Citation: Wang Feng, Chen Lian, Li Huiling, Duan Gaigai, He Shuijian, Zhang Lin, Zhang Guoying, Zhou Zhengping, Jiang Shaohua. N-doped honeycomb-like porous carbon towards high-performance supercapacitor[J]. Chinese Chemical Letters, ;2020, 31(7): 1986-1990. doi: 10.1016/j.cclet.2020.02.020 shu

N-doped honeycomb-like porous carbon towards high-performance supercapacitor

a.
Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China
b.
Media Lab, Massachusetts Institute of Technology, Cambridge, MA 02139, United States
c.
Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
d.
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831, United States

duangaigai@njfu.edu.cn

shaohua.jiang@njfu.edu.cn

Received Date: 13 December 2019
Revised Date: 25 January 2020
Accepted Date: 7 February 2020
Available Online: 13 February 2020

Figures(5)

Biomass-derived porous carbon with developed pore structure is critical to achieving high performance electrode materials. In this work, we report a grape-based honeycomb-like porous carbon (GHPC) prepared by KOH activation and carbonization, followed by N-doping (NGHPC). The obtained NGHPC exhibits a unique honeycomb-like structure with hierarchically interconnected micro/mesopores, and high specific surface area of 1268 m²/g. As a supercapacitor electrode, the NGPHC electrode exhibits a remarkable specific capacitance of 275 F/g at 0.5 A/g in a three-electrode cell. Moreover, the NGHPC//NGHPC symmetric supercapacitor displays a high energy density of 12.6 Wh/kg, and excellent cycling stability of approximately 95.2% capacitance retention after 5000 cycles at 5 A/g. The excellent electrochemical performance of NGHPC is ascribed to its high specific surface area, honeycomb-like structure and high-content of pyrodinic-N (36.29%). It is believed that grape-based carbon materials show great potential as advanced electrode materials for supercapacitors.
- Grape,
- Honeycomb-like,
- Porous carbon,
- Activation,
- Supercapacitor
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