Citation: Yao Hong, Zhou Qi, Zhang Youming, Hu Yinping, Kan Xiaotong, Chen Yanyan, Gong Guanfei, Zhang Qinpeng, Wei Taibao, Lin Qi. Supramolecular polymer materials based on pillar[5]arene: Ultrasensitive detection and efficient removal of cyanide[J]. Chinese Chemical Letters, ;2020, 31(5): 1231-1234. doi: 10.1016/j.cclet.2019.09.046 shu

Supramolecular polymer materials based on pillar[5]arene: Ultrasensitive detection and efficient removal of cyanide

Yao Hong ^a,*, ,
Zhou Qi ^a ,
Zhang Youming ^a,b ,
Hu Yinping ^a ,
Kan Xiaotong ^a ,
Chen Yanyan ^a ,
Gong Guanfei ^a ,
Zhang Qinpeng ^a ,
Wei Taibao ^a ,
Lin Qi ^a,*,

a.
Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Key Laboratory of Eco-environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China
b.
College of Chemistry and Chemical Engineering, Lanzhou City University, Lanzhou 730070, China

yhxbz@126.com

linqi2004@126.com

Received Date: 20 August 2019
Revised Date: 11 September 2019
Accepted Date: 23 September 2019
Available Online: 24 September 2019

Figures(4)

