Citation: Fang Yongzheng, Yang Bowen, He Dongtong, Li Huipeng, Zhu Kai, Wu Lin, Ye Ke, Cheng Kui, Yan Jun, Wang Guiling, Cao Dianxue. Porous and free-standing Ti₃C₂T_x-RGO film with ultrahigh gravimetric capacitance for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(4): 1004-1008. doi: 10.1016/j.cclet.2019.08.043 shu

Porous and free-standing Ti₃C₂T_x-RGO film with ultrahigh gravimetric capacitance for supercapacitors

Fang Yongzheng ^a,1 ,
Yang Bowen ^a,1 ,
He Dongtong ^a ,
Li Huipeng ^a ,
Zhu Kai ^a,c,*, ,
Wu Lin ^b,**, ,
Ye Ke ^a ,
Cheng Kui ^a ,
Yan Jun ^a ,
Wang Guiling ^a ,
Cao Dianxue ^a,*,

a.
Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
b.
Teachers Education College of Harbin Normal University, Harbin 150001, China
c.
Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Sources Co., Ltd., Zunyi 563003, China

^**

kzhu@hrbeu.edu.cn

hsdhxwulin@163.com

caodianxue@hrbeu.edu.cn

Received Date: 29 July 2019
Revised Date: 15 August 2019
Accepted Date: 19 August 2019
Available Online: 26 August 2019

Figures(4)

MXene-based electrode materials exhibit favorable supercapacitor performance in sulfuric acid due to praised pseudocapacitance charge storage mechanism. However, self-stacking of conventional MXene electrodes severely restricts their electrochemical performance, especially at high loading. Herein, a flexible cross-linked porous Ti₃C₂T_x-MXene-reduced graphene oxide (Ti₃C₂T_x-RGO) film is skillfully designed and synthesized by microscopic explosion of graphene oxide (GO) at sudden high temperature. The generated chamber structure between layers could hold a few of electrolyte, leading to a close-fitting reaction at interlayer and avoiding complex ions transmission paths. The Ti₃C₂T_x-RGO film displayed a preferable rate performance than that of pure Ti₃C₂T_x film and a high capacitance of 505 F/g at 2 mV/s. Furthermore, the uniform intralayer structure and unique energy storage process lead to thickness-independenct electrochemical performances. This work provides a simple and feasible improvement approach for the design of MXene-based electrodes, which can be spread other electrochemical systems limited by ions transport, such as metal ions batteries and catalysis.
- MXene,
- RGO,
- Cross-linked porous,
- Supercapacitors,
- High capacitance,
- Thickness independent
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Porous and free-standing Ti3C2Tx-RGO film with ultrahigh gravimetric capacitance for supercapacitors

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Porous and free-standing Ti₃C₂T_x-RGO film with ultrahigh gravimetric capacitance for supercapacitors