Citation: Cui Cong, Cheng Renfei, Zhang Chao, Wang Xiaohui. Pt immobilized spontaneously on porous MXene/MAX hybrid monolith for hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2020, 31(4): 988-991. doi: 10.1016/j.cclet.2019.08.026 shu

Pt immobilized spontaneously on porous MXene/MAX hybrid monolith for hydrogen evolution reaction

Cui Cong ^a,b ,
Cheng Renfei ^a,b ,
Zhang Chao ^a ,
Wang Xiaohui ^a,*,

a.
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
b.
School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

wang@imr.ac.cn

Received Date: 6 July 2019
Revised Date: 2 August 2019
Accepted Date: 15 August 2019
Available Online: 16 August 2019

Figures(4)

Designing efficient electrocatalysts with low Pt loadings for hydrogen evolution reaction (HER) is urgently required for renewable and sustainable energy conversion. Here, we report a strategy that Pt nanoparticulates are spontaneously immobilized on porous MXene/MAX monolith as HER catalysts by utilizing the redox reaction between Ti₃C₂T_x MXene and [PtCl₄]^2- in H₂PtCl₆ aqueous solution. By taking advantage of homogeneously distributed Pt nanoparticulates on highly electrically conductive porous Ti₃C₂T_x/Ti₃AlC₂ monolith, the as-prepared electrocatalysts show high catalytic performance for hydrogen evolution. Specifically, the binder-free electrocatalysts have Pt loadings as low as 8.9 μg/cm², with low overpotential of 43 mV at a current density of 10 mA/cm² and low Tafel slope that three times lower than porous Ti₃C₂T_x/Ti₃AlC₂ without Pt loading. This strategy offers a new approach to constructing ultra-low Pt-loading HER catalysts on the basis of in situ redox reaction between noble metal ions and MXenes.
- Clean energy,
- Hydrogen evolution reaction,
- Pt catalyst,
- MXene,
- Porous MAX phase
1. [1]
  C.W. Hamilton, R.T. Baker, A. Staubitz, I. Manners, Chem. Soc. Rev. 38 (2009) 279-293. doi: 10.1039/B800312M
2. [2]
  A. Midilli, M. Ay, I. Dincer, M.A. Rosen, Renew. Sust. Energ. Rev. 9 (2005) 255-271. doi: 10.1016/j.rser.2004.05.003
3. [3]
  T.E. Mallouk, Nat. Chem. 5 (2013) 362-363. doi: 10.1038/nchem.1634
4. [4]
  P.P. Edwards, V.L. Kuznetsov, W.I.F. David, N.P. Brandon, Energ. Policy 36 (2008) 4356-4362. doi: 10.1016/j.enpol.2008.09.036
5. [5]
  I. Dincer, C. Acar, Int. J. Hydrogen Energ. 40 (2015) 11094-11111. doi: 10.1016/j.ijhydene.2014.12.035
6. [6]
  Y. Zheng, Y. Jiao, M. Jaroniec, S.Z. Qiao, Angew. Chem. Int. Ed. 54 (2015) 52-65. doi: 10.1002/anie.201407031
7. [7]
  X. Zou, Y. Zhang, Chem. Soc. Rev. 44 (2015) 5148-5180. doi: 10.1039/C4CS00448E
8. [8]
  A.A. Yaroshevsky, Appl. Geochem. 44 (2006) 48-55.
9. [9]
  L. Tan, Y. Chi-Lung, Int. Geol. Rev. 12 (2009) 778-786.
10. [10]
  K. Jiang, B. Liu, M. Luo, et al., Nat. Commun. 10 (2019) 1743. doi: 10.1038/s41467-019-09765-y
11. [11]
  Z. Zhang, Y. Chen, L. Zhou, et al., Nat. Commun. 10 (2019) 1657. doi: 10.1038/s41467-019-09596-x
12. [12]
  M. Naguib, M. Kurtoglu, V. Presser, et al., Adv. Mater. 23 (2011) 4248-4253. doi: 10.1002/adma.201102306
13. [13]