An ultrasensitive detection and effective removal material was successfully developed by using a pillar[n] arene-based supramolecular polymer gel (MTP5⊃HB). The MTP5⊃HB can ultrasensitively recognize Cu²⁺ and Fe³⁺, and the limits of detection (LODs) for Cu²⁺ and Fe³⁺ are 1.55 and 2.68 nmol/L, respectively. Additionally, the in-situ generated metallogel MTP5⊃HB-Cu can exclusively detect CN^-, and the LOD for CN^- is 1.13 nmol/L. Noticeably, the xerogel of MTP5⊃HB-Cu can effectively remove CN^- from aqueous solution with 94.40% removal rate. Test kit based on MTP5⊃HB-Cu is also prepared for convenient detection of CN^-.
- Supramolecular polymer gel,
- Fluorescence detection,
- Ultrasensitive,
- Efficient removal,
- Cyanide
1. [1]
  L.L. Wang, J. Zheng, S. Yang, et al., ACS Appl. Mater. Interfaces 7(2015) 19509-19515. doi: 10.1021/acsami.5b06352
2. [2]
  Z.Z. Dong, C. Yang, K. Vellaisamy, et al., ACS Sens. 2(2017) 1517-1522. doi: 10.1021/acssensors.7b00553
3. [3]
  N. Mergu, J.H. Moon, H. Kim, et al., Sens. Actuators B:Chem. 273(2018) 143-152. doi: 10.1016/j.snb.2018.05.165
4. [4]
  Y. Shiraishi, M. Nakamura, N. Hayashi, et al., Anal. Chem. 88(2016) 6805-6811. doi: 10.1021/acs.analchem.6b01279
5. [5]
  E. Jaszczak, Z. Polkowska, S. Narkowicz, et al., Environ. Sci. Pollut. Res. 24(2017) 15929-15948. doi: 10.1007/s11356-017-9081-7
6. [6]
  C.F. Chow, P.Y. Ho, W.L. Wong, et al., Chem. -Eur. J. 21(2015) 12984-12990. doi: 10.1002/chem.201501448
7. [7]
  C.H. Zong, L.R. Zheng, W.H. He, et al., Anal. Chem. 86(2014) 1687-1692. doi: 10.1021/ac403480q
8. [8]
  P. Eskandari, M. Farhadian, A.R.S. Nazar, et al., Ind. Eng. Chem. Res. 58(2019) 2099-2112. doi: 10.1021/acs.iecr.8b05073
9. [9]
  L. Brunsveld, B.J.B. Folmer, E.W. Meijer, et al., Chem. Rev. 101(2001) 4071-4098. doi: 10.1021/cr990125q
10. [10]
  H. Li, Y. Yang, F.F. Xu, et al., Chem. Commun. 55(2019) 271-285. doi: 10.1039/C8CC08085B
11. [11]
  T. Xiao, L. Wang, Chin. Chem. Lett. 29(2018) 1172-1182.
12. [12]
  C.W. Zhang, B. Ou, S.T. Jiang, et al., Polym. Chem. 9(2018) 2021-2030. doi: 10.1039/C8PY00226F
13. [13]
  Z.C. Gao, Y.F. Han, S.H. Chen, et al., ACS Macro Lett. 6(2017) 541-545. doi: 10.1021/acsmacrolett.7b00241
14. [14]
  Q. Lin, G.F. Gong, Y.Q. Fan, et al., Chem. Commun. 55(2019) 3247-3250. doi: 10.1039/C8CC09876J
15. [15]
  H.G. Fu, Y. Chen, Y. Liu, ACS Appl. Mater. Interfaces 11(2019) 16117-16122. doi: 10.1021/acsami.9b04323
16. [16]
  T. Ogoshi, S. Kanai, S. Fujinami, et al., J. Am. Chem. Soc. 130(2008) 5022-5023. doi: 10.1021/ja711260m
17. [17]
  C.J. Li, Chem. Commun. 50(2014) 12420-12433. doi: 10.1039/C4CC03170A
18. [18]
  T. Ogoshi, T. Kakuta, T. Yamagishi, Angew. Chem. Int. Ed. 58(2019) 2197-2206. doi: 10.1002/anie.201805884
19. [19]
  P. Li, Y. Cheng, Y. Liu, Chin. Chem. Lett. 30(2019) 1190-1197. doi: 10.1016/j.cclet.2019.03.035
20. [20]
  S. Sun, J.B. Shi, Y.P. Dong, et al., Chin. Chem. Lett. 24(2013) 987-992. doi: 10.1016/j.cclet.2013.07.014
21. [21]
  Y. Wang, M.Z. Lv, N. Song, et al., Macromolecules 50(2017) 5759-5766. doi: 10.1021/acs.macromol.7b01010
22. [22]
  Z.Y. Li, Y.Y. Zhang, C.W. Zhang, et al., J. Am. Chem. Soc. 136(2014) 8577-8589. doi: 10.1021/ja413047r
23. [23]
  T. Xiao, L. Zhou, L. Xu, et al., Chin. Chem. Lett. 30(2019) 271-276. doi: 10.1016/j.cclet.2018.05.039
24. [24]
  J. Chen, Y. Wang, C. Wang, et al., Chem. Commun. 55(2019) 6817-6826. doi: 10.1039/C9CC03165K
25. [25]
  S. Sun, D. Lu, Q. Huang, et al., J. Colloid. Interf. Sci. 533(2019) 42-46. doi: 10.1016/j.jcis.2018.08.051
26. [26]
  J.D. Luo, Z.L. Xie, J.W.Y. Lam, et al., Chem. Commun. 18(2001) 1740-1741.
27. [27]
  Y.N. Hong, J.W.Y. Lam, B.Z. Tang, Chem. Soc. Rev. 40(2011) 5361-5388. doi: 10.1039/c1cs15113d
28. [28]
  D. Ding, K. Li, B. Liu, et al., Acc. Chem. Res. 46(2013) 2441-2453. doi: 10.1021/ar3003464
29. [29]
  D.H. Dai, Z. Li, J. Yang, et al., J. Am. Chem. Soc. 141(2019) 4756-4763. doi: 10.1021/jacs.9b01546
30. [30]
  J. Huang, N. Sun, P.Y. Chen, et al., Chem. Commun. 50(2014) 2136-2138. doi: 10.1039/c3cc49313j
31. [31]
  P. Wang, B.C. Liang, D.Y. Xia, Inorg. Chem. 58(2019) 2252-2256. doi: 10.1021/acs.inorgchem.8b02896
32. [32]
  A. Pankajakshan, D. Kuznetsov, S. Mandal, Inorg. Chem. 58(2019) 1377-1381. doi: 10.1021/acs.inorgchem.8b02898
33. [33]
  L.W. Ma, S. Wang, C.P. Li, et al., Chem. Commun. 54(2018) 2405-2408. doi: 10.1039/C8CC00213D
34. [34]
  Y.M. Zhang, W. Zhu, W.J. Qu, et al., Chem. Commun. 54(2018) 4549-4552. doi: 10.1039/C8CC00814K
35. [35]
