Citation: Aiqin Xiang, Shuai Xie, Fei Pan, Hongchang Jin, Yiheng Zhai, Yanwu Zhu, Xianghua Kong, Hengxing Ji. Cobalt and nitrogen atoms co-doped porous carbon for advanced electrical double-layer capacitors[J]. Chinese Chemical Letters, ;2021, 32(2): 830-833. doi: 10.1016/j.cclet.2020.04.058 shu

Cobalt and nitrogen atoms co-doped porous carbon for advanced electrical double-layer capacitors

Aiqin Xiang ^a ,
Shuai Xie ^b ,
Fei Pan ^c ,
Hongchang Jin ^b ,
Yiheng Zhai ^a ,
Yanwu Zhu ^c ,
Xianghua Kong ^{a, d, *,} ,
Hengxing Ji ^{b, **,}

a.
School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, China
b.
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Applied Chemistry, University of Science and Technology of China, Hefei 230026, China
c.
Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
d.
CAS Key Laboratory of Materials for Energy Conversion, Hefei 230026, China

^**

kongxh@hfut.edu.cn

jihengx@ustc.edu.cn

Received Date: 17 February 2020
Revised Date: 19 April 2020
Accepted Date: 30 April 2020
Available Online: 11 May 2020

Figures(4)

Electrical double-layer capacitors are widely concerned for their high power density, long cycling life and high cycling efficiency. However, their wide application is limited by their low energy density. In this study, we propose a simple yet environmental friendly method to synthesize cobalt and nitrogen atoms co-doped porous carbon (CoAT-NC) material. Cobalt atoms connected with primarily pyridinic nitrogen atoms can be uniformly dispersed in the amorphous carbon matrix, which is benefit for improving electrical conductivity and density of states of the carbon material. Therefore, an enhanced performance is expected when CoAT-NC is served as electrode in a supercapacitor device. CoAT-NC displays a good gravimetric capacitance of 160 F/g at 0.5 A/g combing with outstanding capacitance retention of 90% at an extremely high current density of 100 A/g in acid electrolyte. Furthermore, a good energy density of 30 Wh/kg can be obtained in the organic electrolyte.
- Electrical double-layer capacitors,
- Cobalt atoms,
- Pyridinic nitrogen,
- Co-doped,
- Density of states
1. [1]
  D.Y. Qu, H. Shi, J. Power Sources 74 (1998) 99-107. doi: 10.1016/S0378-7753(98)00038-X
2. [2]
  T. Brezesinski, J. Wang, S.H. Tolbert, et al., Nat. Mater. 9 (2010) 146-151. doi: 10.1038/nmat2612
3. [3]
  P. Simon, Y. Gogotsi, Nat. Mater. 7 (2008) 845-854. doi: 10.1038/nmat2297
4. [4]
  Y. Gong, D. Li, C. Luo, et al., Green Chem. 19 (2017) 4132-4140. doi: 10.1039/C7GC01681F
5. [5]
  M. Yang, Z. Zhou, Adv. Sci. 4 (2017) 1600408. doi: 10.1002/advs.201600408
6. [6]
  L.L. Zhang, X.S. Zhao, Chem. Soc. Rev. 38 (2009) 2520-2531. doi: 10.1039/b813846j
7. [7]
  R. Chen, F. Wu, L. Li, et al., J. Phys. Chem. C 111 (2007) 5184-5194. doi: 10.1021/jp066429f
8. [8]
  H. Ji, X. Zhao, Z. Qiao, et al., Nat. Commun. 5 (2014) 3317. doi: 10.1038/ncomms4317
9. [9]
  F. Beguin, V. Presser, A. Balducci, et al., Adv. Mater. 26 (2014) 2219-2251. doi: 10.1002/adma.201304137
10. [10]
  L.L. Zhang, Y. Gu, X.S. Zhao, J. Mater. Chem. A 1 (2013) 9395-9408. doi: 10.1039/c3ta11114h
11. [11]
  L. Zhang, F. Zhang, X. Yang, et al., Sci. Rep. UK 3 (2013) 1408. doi: 10.1038/srep01408
12. [12]
  J. Lee, J. Kim, T. Hyeon, Adv. Mater. 18 (2006) 2073-2094. doi: 10.1002/adma.200501576
13. [13]
  Y. Xu, G. Shi, X. Duan, Acc. Chem. Res. 48 (2015) 1666-1675. doi: 10.1021/acs.accounts.5b00117
14. [14]