  M. Naguib, O. Mashtalir, J. Carle, et al., ACS Nano 6 (2012) 1322-1331. doi: 10.1021/nn204153h
14. [14]
  B. Anasori, M.R. Lukatskaya, Y. Gogotsi, Nat. Rev. Mater. 2 (2017) 16098. doi: 10.1038/natrevmats.2016.98
15. [15]
  M.W. Barsoum, Prog. Solid State Ch 28 (2000) 201-281. doi: 10.1016/S0079-6786(00)00006-6
16. [16]
  Z.M. Sun, Int. Mater. Rev. 56 (2013) 143-166.
17. [17]
  X.H. Wang, Y.C. Zhou, J. Mater. Sci. Technol. 26 (2010) 385-416. doi: 10.1016/S1005-0302(10)60064-3
18. [18]
  T. Hu, Z. Li, M. Hu, et al., J. Phys. Chem. C 121 (2017) 19254-19261. doi: 10.1021/acs.jpcc.7b05675
19. [19]
  S. Li, P. Tuo, J. Xie, et al., Nano Energy 47 (2018) 512-518. doi: 10.1016/j.nanoen.2018.03.022
20. [20]
  Z.W. Seh, K.D. Fredrickson, B. Anasori, et al., ACS Energy Lett. 1 (2016) 589-594. doi: 10.1021/acsenergylett.6b00247
21. [21]
  E. Satheeshkumar, T. Makaryan, A. Melikyan, et al., Sci. Rep. 6 (2016) 32049. doi: 10.1038/srep32049
22. [22]
  K. Li, T. Jiao, R. Xing, et al., Sci. China Mater. 61 (2018) 728-736. doi: 10.1007/s40843-017-9196-8
23. [23]
  Y.Y. Yuan, H.S. Li, L.G. Wang, et al., ACS Sustain. Chem. Eng. 7 (2019) 4266-4273. doi: 10.1021/acssuschemeng.8b06045
24. [24]
  Z.W. Zhang, H.N. Li, G.D. Zou, et al., ACS Sustain. Chem. Eng. 4 (2016) 6763-6771. doi: 10.1021/acssuschemeng.6b01698
25. [25]
  G. Zou, Z. Zhang, J. Guo, et al., ACS Appl. Mater. Inter. 8 (2016) 22280-22286. doi: 10.1021/acsami.6b08089
26. [26]
  L. Li, N. Zhang, M.Y. Zhang, et al., ACS Sustain. Chem. Eng. 6 (2018) 7442-7450. doi: 10.1021/acssuschemeng.8b00047
27. [27]
  X.X. Huang, R. Wang, T.F. Jiao, et al., ACS Omega 4 (2019) 1897-1906. doi: 10.1021/acsomega.8b03615
28. [28]
  R.P. Pandey, K. Rasool, V.E. Madhavan, et al., J. Mater. Chem. A: Mater. Energy Sustain. 6 (2018) 3522-3533. doi: 10.1039/C7TA10888E
29. [29]
  R.B. Rakhi, P. Nayak, C. Xia, H.N. Alshareef, Sci. Rep. 6 (2016) 36422. doi: 10.1038/srep36422
30. [30]
  J.S. Zheng, B. Wang, A.L. Ding, et al., Electroanal. Chem. 816 (2018) 189-194. doi: 10.1016/j.jelechem.2018.03.056
31. [31]
  J. Zhang, Y. Zhao, X. Guo, et al., Nat. Catal. 1 (2018) 985-992. doi: 10.1038/s41929-018-0195-1
32. [32]
  K. Xiong, L. Li, L. Zhang, et al., J. Mater. Chem. A: Mater. Energy Sustain. 3 (2015) 1863-1867. doi: 10.1039/C4TA05686H
33. [33]
  J. Xie, X. Wang, A. Li, F. Li, Y. Zhou, Corros. Sci. 60 (2012) 129-135. doi: 10.1016/j.corsci.2012.03.047
34. [34]
  V. Presser, M. Naguib, L. Chaput, et al., J. Raman Spectrosc. 43 (2012) 168-172. doi: 10.1002/jrs.3036
35. [35]
  H. Zhang, X.H. Wang, H.M. Xiang, Z.J. Li, Y.C. Zhou, Appl. Phys. Lett. 104 (2014) 131903. doi: 10.1063/1.4870262
36. [36]
  M. Hu, Z. Li, T. Hu, et al., ACS Nano 10 (2016) 11344-11350. doi: 10.1021/acsnano.6b06597
37. [37]
  T. Hu, J.M. Wang, H. Zhang, et al., Phys. Chem. Chem. Phys. 17 (2015) 9997-10003. doi: 10.1039/C4CP05666C
38. [38]
  M.R. Lukatskaya, S.M. Bak, X.Q. Yu, et al., Adv. Energy Mater. 5 (2015) 1500589. doi: 10.1002/aenm.201500589
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