Citation: Tan Junjiang, Hu Jinyong, Ren Jianxu, Peng Jinfeng, Liu Can, Song Yiqiao, Zhang Yong. Fast response speed of mechanically exfoliated MoS₂ modified by PbS in detecting NO₂[J]. Chinese Chemical Letters, ;2020, 31(8): 2103-2108. doi: 10.1016/j.cclet.2020.03.060 shu

Fast response speed of mechanically exfoliated MoS₂ modified by PbS in detecting NO₂

Tan Junjiang ^a ,
Hu Jinyong ^a,*, ,
Ren Jianxu ^a ,
Peng Jinfeng ^c ,
Liu Can ^a ,
Song Yiqiao ^a ,
Zhang Yong ^a,b,*,

a.
School of Physics and Optoelectronics, Xiangtan University, Xiangtan 411105, China
b.
Hunan Institute of Advanced Sensing and Information Technology, Xiangtan University, Xiangtan 411105, China
c.
School of Mechanical Engineering, Xiangtan University, Xiangtan 411105, China

jyhu_233@xtu.edu.cn

zhangyong@xtu.edu.cn

Received Date: 3 March 2020
Revised Date: 20 March 2020
Accepted Date: 23 March 2020
Available Online: 4 April 2020

Figures(5)

MoS₂, acting as a promising gas sensing material, has shown huge potential in monitoring of toxic and harmful gases at room temperature. However, MoS₂-based gas sensors still suffer from poor gas sensing performance such as poor sensitivity, long response time. Constructing the heterostructure is an effective approach to improve gas-sensing performance of MoS₂. Herein, PbS@MoS₂ composites synthesized by mechanical exfoliation combining with wet-chemical precipitation are used to investigate its performance in detecting NO₂ at room temperature. The response value of PbS@MoS₂ gas sensor against NO₂ is significantly improved compared with the pure MoS₂ gas sensor. At the same time, the modification with PbS also accelerates the response speed of MoS₂, and the response time is almost reduced by two orders of magnitude, from hundreds of seconds to less than ten seconds. The enhanced response value and fast response time are mainly benefited from the modulation effect of NO₂ to PbS@MoS₂ heterostructure and the mechanically exfoliated MoS₂ surface with few defects. This work can be expected to provide useful guidance for designing composite materials with excellent gas sensing properties.
- Mechanically exfoliated MoS₂ nanosheets,
- PbS@MoS₂ heterostructure,
- Fast response speed,
- Room-temperature detection,
- NO₂ sensing properties
1. [1]
  X.H. Liu, T.T. Ma, N. Pinna, J. Zhang, Adv. Funct. Mater. 27(2017) 1702168. doi: 10.1002/adfm.201702168
2. [2]
  K. Lee, R. Gatensby, N. McEvoy, T. Hallam, G.S. Duesberg, Adv. Mater. 25(2013) 6699-6702. doi: 10.1002/adma.201303230
3. [3]
  H. Li, Z. Yin, Q. He, et al., Small 8(2012) 63-67. doi: 10.1002/smll.201101016
4. [4]
  T.T. Xu, Y.Y. Pei, Y.Y. Liu, et al., J. Alloys Compd. 725(2017) 253-259. doi: 10.1016/j.jallcom.2017.06.105
5. [5]
  X. Yu, D. Wang, Y.Q. Wang, J. Yan, X.Y. Wang, Chin. Chem. Lett. (2019), doi: http://dx.doi.org/10.1016/j.cclet.2019.11.032. doi: 10.1016/j.cclet.2019.11.032
6. [6]
  S.M. Cui, Z.H. Wen, X.K. Huang, J.B. Chang, J.H. Chen, Small 11(2015) 2305-2313. doi: 10.1002/smll.201402923
7. [7]
  X. Xin, Y. Zhang, X.X. Guan, et al., ACS Appl. Mater. Interfaces 11(2019) 9438-9447. doi: 10.1021/acsami.8b20984
8. [8]
  B. Chen, E.Z. Liu, F. He, et al., Nano Energy 26(2016) 541-549. doi: 10.1016/j.nanoen.2016.06.003
9. [9]
  S. Zhang, H. Yang, H. Gao, et al., ACS Appl. Mater. Interfaces 9(2017) 23635-23646. doi: 10.1021/acsami.7b03673
10. [10]
  D.Z. Wang, Z. Pan, Z.Z. Wu, Z.P. Wang, Z.H. Liu, J. Power Sources 264(2014) 229-234. doi: 10.1016/j.jpowsour.2014.04.066
11. [11]
  M.Y. Li, C.H. Chen, Y.M. Shi, L.J. Li, Mater. Today 19(2016) 322-335. doi: 10.1016/j.mattod.2015.11.003
12. [12]
