Citation: Bing Li, Huan Pang, Huaiguo Xue. Fe-based phosphate nanostructures for supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(2): 885-889. doi: 10.1016/j.cclet.2020.07.004 shu

Fe-based phosphate nanostructures for supercapacitors

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

panghuan@yzu.edu.cn

chhgxue@yzu.edu.cn

Received Date: 11 June 2020
Revised Date: 29 June 2020
Accepted Date: 1 July 2020
Available Online: 2 July 2020

Figures(5)

Fe-based phosphates with excellent physical and chemical features are potential electrode materials for supercapacitors. In this work, we successfully synthesized Fe-based phosphates with different dimensions, morphologies, and compositions by one-step hydrothermal method. Influence factors on the chemical composition and morphology of the as-prepared materials were explored and the energy storage performance of the as-prepared samples were tested under the traditional three electrode system. Two-dimensional (2D) iron metaphosphate (Fe(PO₃)₃) showed the best electrochemical performance. For Fe(PO₃)₃ electrode materials, the layered structure can provide a larger specific surface area than the bulk structure, which is conducive to the diffusion and transport of electrolyte ions during charging-discharging and further improves the rate performance and cycle stability of supercapacitor. 2D Fe(PO₃)₃ and activated carbon were used as electrode materials to construct a 2D Fe(PO₃)₃//AC supercapacitor. The supercapacitor showed high energy density, high power density, and excellent cycling stability, which indicates 2D Fe(PO₃)₃ is a promising electrode material for supercapacitors.
- Two-dimensional,
- Fe-based phosphate,
- Fe(PO₃)₃,
- Electrode material,
- Supercapacitor
1. [1]
  W. Zhou, S. Lv, X.L. Liu, Chem. Commun. 55 (2019) 11207-11210. doi: 10.1039/C9CC06048K
2. [2]
  B.W. Lin, X.H. Zhu, L.Z. Fang, Adv. Mater. 31 (2019) 1900060.
3. [3]
  L. Xue, Q.H. Zhang, X.H. Zhu, et al., Nano Energy 56 (2019) 463-472. doi: 10.1016/j.nanoen.2018.11.085
4. [4]
  Y. Li, Y.Y. Shan, H. Pang, Chin. Chem. Lett. 31 (2020) 2280-2286. doi: 10.1016/j.cclet.2020.03.027
5. [5]
  B. Li, M.B. Zheng, H.G. Xue, et al., Inorg. Chem. Front. 3 (2016) 175-202. doi: 10.1039/C5QI00187K
6. [6]
  H.Y. Duan, T. Wang, X.Y. Wu, et al., Chin. Chem. Lett. 31 (2020) 2330-2332. doi: 10.1016/j.cclet.2020.06.001
7. [7]
  X.L. Xu, W.H. Shi, P. Li, Chem. Mater. 29 (2017) 6058-6065. doi: 10.1021/acs.chemmater.7b01947
8. [8]
  Y.Q. Jiang, C. Zhou, J.P. Liu, Energy Storage Mater. 11 (2018) 75-82. doi: 10.1016/j.ensm.2017.09.013
9. [9]
  X. Huang, C.L. Tan, Z.Y. Yin, et al., Adv. Mater. 26 (2014) 2185. doi: 10.1002/adma.201304964
10. [10]
  X. Huang, Z.Y. Zeng, H. Zhang, Chem. Soc. Rev. 42 (2013) 1934. doi: 10.1039/c2cs35387c
11. [11]
  X.L. Xu, W.H. Shi, W.X. Liu, J. Mater. Chem. A 6 (2018) 24086-24091. doi: 10.1039/C8TA06412A
12. [12]
  B. Li, P. Gu, Y.C. Feng, et al., Adv. Funct. Mater. 27 (2017) 1605784. doi: 10.1002/adfm.201605784
13. [13]
  H.Y. Liang, J.H. Lin, H. Jia, et al., J. Power Sources 378 (2018) 248-254. doi: 10.1016/j.jpowsour.2017.12.046
14. [14]