  J. Mei, N.L.C. Leung, R.T.K. Kwok, et al., Chem. Rev. 115(2015) 11718-11940. doi: 10.1021/acs.chemrev.5b00263
36. [36]
  L.Q. Shangguan, H. Xing, J.H. Mondal, et al., Chem. Commun. 53(2017) 889-892. doi: 10.1039/C6CC08336F
37. [37]
  S.L. Wang, Y.L. Wang, Z.X. Chen, et al., Chem. Commun. 51(2015) 3434-3437. doi: 10.1039/C4CC08820D
38. [38]
  N. Malviya, M. Das, P. Mandal, et al., Soft Matter 13(2017) 6243-6249. doi: 10.1039/C7SM01199G
39. [39]
  X.D. Chi, M. Xue, Y. Yao, et al., Org. Lett. 15(2013) 4722-4725. doi: 10.1021/ol402048n
40. [40]
  S. Nagashima, T. Ozawa, Int. J. Environ. Anal. Chem. 10(1980) 99-106.
41. [41]
  L.F. Zhang, J.S. Zhang, Z.F. Zheng, et al., Anal. Chem. 91(2019) 8762-8766. doi: 10.1021/acs.analchem.9b01811
1. [1]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
2. [2]
  Yuxin Li , Chengbin Liu , Qiuju Li , Shun Mao . Fluorescence analysis of antibiotics and antibiotic-resistance genes in the environment: A mini review. Chinese Chemical Letters, 2024, 35(10): 109541-. doi: 10.1016/j.cclet.2024.109541
3. [3]
  Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699
4. [4]
  Min Huang , Ru Cheng , Shuai Wen , Liangtong Li , Jie Gao , Xiaohui Zhao , Chunmei Li , Hongyan Zou , Jian Wang . Ultrasensitive detection of microRNA-21 in human serum based on the confinement effect enhanced chemical etching of gold nanorods. Chinese Chemical Letters, 2024, 35(9): 109379-. doi: 10.1016/j.cclet.2023.109379
5. [5]
  Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
6. [6]
  Lei Zhou , Youjun Zhou , Lizhen Fang , Yiqiao Bai , Yujia Meng , Liang Li , Jie Yang , Yong Yao . Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications. Chinese Chemical Letters, 2024, 35(9): 109509-. doi: 10.1016/j.cclet.2024.109509
7. [7]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
8. [8]
  Rui Wang , Yang Liang , Julius Rebek Jr. , Yang Yu . Stabilization and detection of labile reaction intermediates in supramolecular containers. Chinese Chemical Letters, 2024, 35(6): 109228-. doi: 10.1016/j.cclet.2023.109228
9. [9]
  Xiaoman Dang , Zhiying Wu , Tangxin Xiao , Zhouyu Wang , Leyong Wang . Highly robust supramolecular polymer networks crosslinked by metallacycles. Chinese Chemical Letters, 2024, 35(12): 110208-. doi: 10.1016/j.cclet.2024.110208
10. [10]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
11. [11]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
12. [12]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
13. [13]
  Gaojian Yang , Zhiyang Li , Rabia Usman , Zhu Chen , Yuan Liu , Song Li , Hui Chen , Yan Deng , Yile Fang , Nongyue He . DNA walker induced "signal on" fluorescence aptasensor strategy for rapid and sensitive detection of extracellular vesicles in gastric cancer. Chinese Chemical Letters, 2025, 36(2): 109930-. doi: 10.1016/j.cclet.2024.109930
14. [14]
  Ying Chen , Li Li , Junyao Zhang , Tongrui Sun , Xuan Zhang , Shiqi Zhang , Jia Huang , Yidong Zou . Tailored ionically conductive graphene oxide-encased metal ions for ultrasensitive cadaverine sensor. Chinese Chemical Letters, 2024, 35(8): 109102-. doi: 10.1016/j.cclet.2023.109102
15. [15]
  Qinghong Pan , Huafang Zhang , Qiaoling Liu , Donghong Huang , Da-Peng Yang , Tianjia Jiang , Shuyang Sun , Xiangrong Chen . A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification. Chinese Chemical Letters, 2025, 36(1): 110169-. doi: 10.1016/j.cclet.2024.110169
16. [16]
  Lei Zhu , Hai-Ruo Li , Yi-Ning Mao , Ruiying Liu , Bo Zhang , Jing Chen , Wengui Xu , Libo Zhang , Cheng-Peng Li . A four-fold interpenetrated MOF for efficient perrhenate/pertechnetate removal from alkaline nuclear effluents. Chinese Chemical Letters, 2024, 35(12): 109921-. doi: 10.1016/j.cclet.2024.109921
17. [17]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
18. [18]
  Zheng Zhao , Ben Zhong Tang . An efficient strategy enabling solution processable thermally activated delayed fluorescence emitter with high horizontal dipole orientation. Chinese Journal of Structural Chemistry, 2024, 43(6): 100270-100270. doi: 10.1016/j.cjsc.2024.100270
19. [19]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
20. [20]
  Wantong Zhang , Zixing Xu , Guofei Dai , Zhijian Li , Chunhui Deng . Removal of Microcystin-LR in lake water sample by hydrophilic mesoporous silica composites under high-throughput MALDI-TOF MS detection platform. Chinese Chemical Letters, 2024, 35(5): 109135-. doi: 10.1016/j.cclet.2023.109135

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1000)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142