Citation: Peng Sha, Song Yan-Xi, He Jun-Yi, Tang Shan-Shan, Tan Jia-Xi, Cao Zhong, Lin Ying-Wu, He Wei-Min. TsCl-promoted sulfonylation of quinoline N-oxides with sodium sulfinates in water[J]. Chinese Chemical Letters, ;2019, 30(12): 2287-2290. doi: 10.1016/j.cclet.2019.08.002 shu

TsCl-promoted sulfonylation of quinoline N-oxides with sodium sulfinates in water

Peng Sha ^a ,
Song Yan-Xi ^a ,
He Jun-Yi ^b ,
Tang Shan-Shan ^a ,
Tan Jia-Xi ^c ,
Cao Zhong ^b ,
Lin Ying-Wu ^d ,
He Wei-Min ^a,*,

a.
Department of Chemistry, Hunan University of Science and Engineering, Yongzhou, China
b.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha, China
c.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, China
d.
School of Chemistry and Chemical Engineering, University of South China, Hengyang, China

weiminhe2016@yeah.net

Received Date: 7 July 2019
Revised Date: 24 July 2019
Accepted Date: 31 July 2019
Available Online: 5 December 2019

Figures(4)

An eco-friendly protocol for the synthesis of various 2-sulfonyl quinolines/pyridines through sulfonylation of heteroaromatic N-oxides with sodium sulfinates in water at ambient temperature under metal-and oxidant-free conditions has been developed. The mild reaction conditions, high reaction efficiency, operational simplicity, short reaction time and remarkable functional-group compatibility make the developed protocol very attractive for the preparation of 2-sulfonyl N-heteroaromatic compounds.
- Quinoline N-oxides,
- 2-Sulfonylquinolines,
- Sodium sulfinates,
- Sulfonylation,
- In water
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