  S.J. Hou, X.T. Xu, M. Wang, et al., J. Mater. Chem. A 5 (2017) 19054. doi: 10.1039/C7TA04720G
15. [15]
  N.N. Zhang, X. Xiao, H. Pang, Nanoscale Horiz. 4 (2019) 99-116. doi: 10.1039/C8NH00144H
16. [16]
  Y. Yan, Y.Q. Luo, J.Y. Ma, et al., Small 14 (2018) 1801815. doi: 10.1002/smll.201801815
17. [17]
  C. Feng, J.F. Zhang, Y. He, et al., ACS Nano 9 (2015) 1730-1739. doi: 10.1021/nn506548d
18. [18]
  Y.H. Dai, L.B. Kong, K. Yan, et al., Ionics 22 (2016) 1461-1469. doi: 10.1007/s11581-016-1652-y
19. [19]
  N. Liu, Y.L. Su, Z.Q. Wang, et al., ACS Nano 11 (2017) 7879-7888. doi: 10.1021/acsnano.7b02344
20. [20]
  Y. Li, Y.X. Xu, Y. Liu, et al., Small 15 (2019) 1902463. doi: 10.1002/smll.201902463
21. [21]
  W.W. Liu, M.H. Zhu, J.H. Liu, X. Li, J. Liu, Chin. Chem. Lett. 30 (2019) 750-756. doi: 10.1016/j.cclet.2018.09.013
22. [22]
  H.F. Liang, C. Xia, A.H. Emwas, et al., Nano Energy 49 (2018) 155-162. doi: 10.1016/j.nanoen.2018.04.032
23. [23]
  L. Wang, H.M. Ji, S.S. Wang, et al., Nanoscale 5 (2013) 3793. doi: 10.1039/c3nr00256j
24. [24]
  X.C. Li, L. Zhang, G.H. He, Carbon 99 (2016) 514-522. doi: 10.1016/j.carbon.2015.12.076
25. [25]
  J.Q. Liu, M.B. Zheng, X.Q. Shi, et al., Adv. Funct. Mater. 26 (2016) 919-930. doi: 10.1002/adfm.201504019
26. [26]
  C. Shen, R.Z. Li, L.J. Yan, et al., Ionics 25 (2019) 2769-2779. doi: 10.1007/s11581-018-2739-4
27. [27]
  X. Chen, K.F. Chen, H. Wang, et al., Electrochim. Acta 147 (2014) 216-224. doi: 10.1016/j.electacta.2014.08.132
28. [28]
  X. Chen, K.F. Chen, H. Wang, et al., J. Colloid Interf. Sci. 444 (2015) 49-57. doi: 10.1016/j.jcis.2014.12.026
29. [29]
  H. Xu, J.X. Wu, C.L. Li, et al., Electrochim. Acta 165 (2015) 14-21. doi: 10.1016/j.electacta.2015.01.224
30. [30]
  C.X. Zhang, H.X. Liu, J. He, et al., Chem. Commun. 55 (2019) 10511-10514. doi: 10.1039/C9CC04481G
31. [31]
  P.P. Sun, Z.H. Li, L. Zhang, et al., J. Alloys. Compd. 750 (2018) 607-616. doi: 10.1016/j.jallcom.2018.04.024
32. [32]
  X.R. Li, X. Xiao, Q. Li, et al., Inorg. Chem. Front. 5 (2018) 11-28. doi: 10.1039/C7QI00434F
33. [33]
  Y.X. Chang, N.E. Shi, S.L. Zhao, et al., ACS Appl. Mater. Interfaces 8 (2016) 22534-22544. doi: 10.1021/acsami.6b07209
34. [34]
  X.Y. Qin, B.Y. Yan, J. Yu, et al., Inorg. Chem. Front. 4 (2017) 1424-1444. doi: 10.1039/C7QI00184C
35. [35]
  J.H. Zhao, Y.J. Zhang, Z. Run, et al., Chem. Open. 4 (2015) 274-277.
36. [36]
  Y.F. Zhao, Z.Y. Chen, D.B. Xiong, et al., Sci. Rep. 6 (2016) 17613. doi: 10.1038/srep17613
37. [37]
  D. Li, C.S. Pan, R. Shi, et al., CrystEngComm. 13 (2011) 6688-6693. doi: 10.1039/c1ce05483j
38. [38]
  C.Q. Min, X.Q. Ou, Z.X. Shi, et al., Ionics 24 (2018) 1285-1292. doi: 10.1007/s11581-017-2287-3
39. [39]
  T.C. Liu, Y.D. Duan, G.X. Zhang, et al., J. Mater. Chem. A 4 (2016) 4479-4484. doi: 10.1039/C6TA00454G
40. [40]
  D.Z. Zhong, L. Liu, D.D. Li, et al., J. Mater. Chem. A 5 (2017) 18627-18633. doi: 10.1039/C7TA05580C
41. [41]
  X.J. Wei, Y.H. Li, H.R. Peng, et al., Chem. Eng. J. 355 (2019) 336-340. doi: 10.1016/j.cej.2018.08.009
42. [42]
  A.K. Singha, K. Mandal, J. Appl. Phys. 117 (2015) 105101. doi: 10.1063/1.4913218
43. [43]
