Citation: Zhou Ziyang, Miao Ling, Duan Hui, Wang Zhiwei, Lv Yaokang, Xiong Wei, Zhu Dazhang, Li Liangchun, Liu Mingxian, Gan Lihua. Highly active N, O-doped hierarchical porous carbons for high-energy supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(5): 1226-1230. doi: 10.1016/j.cclet.2020.02.026 shu

Highly active N, O-doped hierarchical porous carbons for high-energy supercapacitors

Zhou Ziyang ^{a, 1} ,
Miao Ling ^{a, 1} ,
Duan Hui ^a ,
Wang Zhiwei ^b ,
Lv Yaokang ^c ,
Xiong Wei ^e ,
Zhu Dazhang ^a ,
Li Liangchun ^a ,
Liu Mingxian ^a,b,d,**, ,
Gan Lihua ^a,*,

a.
Shanghai Key Lab. of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China
b.
State Key Laboratory of Pollution Control and Resources Reuse, Shanghai Institute of Pollution Control and Ecological Security, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
c.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
d.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
e.
School of Chemistry and Environmental Engineering, Key Laboratory for Green Chemical Process(Ministry of Education), Hubei Key Lab. of Novel Reactor&Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430205, China

^**

liumx@tongji.edu.cn

ganlh@tongji.edu.cn

Received Date: 6 January 2020
Revised Date: 4 February 2020
Accepted Date: 13 February 2020
Available Online: 14 February 2020

Figures(4)

Highly active N, O-doped hierarchical porous carbons (NOCs) are fabricated through the in-situ polymerization and pyrolysis of o-tolidine and p-benzoquinone. As-prepared NOCs have a variety of faradaic-active species (N-6, N-5 and O-I), high ion-accessible platform (1799 m² /g) and hierarchically micro-meso-macro porous architecture. Consequently, the resultant NOC electrode delivers an advantageous specific capacitance (311 F/g), with a pseudocapacitive contribution of 37% in a threeelectrode configuration, and an enhanced energy output of 18.0 Wh/kg@350 W/kg owing to the enlarged faradaic effect in an aqueous redox-active cell. Besides, a competitive energy density (74.9 Wh/kg) and high-potential durability (87.8%) are achieved in an ionic liquid (EMIMBF₄)-assembled device. This study sheds light on a straightforward avenue to optimize the faradaic activity and nanoarchitecture for advanced supercapacitors.
- N, O-doped carbon,
- Hierarchical porous structure,
- Faradaic activity,
- Supercapacitor,
- High energy density
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