Citation: Zou Qi, Song Huan, Tang Mingjin, Lu Keding. Measurements of HO₂ uptake coefficient on aqueous (NH₄)₂SO₄ aerosol using aerosol flow tube with LIF system[J]. Chinese Chemical Letters, ;2019, 30(12): 2236-2240. doi: 10.1016/j.cclet.2019.07.041 shu

Measurements of HO₂ uptake coefficient on aqueous (NH₄)₂SO₄ aerosol using aerosol flow tube with LIF system

Zou Qi ^a ,
Song Huan ^a ,
Tang Mingjin ^b ,
Lu Keding ^a,*,

a.
College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
b.
State Key Laboratory of Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China

k.lu@pku.edu.cn

Received Date: 22 April 2019
Revised Date: 16 July 2019
Accepted Date: 17 July 2019
Available Online: 18 December 2019

Figures(3)

Laboratory studies of HO₂ uptake coefficients, γ(HO₂), were conducted at room temperature using an aerosol flow tube coupled with a laser induced fluorescence (LIF) system. The measurement was conducted with atmospherically relevant HO₂ concentrations (~1×10⁹ molecule/cm³) at 51% RH. The measured γ(HO₂) onto aqueous (NH₄)₂SO₄ aerosol was 0.001 ±0.0007, which was consistent with the relatively low first-order loss rate of HO₂ onto aqueous (NH₄)₂SO₄ aerosol. The γ(HO₂) was elevated with increase of Cu(Ⅱ) concentrations in aqueous (NH₄)₂SO₄ aerosol. The threshold of Cu(Ⅱ) concentration was 10^-3 mol/L for the dramatic increase of γ(HO₂). It was found that γ(HO₂) reached 0.1 when Cu(Ⅱ) concentration in aerosol was larger than 10^-3 mol/L, suggesting that γ(HO₂) is very sensitive to concentration of transition metal ions in aerosol.
- Heterogeneous reaction,
- HO₂ uptake coefficient,
- Aerosol flow tube,
- Laser induced fluorescence,
- Transition metal ion
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Measurements of HO₂ uptake coefficient on aqueous (NH₄)₂SO₄ aerosol using aerosol flow tube with LIF system