  Y. Zhao, Y. Xie, S. Yan, et al., Chem. Mater. 20 (2008) 3959-3964. doi: 10.1021/cm8002468
44. [44]
  L. Yang, Z.L. Guo, J. Huang, Adv. Mater. 29 (2017) 1704574. doi: 10.1002/adma.201704574
1. [1]
  Yuchen Wang , Yaoyu Liu , Xiongfei Huang , Guanjie He , Kai Yan . Fe nanoclusters anchored in biomass waste-derived porous carbon nanosheets for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(8): 109301-. doi: 10.1016/j.cclet.2023.109301
2. [2]
  Wenhao Feng , Chunli Liu , Zheng Liu , Huan Pang . In-situ growth of N-doped graphene-like carbon/MOF nanocomposites for high-performance supercapacitor. Chinese Chemical Letters, 2024, 35(12): 109552-. doi: 10.1016/j.cclet.2024.109552
3. [3]
  Dongying Fu , Lin Pan , Yanli Ma , Yue Zhang . Bilayered Dion–Jacobson lead-iodine hybrid perovskite with aromatic spacer for broadband photodetection. Chinese Chemical Letters, 2025, 36(2): 109621-. doi: 10.1016/j.cclet.2024.109621
4. [4]
  Zixuan Guo , Xiaoshuai Han , Chunmei Zhang , Shuijian He , Kunming Liu , Jiapeng Hu , Weisen Yang , Shaoju Jian , Shaohua Jiang , Gaigai Duan . Activation of biomass-derived porous carbon for supercapacitors: A review. Chinese Chemical Letters, 2024, 35(7): 109007-. doi: 10.1016/j.cclet.2023.109007
5. [5]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
6. [6]
  Xinghong Cai , Qiang Yang , Yao Tong , Lanyin Liu , Wutang Zhang , Sam Zhang , Min Wang . AlO₂: A novel two-dimensional material with a high negative Poisson's ratio for the adsorption of volatile organic compounds. Chinese Chemical Letters, 2025, 36(2): 109586-. doi: 10.1016/j.cclet.2024.109586
7. [7]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
8. [8]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
9. [9]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
10. [10]
  Yuan ZHU , Xiaoda ZHANG , Shasha WANG , Peng WEI , Tao YI . Conditionally restricted fluorescent probe for Fe³⁺ and Cu²⁺ based on the naphthalimide structure. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232
11. [11]
  Yanqiong Wang , Yaqi Hou , Fengwei Huo , Xu Hou . Fe³⁺ ion quantification with reusable bioinspired nanopores. Chinese Chemical Letters, 2025, 36(2): 110428-. doi: 10.1016/j.cclet.2024.110428
12. [12]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
13. [13]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
14. [14]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
15. [15]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
16. [16]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
17. [17]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
18. [18]
  Jiahao Li , Guinan Chen , Chunhong Chen , Yuanyuan Lou , Zhihao Xing , Tao Zhang , Chengtao Gong , Yongwu Peng . Modulated synthesis of stoichiometric and sub-stoichiometric two-dimensional covalent organic frameworks for enhanced ethylene purification. Chinese Chemical Letters, 2025, 36(1): 109760-. doi: 10.1016/j.cclet.2024.109760
19. [19]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
20. [20]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(1367)
HTML views(209)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142