. Ed. 54 (2015) 12116-12120;
  (i) Z. Yang, M. Zhong, X. Ma, et al., Angew. Chem. Int. Ed. 54 (2015) 10225-10229;
  (j) J.K. Pagano, J.M. Dorhout, R. Waterman, K.R. Czerwinski, J.L. Kiplinger, Chem. Commun. 51 (2015) 17379-17381;
  (k) S. Bagherzadeh, N.P. Mankad, Chem. Commun. 52 (2016) 3844-3846.
25. [25]
  K.M. Marczenko, J.A. Zurakowski, K.L. Bamford, J.W. MacMillan, S.S. Chitnis, Angew. Chem. Int. Ed. 58 (2019) 18096-18101.
26. [26]
  N. Hara, T. Saito, K. Semba, et al., J. Am. Chem. Soc. 140 (2018) 7070-7073.
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