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Citation: Weipeng Chen, Guojun Zhou, Zhuolun Gou, Sen Wang, Yuanqi Zhai, Tian Han, Jürgen Schnack, Yanzhen Zheng. Hendecanuclear [Cu6Gd5] magnetic cooler with high molecular symmetry of D3h[J]. Chinese Chemical Letters, ;2021, 32(2): 838-841. doi: 10.1016/j.cclet.2020.05.018 shu

Hendecanuclear [Cu6Gd5] magnetic cooler with high molecular symmetry of D3h

  • a.

    Shenzhen Research School and Frontier Institute of Science and Technology (FIST), State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis of Condensed Matter, Xi'an Key Laboratory of Sustainable Energy and Materials Chemistry and School of Science, Xi'an Jiaotong University, Xi'an 710054, China

  • b.

    School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

  • c.

    Faculty of Physics, Bielefeld University, D-33501 Bielefeld, PO Box 100131, Germany

    * Corresponding authors.
    E-mail addresses: jschnack@uni-bielefeld.de (J. Schnack), zheng.yanzhen@xjtu.edu.cn (Y. Zheng).
    1 These authors contributed equally to this work.
  • Received Date: 5 March 2020
    Revised Date: 15 April 2020
    Accepted Date: 13 May 2020
    Available Online: 17 May 2020

Figures(4)

  • A new family of isostructural 3d-4f polymetallic complexes, formulated as [Cu6Ln5(μ3−OH)9 (C4H8O2N)6(C5H4ON)6(H2O)9]·(ClO4)6·(H2O)22 (Ln = Pr, 1; Nd, 2; Sm, 3; Eu, 4; Gd, 5), was successfully isolated through the simple hydrolysis reaction of 2-aminoisobutyric acid, 2-hydroxypyridine, Cu(CH3COO)2·H2O, and Ln(ClO4)3·6H2O. Notably, the [Cu6Ln5] clusters with high molecular symmetry of D3h are rare examples of 2-aminoisobutyric acid-based 3d-4f clusters. The successful theoretical modeling of 5 yielded that the Gd-Gd exchange is of order 0.2 K, whereas the Gd-Cu exchange is an order of magnitude larger. Magnetization data collected for complex 5 yield a magnetic entropy change (−ΔSm) of 19.6 J kg−1 K−1 at 3 K and 7 T, which may be attributed to the weak magnetic interactions between the component metal ions.
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