Citation: Xia Liu, Xiaoping Yang, Yanan Ma, Jieni Liu, Dongliang Shi, Desmond Schipper. Construction of a nano-rectangular Zn-Nd complex with near-infrared luminescent response towards metal ions[J]. Chinese Chemical Letters, ;2021, 32(1): 569-572. doi: 10.1016/j.cclet.2020.03.016 shu

Construction of a nano-rectangular Zn-Nd complex with near-infrared luminescent response towards metal ions

Xia Liu ^a ,
Xiaoping Yang ^{a, b, *,} ,
Yanan Ma ^a ,
Jieni Liu ^a ,
Dongliang Shi ^a ,
Desmond Schipper ^c

a.
College of Chemistry and Materials Engineering, Zhejiang Key Laboratory of Carbon Materials, Wenzhou University, Wenzhou 325035, China
b.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001, China
c.
Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin 78712, United States

xpyang@wzu.edu.cn

Received Date: 2 February 2020
Revised Date: 17 February 2020
Accepted Date: 5 March 2020
Available Online: 6 March 2020

Figures(4)

One 6-metal Zn-Nd complex [Zn₂Nd₄L₂(OAc)₁₀(OH)₂(CH₃OH)₂] (1) with Schiff base ligand bis(3-methoxysalicylidene)ethylene-1,2-phenylenediamine (H₂L) was constructed, and it has nanoscale rectangular structure (8×11×28 Å). Excited by ligand-centered absorption bands, 1 shows NIR emission of Nd³⁺ ion. Interestingly, 1 exhibits lanthanide luminescent response towards metal ions, especially to alkali metal ions (Li⁺, Na⁺ and K⁺) at ppm level.
- Construction,
- Zn-Ln complexes,
- Schiff base ligand,
- NIR luminescence properties,
- Luminescent response
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