  X. Wang, Y. Zhang, C. Zhi, et al., Nat. Commun. 4 (2013) 2905. doi: 10.1038/ncomms3905
15. [15]
  Y. Zhu, S. Murali, M.D. Stoller, et al., Science 332 (2011) 1537-1541. doi: 10.1126/science.1200770
16. [16]
  J. Chmiola, G. Yushin, Y. Gogotsi, et al., Science 313 (2006) 1760-1763. doi: 10.1126/science.1132195
17. [17]
  J. Chen, Y. Han, X. Kong, et al., Angew. Chem. Int. Ed. 55 (2016) 13822-13827. doi: 10.1002/anie.201605926
18. [18]
  Z. Du, X. Chen, W. Hu, et al., J. Am. Chem. Soc. 141 (2019) 3977-3985. doi: 10.1021/jacs.8b12973
19. [19]
  H. Tong, S. Yue, F. Jin, et al., Ceram. Int. 44 (2018) 3113-3121. doi: 10.1016/j.ceramint.2017.11.078
20. [20]
  W. Zhang, C. Xu, C. Ma, et al., Adv. Mater. 29 (2017) 1701677. doi: 10.1002/adma.201701677
21. [21]
  M. Liu, J. Niu, Z. Zhang, et al., Nano Energy 51 (2018) 366-372. doi: 10.1016/j.nanoen.2018.06.037
22. [22]
  J. Xu, Z. Tan, W. Zeng, et al., Adv. Mater. 28 (2016) 5222-5228. doi: 10.1002/adma.201600586
23. [23]
  Q.S. Huang, P.J. Zhou, H. Yang, et al., Electrochim. Acta 232 (2017) 339-347. doi: 10.1016/j.electacta.2017.02.163
24. [24]
  Y. Liu, L. Yu, X. Jiang, et al., Int. J. Energy Res. 43 (2019) 4217-4228. doi: 10.1002/er.4546
25. [25]
  H. Fei, J. Dong, M.J. Arellano-Jiménez, et al., Nat. Commun. 6 (2015) 8668. doi: 10.1038/ncomms9668
26. [26]
  E.S. Andreiadis, P.-A. Jacques, P.D. Tran, et al., Nat. Chem. 5 (2013) 48-53. doi: 10.1038/nchem.1481
27. [27]
  Y. Jiao, Y. Zheng, P. Chen, et al., J. Am. Chem. Soc. 139 (2017) 18093-18100. doi: 10.1021/jacs.7b10817
28. [28]
  Y. Zheng, Y. Jiao, Y. Zhu, et al., J. Am. Chem. Soc. 139 (2017) 3336-3339. doi: 10.1021/jacs.6b13100
29. [29]
  A. Wang, J. Li, T. Zhang, Int. Rev. Chem. Eng. 2 (2018) 65-81.
30. [30]
  T. Purkait, G. Singh, M. Singh, et al., Sci. Rep. UK 7 (2017) 15239. doi: 10.1038/s41598-017-15463-w
31. [31]
  X. Sun, J. Ye, F. Pan, et al., New J. Chem. 42 (2018) 12421-12428. doi: 10.1039/C8NJ01788C
32. [32]
  M. Sevilla, A.B. Fuertes, ACS Nano 8 (2014) 5069-5078. doi: 10.1021/nn501124h
1. [1]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
2. [2]
  Juhong Zhou , Hui Zhao , Ping Han , Ziyue Wang , Yan Zhang , Xiaoxia Mao , Konglin Wu , Shengjue Deng , Wenxiang He , Binbin Jiang . Strategic modulation of CoFe sites for advanced bifunctional oxygen electrocatalyst. Chinese Journal of Structural Chemistry, 2025, 44(1): 100470-100470. doi: 10.1016/j.cjsc.2024.100470
3. [3]
  Sushu Zhang , Yang Yang , Jingyu Wang . Pyridinic nitrogen-substituted graphene membranes for exceptional CO2 capture. Chinese Journal of Structural Chemistry, 2025, 44(2): 100440-100440. doi: 10.1016/j.cjsc.2024.100440
4. [4]
  Yanhui Lu , Chengang Pei , Wenqiang Li , Qing Liu , Huan Pang , Xu Yu . Tailoring active sites of cerium and nitrogen Co-doped rhenium disulfide for enhanced hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(12): 111646-. doi: 10.1016/j.cclet.2025.111646
5. [5]
  Yining Li , Shimei Wu , Lantao Chen , Haosen Fan , Yufei Zhang , Lingxing Zeng . Multiple yolks-shell cobalt phosphosulfide nanocrystals encapsulating into rich heteroatoms co-doped carbon frameworks for advanced sodium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(9): 110371-. doi: 10.1016/j.cclet.2024.110371
6. [6]
  Jiahao Xie , Jin Liu , Bin Liu , Xin Meng , Zhuang Cai , Xiaoqin Xu , Cheng Wang , Shijie You , Jinlong Zou . Yolk shell-structured pyrite-type cobalt sulfide grafted by nitrogen-doped carbon-needles with enhanced electrical conductivity for oxygen electrocatalysis. Chinese Chemical Letters, 2024, 35(7): 109236-. doi: 10.1016/j.cclet.2023.109236
