Citation: Yufeng Cao, Yanmei Chen, Zhecheng Zhang, Jin Wang, Xiaolei Yuan, Qin Zhao, Yue Ding, Yong Yao. CO₂ and photo-controlled reversible conversion of supramolecular assemblies based on water soluble pillar[5]arene and coumarin-containing guest[J]. Chinese Chemical Letters, ;2021, 32(1): 349-352. doi: 10.1016/j.cclet.2020.03.058 shu

CO₂ and photo-controlled reversible conversion of supramolecular assemblies based on water soluble pillar[5]arene and coumarin-containing guest

School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China

zhao.q@ntu.edu.cn

yaoyong1986@ntu.edu.cn

Received Date: 8 February 2020
Revised Date: 14 March 2020
Accepted Date: 23 March 2020
Available Online: 27 March 2020

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In this communication, a new supramolecualr amphiphile was successfully constructed based on water soluble pillar[5]arene and a unique guest which contain a CO₂ responsive tertiary amine unit and a UV responsive coumarin group. When guest molecule 1 dispersed in water, it self-assembled into sheet-like structures. Upon bubbling CO₂, 1 transformed into 1H due to the tertiary amine unit was protonated, accompany the nano-sheets transformed into vesicles. Further irradiation of 1H with 365 nm light for 3 h, the coumarin group reacted with each other to form bola-type amphiphie 2H. In this case, vesicles collapsed and re-assembled into nano-tubes. However, when addition of WP5 into the solution of 1H, the vesicles transformed into micelles, this is due to the formation of supramolecular amphiphile WP5&1H. Upon irradiation of WP5&1H with 365 nm light for 3 h, nano-ribbons observed instead of micelles in the solution. Notably, nanotubes from 2H could also transform into nano-ribbons after adding WP5. The self-assembly process and the resultant assemblies were characterized by TEM, SEM, DLS, SAXS and NMR technologies. Due to both CO₂ and light are pgreenq for living organisms, we anticipated our system can offer the possibilities in pon demandq drug absorption and release.
- Pillar[5]arene,
- Supramolecular assemblies,
- Amphiphiles,
- Reversible conversion,
- Coumarin
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CO2 and photo-controlled reversible conversion of supramolecular assemblies based on water soluble pillar[5]arene and coumarin-containing guest

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通讯作者: 陈斌, bchen63@163.com

CO₂ and photo-controlled reversible conversion of supramolecular assemblies based on water soluble pillar[5]arene and coumarin-containing guest