  H. Li, J. Wu, Z. Yin, H. Zhang, Acc. Chem. Res. 47(2014) 1067-1075. doi: 10.1021/ar4002312
13. [13]
  W. Li, Y. Zhang, X. Long, et al., Sensors 19(2019) 2123. doi: 10.3390/s19092123
14. [14]
  Q. Zhang, H. Zhang, M.K. Xu, Z.R. Shen, Q. Wei, Chin. Chem. Lett. 29(2018) 538-542. doi: 10.1016/j.cclet.2017.09.018
15. [15]
  C. Li, Z.S. Yu, S.M. Fang, et al., Chin. Chem. Lett. 19(2008) 599-603. doi: 10.1016/j.cclet.2008.03.032
16. [16]
  H.Q. Cao, G.Z. Wang, S.C. Zhang, X.R. Zhang, Nanotechnology 17(2006) 3280-3287. doi: 10.1088/0957-4484/17/13/034
17. [17]
  J.P. Ge, J. Wang, H.X. Zhang, et al., Chemistry 11(2005) 1889-1894. doi: 10.1002/chem.200400633
18. [18]
  M. Shkir, M.T. Khan, A. Khan, et al., Mater. Sci. Semicond. Process. 96(2019) 16-23. doi: 10.1016/j.mssp.2019.02.020
19. [19]
  M. Shkir, S. AlFaify, V. Ganeshi, S. Yahia, Solid State Sci. 70(2017) 81-85. doi: 10.1016/j.solidstatesciences.2017.06.006
20. [20]
  F. Gode, O. Baglayan, E. Guneri, Chalcogenide Lett. 12(2015) 519-528.
21. [21]
  T. Guo, L.N. Wang, S. Sun, et al., Chin. Chem. Lett. 30(2019) 1253-1260. doi: 10.1016/j.cclet.2019.02.009
22. [22]
  H. Li, Q. Zhang, C.C.R. Yap, et al., Adv. Funct. Mater. 22(2012) 1385-1390. doi: 10.1002/adfm.201102111
23. [23]
  Y. Zhang, H.F. Zou, J.F. Peng, et al., Sens. Actuator. B-Chem. 272(2018) 459-467. doi: 10.1016/j.snb.2018.06.007
24. [24]
  C.J. Han, Z. Tian, H.L. Dou, X.M. Wang, X.W. Yang, Chin. Chem. Lett. 29(2018) 606-611. doi: 10.1016/j.cclet.2018.01.017
25. [25]
  Y.Y. Hu, Y.L. Bai, X.Y. Wu, et al., J. Alloys Compd. 797(2019) 1126-1132. doi: 10.1016/j.jallcom.2019.05.142
26. [26]
  J. Muscat, C. Klauber, Surf. Sci. 491(2001) 226-238. doi: 10.1016/S0039-6028(01)01408-X
27. [27]
  H. Ji, C. Liu, T. Wang, et al., Small 11(2015) 6480-6490. doi: 10.1002/smll.201502355
28. [28]
  C.Y. Zhai, M.S. Zhu, D. Bin, et al., J. Power Sources 275(2015) 483-488. doi: 10.1016/j.jpowsour.2014.11.030
29. [29]
  X.Y. Lin, J. Wang, Z.Y. Chu, et al., Chin. Chem. Lett. 31(2020) 1124-1128. doi: 10.1016/j.cclet.2019.07.003
30. [30]
  O.A. Castelo-González, M. Sotelo-Lerma, J.A. García-Valenzuela, J. Korean Inst. Electr. Electron. Mater. Eng. 46(2016) 393-400.
31. [31]
  K. Wan, D. Wang, F. Wang, et al., ACS Appl. Mater. Interfaces 11(2019) 45214-45225. doi: 10.1021/acsami.9b16599
32. [32]
  Y. Han, D. Huang, Y. Ma, et al., ACS Appl. Mater. Interfaces 10(2018) 22640-22649. doi: 10.1021/acsami.8b05811
33. [33]
  H.F. Li, G.Z. Lu, Q.G. Dai, et al., Appl. Catal. B 102(2011) 475-483. doi: 10.1016/j.apcatb.2010.12.029
34. [34]
  H. Long, A. Harley-Trochimczyk, T. Pham, et al., Adv. Funct. Mater. 26(2016) 5158-5165. doi: 10.1002/adfm.201601562
35. [35]
  H.L. Tai, Z.H. Duan, Z.Z. He, et al., Sens. Actuator. B-Chem. 298(2019) 126874. doi: 10.1016/j.snb.2019.126874
36. [36]
  A. Mosahebfard, H.D. Jahromi, M.H. Sheikhi, IEEE Sens. J.16(2016) 4174-4179. doi: 10.1109/JSEN.2016.2546966
37. [37]
  P. Salimi kuchi, H. Roshan, M.H. Sheikhi, J. Alloys Compd. 816(2020) 152666. doi: 10.1016/j.jallcom.2019.152666
38. [38]
  X. Gao, F. Li, R. Wang, T. Zhang, Sens. Actuator. B-Chem. 258(2018) 1230-1241. doi: 10.1016/j.snb.2017.11.088
39. [39]
  E. Wu, Y. Xie, B. Yuan, et al., ACS Appl. Mater. Interfaces 10(2018) 35664-35669. doi: 10.1021/acsami.8b14142
40. [40]
  S.W. Choi, A. Katoch, J.H. Kim, S.S. Kim, ACS Appl. Mater. Interfaces 6(2014) 17723-17729. doi: 10.1021/am504164j
41. [41]
  D.X. Ju, H.Y. Xu, Q. Xu, et al., Sens. Actuator. B-Chem. 215(2015) 39-44. doi: 10.1016/j.snb.2015.03.015
42. [42]
  D. Zhang, C. Jiang, P. Li, Y. Sun, ACS Appl. Mater. Interfaces 9(2017) 6462-6471. doi: 10.1021/acsami.6b15669
