Citation: Chen Fushan, Yang Tao, Zhao Songlin, Jiang Taotao, Yu Lu, Xiong Houfeng, Guo Chuankun, Rao Yufang, Liu Yan, Liu Liu, Zhou Jian, Tu Pengxiang, Ni Jun, Zhang Qunfeng, Li Xiaonian. Highly selective oxidation of amines to imines by Mn₂O₃ catalyst under eco-friendly conditions[J]. Chinese Chemical Letters, ;2019, 30(12): 2282-2286. doi: 10.1016/j.cclet.2019.09.007 shu

Highly selective oxidation of amines to imines by Mn₂O₃ catalyst under eco-friendly conditions

Chen Fushan ^a,b ,
Yang Tao ^b ,
Zhao Songlin ^a,c ,
Jiang Taotao ^a ,
Yu Lu ^a ,
Xiong Houfeng ^b ,
Guo Chuankun ^b ,
Rao Yufang ^b ,
Liu Yan ^b ,
Liu Liu ^a ,
Zhou Jian ^a ,
Tu Pengxiang ^a ,
Ni Jun ^a ,
Zhang Qunfeng ^a,*, ,
Li Xiaonian ^a

a.
Industrial Catalysis Institute of Zhejiang University of Technology, Hangzhou, China
b.
Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang University, Jiujiang, China, br, c School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, China
c.
School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, China

zhangqf@zjut.edu.cn

Received Date: 23 June 2019
Revised Date: 30 August 2019
Accepted Date: 5 September 2019
Available Online: 5 December 2019

Figures(4)

Enhancing the selectivity of imines for the oxidative self-coupling of primary amines was found to be challenging in the heterogeneous catalysis. Three different manganese oxides (M-3, M-4, M-5) were synthesized by controlling the calcination temperature using a simple template-free oxalate route. The prepared manganese oxides were systematically characterized using XRD, N₂ sorption, SEM, TEM, XPS, H₂-TPR techniques. M-4 gave 96.2% selectivity of imine at 100% conversion of benzylamine, which was far more superior than other existing protocols. Mn³⁺/Mn⁴⁺ ratio was found to affect the selectivity of the imines. The probable reaction pathway for amines oxidation catalyzed by manganese oxides was proposed for the first time.
- Oxalate route,
- Mn₂O₃,
- Self-coupling of amines,
- Heterogeneous catalysis,
- Aerobic oxidation
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Highly selective oxidation of amines to imines by Mn2O3 catalyst under eco-friendly conditions

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通讯作者: 陈斌, bchen63@163.com

Highly selective oxidation of amines to imines by Mn₂O₃ catalyst under eco-friendly conditions