Citation: Fu-Sheng He, Shimin Xie, Yanfang Yao, Jie Wu. Recent advances in the applications of [1.1.1]propellane in organic synthesis[J]. Chinese Chemical Letters, ;2020, 31(12): 3065-3072. doi: 10.1016/j.cclet.2020.04.023 shu

Recent advances in the applications of [1.1.1]propellane in organic synthesis

Fu-Sheng He ^{a, 1} ,
Shimin Xie ^{b, 1} ,
Yanfang Yao ^a ,
Jie Wu ^{a, c, *,}

a.
School of Pharmaceutical and Materials Engineering &Institute for Advanced Studies, Taizhou University, Taizhou 318000, China
b.
College of Chemistry, Xiangtan University, Xiangtan 411105, China
c.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

jie_wu@fudan.edu.cn

Received Date: 16 March 2020
Revised Date: 27 March 2020
Accepted Date: 12 April 2020
Available Online: 19 April 2020

Figures(23)

As a highly strained small molecule, [1.1.1]propellane has been widely used in various synthetic transformations owing to the exceptional reactivity of the central bond between the two bridgehead carbons. Utilizing strain-release approaches, the rapid development of strategies for the construction of bicyclo[1.1.1]pentane (BCP) and cyclobutane derivatives using [1.1.1]propellane as the starting material has been witnessed in the past few years. In this review, we highlight the most recent advances in this field. Accordingly, the reactivity of [1.1.1]propellane can be divided into three pathways, including radical, anionic and transition metal-catalyzed pathways under appropriate conditions.
- [1.1.1]Propellane,
- Bicyclo[1.1.1]pentane,
- Cyclobutane,
- Radical,
- Transition metal catalysis,
- Photocatalyst
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