43. [43]
  S.J. Zhao, J.M. Xue, W. Kang, Chem. Phys. Lett. 595-596(2014) 35-42.
44. [44]
  B. Cho, M.G. Hahm, M. Choi, et al., Sci. Rep. 5(2015) 8052. doi: 10.1038/srep08052
1. [1]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
2. [2]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
3. [3]
  Junan Pan , Xinyi Liu , Huachao Ji , Yanwei Zhu , Yanling Zhuang , Kang Chen , Ning Sun , Yongqi Liu , Yunchao Lei , Kun Wang , Bao Zang , Longlu Wang . The strategies to improve TMDs represented by MoS₂ electrocatalytic oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(11): 109515-. doi: 10.1016/j.cclet.2024.109515
4. [4]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
5. [5]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
6. [6]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
7. [7]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
8. [8]
  Dian-Xue Ma , Yu-Wu Zhong . Achieving highly-efficient room-temperature phosphorescence with a nylon matrix. Chinese Journal of Structural Chemistry, 2024, 43(9): 100391-100391. doi: 10.1016/j.cjsc.2024.100391
9. [9]
  Jiayin Zhou , Depeng Liu , Longqiang Li , Min Qi , Guangqiang Yin , Tao Chen . Responsive organic room-temperature phosphorescence materials for spatial-time-resolved anti-counterfeiting. Chinese Chemical Letters, 2024, 35(11): 109929-. doi: 10.1016/j.cclet.2024.109929
10. [10]
  Cuiwu MO , Gangmin ZHANG , Chao WU , Zhipeng HUANG , Chi ZHANG . A(NH₂SO₃) (A=Li, Na): Two ultraviolet transparent sulfamates exhibiting second harmonic generation response. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1387-1396. doi: 10.11862/CJIC.20240045
11. [11]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
12. [12]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453
13. [13]
  Shengwen Guan , Zhaotong Wei , Ningxu Han , Yude Wei , Bin Xu , Ming Wang , Junjuan Shi . Construction of metallo-complexes with 2,2′:6′,2″-terpyridine substituted triphenylamine in different modified positions and their photophysical properties. Chinese Chemical Letters, 2024, 35(7): 109348-. doi: 10.1016/j.cclet.2023.109348
14. [14]
  Ying Zhao , Yin-Hang Chai , Tian Chen , Jie Zheng , Ting-Ting Li , Francisco Aznarez , Li-Long Dang , Lu-Fang Ma . Size-controlled synthesis and near-infrared photothermal response of Cp* Rh-based metalla[2]catenanes and rectangular metallamacrocycles. Chinese Chemical Letters, 2024, 35(6): 109298-. doi: 10.1016/j.cclet.2023.109298
15. [15]
  Xing Xiao , Yunling Jia , Wanyu Hong , Yuqing He , Yanjun Wang , Lizhi Zhao , Huiqin An , Zhen Yin . Sulfur-defective ZnIn2S4 nanosheets decorated by TiO2 nanosheets with exposed {001} facets to accelerate charge transfer for efficient photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100474-100474. doi: 10.1016/j.cjsc.2024.100474
16. [16]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
17. [17]
  Haohao Sun , Wenxuan Wang , Yuli Xiong , Zelang Jian , Wen Chen . Boosting the electrochromic properties by large V₂O₅ nanobelts interlayer spacing tuned via PEDOT. Chinese Chemical Letters, 2024, 35(9): 109213-. doi: 10.1016/j.cclet.2023.109213
18. [18]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
19. [19]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
20. [20]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(610)
HTML views(20)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fast response speed of mechanically exfoliated MoS2 modified by PbS in detecting NO2

Metrics

通讯作者: 陈斌, bchen63@163.com

Fast response speed of mechanically exfoliated MoS₂ modified by PbS in detecting NO₂