Citation: Chen Wenwei, Chen Qi, Ma Yingjie, Leng Xuebing, Bai Sheng-Di, Deng Liang. Formal Co(0), Fe(0), and Mn(0) complexes with NHC and styrene ligation[J]. Chinese Chemical Letters, ;2020, 31(5): 1342-1344. doi: 10.1016/j.cclet.2019.11.019 shu

Formal Co(0), Fe(0), and Mn(0) complexes with NHC and styrene ligation

Chen Wenwei ^a,b ,
Chen Qi ^b ,
Ma Yingjie ^b ,
Leng Xuebing ^b ,
Bai Sheng-Di ^a,*, ,
Deng Liang ^b,*,

a.
Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, China
b.
State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

sdbai@sxu.edu.cn

deng@sioc.ac.cn

Received Date: 8 October 2019
Revised Date: 5 November 2019
Accepted Date: 12 November 2019
Available Online: 13 November 2019

Figures(2)

The limited knowledge on low-coordinate zero-valent transition-metal species has intrigued great synthetic efforts in developing ligand sets for their stabilization. While the combined ligand set of N-heterocyclic carbene (NHC) with vinylsilanes was the only known ligand system amenable to the stabilization of three-coordinate formal zero-valent cobalt, iron, and manganese complexes, the exploration on other ligands has proved that the ligand set of NHCs with styrene is equally effective in stabilizing three-coordinate formal zero-valent metal complexes in the form of (NHC)M(η²-CH₂CHPh)₂ (NHC=IPr, IMes; M=Co, Fe, Mn). These styrene complexes can be prepared by the one-pot reactions of MCl₂ with styrene, NHC and KC₈, and have been characterized by various spectroscopic methods. Preliminary reactivity study indicated that the interaction of[(IMes)Fe(η²-CH₂CHPh)₂] with DippN₃ produces the iron(Ⅳ) bisimido complex[(IMes)Fe(NDipp)₂] and styrene, which hints at the utility of these zero-valent metal styene complexes as synthons of the mono-coordinate species (NHC)M(0).
- Alkene,
- Cobalt,
- Iron,
- N-Heterocyclic carbene,
- Manganese
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