7. [7]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
8. [8]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
9. [9]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
10. [10]
  Junmei FAN , Wei LIU , Ruitao ZHU , Chenxi QIN , Xiaoling LEI , Haotian WANG , Jiao WANG , Hongfei HAN . High sensitivity detection of baicalein by N, S co-doped carbon dots and their application in biofluids. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2009-2020. doi: 10.11862/CJIC.20240120
11. [11]
  Hangwen Zheng , Ziqian Wang , HuiJie Zhang , Jing Lei , Rihui Li , Jian Yang , Haiyan Wang . Synthesis and applications of B, N co-doped carbons for zinc-based energy storage devices. Chinese Chemical Letters, 2025, 36(3): 110245-. doi: 10.1016/j.cclet.2024.110245
12. [12]
  Xuehua SUN , Min MA , Jianting LIU , Rui TIAN , Hongmei CHAI , Huali CUI , Loujun GAO . Pr/N co-doped biomass carbon dots with enhanced fluorescence for efficient detection of 2,4-dinitrophenylhydrazine. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 561-573. doi: 10.11862/CJIC.20240294
13. [13]
  Menglin Zhou , Lin Zhang , Xuefei Shan , Fengqin Chang , Wentong Chen , Xuguang An , Guangzhi Hu . Hydrangea-like B/N co-doped carbon-based electrochemical sensors for the efficient and sensitive detection of aristolochic acid in Aristolochia. Chinese Chemical Letters, 2025, 36(12): 111073-. doi: 10.1016/j.cclet.2025.111073
14. [14]
  Guanjun Chen , Jiayi Yang , Zheming Huang , Long Chen , Wenyuan Duan , Tong Wang , Xingang Kong , Haibo Yang . Engineering the interlayer sodium density in layered sodium cobalt oxide for boosted chlorine evolution reaction. Chinese Chemical Letters, 2025, 36(12): 111662-. doi: 10.1016/j.cclet.2025.111662
15. [15]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
16. [16]
  Xiujuan Wang , Yijie Wang , Luyun Cui , Wenqiang Gao , Xiao Li , Hong Liu , Weijia Zhou , Jingang Wang . Coordination-based synthesis of Fe single-atom anchored nitrogen-doped carbon nanofibrous membrane for CO₂ electroreduction with nearly 100% CO selectivity. Chinese Chemical Letters, 2024, 35(12): 110031-. doi: 10.1016/j.cclet.2024.110031
17. [17]
  Yu Pang , Min Wang , Ning-Hua Yang , Min Xue , Yong Yang . One-pot synthesis of a giant twisted double-layer chiral macrocycle via [4 + 8] imine condensation and its X-ray structure. Chinese Chemical Letters, 2024, 35(10): 109575-. doi: 10.1016/j.cclet.2024.109575
18. [18]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
19. [19]
  Xiaodan Wang , Yingnan Liu , Zhibin Liu , Zhongjian Li , Tao Zhang , Yi Cheng , Lecheng Lei , Bin Yang , Yang Hou . Highly efficient electrosynthesis of H₂O₂ in acidic electrolyte on metal-free heteroatoms co-doped carbon nanosheets and simultaneously promoting Fenton process. Chinese Chemical Letters, 2024, 35(7): 108926-. doi: 10.1016/j.cclet.2023.108926
20. [20]
  Yuanhua Xiao , Jinhui Shou , Shiwei Zhang , Ya Shen , Junwei Liu , Dangcheng Su , Yang Kong , Xiaodong Jia , Qingxiang Yang , Shaoming Fang , Xuezhao Wang . Synergistic interlayer confinement and built-in electric field construct reconstruction-inhibited cobalt selenide for robust oxygen evolution at high current density. Chinese Chemical Letters, 2025, 36(11): 111441-. doi: 10.1016/j.cclet.2025.111441

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(2180)
HTML views(162)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142