Citation: Shu Song, Wang Peng, Zhang Wendong, Wang Weilu, Li Jianjun, Chu Yinghao, Wei Fusheng, Zhang Xianming, Jiang Guangming. Pd nanoparticles on defective polymer carbon nitride: Enhanced activity and origin for electrocatalytic hydrodechlorination reaction[J]. Chinese Chemical Letters, ;2020, 31(10): 2762-2768. doi: 10.1016/j.cclet.2020.04.022 shu

Pd nanoparticles on defective polymer carbon nitride: Enhanced activity and origin for electrocatalytic hydrodechlorination reaction

Shu Song ^a,1 ,
Wang Peng ^a,1 ,
Zhang Wendong ^c ,
Wang Weilu ^b ,
Li Jianjun ^a ,
Chu Yinghao ^a,*, ,
Wei Fusheng ^a ,
Zhang Xianming ^b ,
Jiang Guangming ^b,*,

a.
College of Architecture and Environment, Sichuan University, Chengdu 610065, China
b.
Engineering Research Center for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing 400067, China
c.
Chongqing Key Laboratory of Three Gorges Reservoir Area Surface Process and Environmental Remote Sensing, Chongqing Key Laboratory of Inorganic Functional Materials, Chongqing Normal University, Chongqing 401331, China

chuyinghao@scu.edu.cn

jiangguangming@zju.edu.cn

Received Date: 14 January 2020
Revised Date: 30 March 2020
Accepted Date: 2 April 2020
Available Online: 20 April 2020

Figures(4)

Here we report a facile defect-engineering strategy on the support to optimize the metal-support interaction and enhance the metal's electrocatalytic hydrodechlorination performance in converting 2, 4-dichlorophenol (2, 4-DCP) to phenol. The specific activity of the Pd nanoparticles (Pd NPs) on defective polymer carbon nitride (Pd/PCN-x) reaches 0.09 min^-1 m^-2_Pd, which is 1.5 times that of the Pd NPs supported on the perfect PCN (Pd/PCN-0). The combined experimental and theoretical results demonstrate that the strong adsorption of phenol on Pd/PCN-0 passivates the active sites, limiting the dechlorination progress. The PCN-x containing -C≡N defects can effectively mediate the spatial configuration and electronic structure of Pd NPs, and promote the preferential adsorption of 2, 4-DCP rather than phenol, resulting in an enhanced dechlorination efficiency.
- Hydrodechlorination,
- Electrocatalysis,
- Adsorption properties,
- Metal-support interaction,
- N defects
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