Citation: Song Tingting, Zhao Hongyu, Hu Yu, Sun Nannan, Zhang Haijiao. Facile assembly of mesoporous silica nanoparticles with hierarchical pore structure for CO₂ capture[J]. Chinese Chemical Letters, ;2019, 30(12): 2347-2350. doi: 10.1016/j.cclet.2019.07.024 shu

Facile assembly of mesoporous silica nanoparticles with hierarchical pore structure for CO₂ capture

Song Tingting ^a ,
Zhao Hongyu ^a,b ,
Hu Yu ^a ,
Sun Nannan ^b ,
Zhang Haijiao ^a,*,

a.
Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai 200444, China
b.
CAS Key Lab of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, China

hjzhang128@shu.edu.cn

Received Date: 30 April 2019
Revised Date: 5 July 2019
Accepted Date: 10 July 2019
Available Online: 11 December 2019

Figures(4)

In the work, we propose an efficient one-pot approach for synthesis of a new type of mesoporous silica nanoparticles (MSNs). That can be successfully realized by using tetraethylorthosilicate (TEOS) and N-[3-(trimethoxysilyl)propyl]ethylenediamine (TSD) as the silica precursors and cetyltrimethylammonium bromide (CTAB) as the structure-directing agent through a facile assembly process. The as-synthesized MSNs possess a spherical morphology with about 230 nm, a relatively high surface area of 133 m²/g, and a hierarchical pore size distribution. When applied as the sorbents, the amine-functioned MSNs demonstrate the enhanced adsorption capacity for CO₂ capture (at 1 bar, 15 vol% CO₂, up to 80.5 mg/g at 75℃), high selectivity, and good cycling durability, benefiting from the suitable modification of polyethyleneimine.
- Mesoporous silica nanoparticles,
- Hierarchical pore structure,
- Self-assembly,
- Amine-functionization,
- Adsorption
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沈阳化工大学材料科学与工程学院沈阳 110142

Facile assembly of mesoporous silica nanoparticles with hierarchical pore structure for CO2 capture

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通讯作者: 陈斌, bchen63@163.com

Facile assembly of mesoporous silica nanoparticles with hierarchical pore structure for CO₂ capture