Citation: Chen Gong, Nengzi Li-Chao, Gao Yingjie, Zhu Guixian, Gou Jianfeng, Cheng Xiuwen. Degradation of tartrazine by peroxymonosulfate through magnetic Fe₂O₃/Mn₂O₃ composites activation[J]. Chinese Chemical Letters, ;2020, 31(10): 2730-2736. doi: 10.1016/j.cclet.2020.02.033 shu

Degradation of tartrazine by peroxymonosulfate through magnetic Fe₂O₃/Mn₂O₃ composites activation

a.
Key Laboratory of Western China's Environmental Systems(Ministry of Education) and Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China
b.
Academy of Economics and Environmental Sciences, Xichang University, Xichang 615000, China

chengxw@lzu.edu.cn

Received Date: 4 January 2020
Revised Date: 9 February 2020
Accepted Date: 17 February 2020
Available Online: 18 February 2020

Figures(4)

In this study, Fe₂O₃/Mn₂O₃ composite was synthesized by a facile two-step technique, and several methods were carried out to characterize it. Then, the decomposition experiments of tartrazine (TTZ), a kind of refractory organic pollutant, were conducted under various environmental condition to detect the catalyst performance, such as reaction system, the dosage of catalyst, peroxymonosulfate (PMS) concentration, initial pH, different natural water substances. The results exhibited that Fe₂O₃/Mn₂O₃ composite with the mole rate 2:3 had the best PMS activation performance and the removal efficiency was 97.3% within 30 min. Besides, the optimum degradation conditions of TTZ were also discussed, that is catalyst dosage (0.6 g/L), PMS concentration (0.8 g/L) and the initial pH 11. In addition, proved by the natural water substances adding experiments, HPO₄^2-, HCO₃^-, NO₃^- and NOM (nature organic matter) could slow down the experiments progressing, but Cl^- could boost it. Then inhibitor experiments indicated both the HO^· and SO₄^·- played a vital role in the experiments. Reusability and ions leaching experiments as well as the used catalyst physical characterization images exhibited the excellent stability and cyclicity of the Fe₂O₃/Mn₂O₃ composite. Finally, based on the XPS (X-ray photoelectron spectroscopy) and the experiments results, the possible mechanism of TTZ degradation was proposed. This system might provide a novel thought for the decomposition of refractory organic pollutant and had potential in promotion of actual sewage treatment technology.
- Fe₂O₃/Mn₂O₃,
- Peroxymonosulfate,
- Tartrazine,
- Degradation,
- Activation,
- Mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142

Degradation of tartrazine by peroxymonosulfate through magnetic Fe2O3/Mn2O3 composites activation

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Degradation of tartrazine by peroxymonosulfate through magnetic Fe₂O₃/Mn₂O₃ composites activation