Citation: Jinjin Li, Congcong Liu, Jingjiang Wei, Yuantao Yan, Xiaoli Zhao, Xiaowei Yang. Morphology mediation of MoS₂ nanosheets with organic cations for fast sodium ion storage[J]. Chinese Chemical Letters, ;2021, 32(2): 880-884. doi: 10.1016/j.cclet.2020.06.036 shu

Morphology mediation of MoS₂ nanosheets with organic cations for fast sodium ion storage

School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

zxl36@tongji.edu.cn

Received Date: 10 May 2020
Revised Date: 21 June 2020
Accepted Date: 25 June 2020
Available Online: 25 June 2020

Figures(4)

Ion diffusion kinetics, depending on the size, tortuosity, connectivity of the channels, greatly affects the rate performance of the electrodes. Two-dimensional materials (2DMs) has emerged as promising electrode materials in the past decades. However, the applications of 2DMs electrodes are limited by the strong restacking problem, which leads to a poor rate capability. In this work, we for the first time mediated the morphology of molybdenum disulfide (MoS₂) nanosheets via a facile coagulation method; abundant sheet crumples were induced, which greatly enhance their surface accessibility and thus benefit the ion diffusion kinetics. Consequently, the crumpled-MoS₂ electrodes follow a capacitive Na-ion charge-storage mechanism to a large extent. Importantly, we demonstrate the special role of organic cations in the inter-sheet assembly configuration, in sharp contrast with that of alkali/alkaline-earth ones. We propose that organic cations cause edge/face contact of the sheets, instead of the face/face contact, thus affording a house-of-cards structure.
- Ion diffusion kinetics,
- Crumpled MoS₂ nanosheets,
- Anti-restacking,
- Organic cations,
- Na-ion storage
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Morphology mediation of MoS₂ nanosheets with organic cations for fast sodium ion storage