Citation: Song Zhaoxia, Liu Wei, Wei Xiaofei, Zhou Quan, Liu Hongda, Zhang Zheng, Liu Guichang, Zhao Zhongfu. Charge storage mechanism of copper hexacyanoferrate nanocubes for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(5): 1213-1216. doi: 10.1016/j.cclet.2019.07.022 shu

Charge storage mechanism of copper hexacyanoferrate nanocubes for supercapacitors

Song Zhaoxia ^a ,
Liu Wei ^b,*, ,
Wei Xiaofei ^a ,
Zhou Quan ^a ,
Liu Hongda ^b ,
Zhang Zheng ^b ,
Liu Guichang ^b ,
Zhao Zhongfu ^b,*,

a.
Department of Chemical Engineering, College of Life Science, Dalian Minzu University, Dalian 116600, China
b.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

liuwei08@dlut.edu.cn

zfzhao@dlut.edu.cn

Received Date: 12 June 2019
Revised Date: 6 July 2019
Accepted Date: 9 July 2019
Available Online: 9 July 2019

Figures(3)

The widely accepted theory concerning the electrochemical energy storage mechanism of copper hexacyanoferrate (CuHCF) for supercapacitors is that CuHCF stores charge by the reversible redox processes of Fe³⁺/Fe²⁺ couple and Cu cations are electrochemically inactive. In this work, CuHCF nanocubes (CuHCF-NC) were synthesized in the presence of potassium citrate and its electrochemical properties were tentatively studied in 1 mol/L Na₂SO₄ aqueous electrolyte. Good supercapacitive performance was exhibited. The combined analyses of cyclic voltammogram (CV) and X-ray photoelectron spectroscopy (XPS) disclosed that the CuHCF nanocubes underwent the redox reactions of Fe³⁺/Fe²⁺ and Cu²⁺/Cu⁺ couples to store charges. The Cu²⁺/Cu⁺ redox couple was activated due to the strong coordination interaction between the carboxylate groups of citrate ions and surface Cu cations.
- Copper hexacyanoferrate,
- Supercapacitor,
- Electrode material,
- Charge storage mechanism,
- Redox couple
1. [1]
  [1] Y. Xu, S. Zheng, H. Tang, et al., Energy Storage Mater. 9 (2017) 11-30. doi: 10.1016/j.ensm.2017.06.002
2. [2]
  Y. Xu, Q. Li, H. Xue, H. Pang, Coord. Chem. Rev. 376 (2018) 292-318. doi: 10.1016/j.ccr.2018.08.010
3. [3]
  Y. Yan, B. Li, W. Guo, H. Pang, H. Xue, J. Power Sources 329 (2016) 148-169. doi: 10.1016/j.jpowsour.2016.08.039
4. [4]
  B. Li, P. Gu, Y. Feng, et al., Adv. Funct. Mater. 27 (2017) 1605784.
5. [5]
  L. Yao, T. Cheng, X. Shen, et al., Chin. Chem. Lett. 29 (2018) 587-591. doi: 10.1016/j.cclet.2018.01.007
6. [6]
  A. Lisowska-Oleksiak, A.P. Nowak, J. Power Sources 173 (2007) 829-836. doi: 10.1016/j.jpowsour.2007.05.046
7. [7]
  J. Chen, K. Huang, S. Liu, Electrochem. commun. 10 (2008) 1851-1855. doi: 10.1016/j.elecom.2008.07.046
8. [8]
  L. Zhou, M. Zhang, Y. Wang, et al., Electrochim. Acta 232 (2017) 106-113. doi: 10.1016/j.electacta.2017.02.096
9. [9]
  K. Lu, D. Li, X. Gao, et al., J. Mater. Chem. A 3 (2015) 16013-16019. doi: 10.1039/C5TA04244E
10. [10]
  H. Pang, Y. Zhang, T. Cheng, W.Y. Lai, W. Huang, Nanoscale 7 (2015) 16012-16019. doi: 10.1039/C5NR04322K
11. [11]
  Y. Wang, H. Zhong, L. Hu, et al., J. Mater. Chem. A 1 (2013) 2621-2630. doi: 10.1039/c2ta01354a
12. [12]
  H. Jiang, Y.T. Xu, T. Wang, et al., Electrochim. Acta 166 (2015) 157-162. doi: 10.1016/j.electacta.2015.03.089
13. [13]
  K. Krishnamoorthy, P. Pazhamalai, S. Sahoo, et al., Chem. Electro. Chem. 4 (2017) 1-8.
14. [14]
  F. Zhao, Y. Wang, X. Xu, et al., ACS Appl. Mater. Interfaces6 (2014) 11007-11012. doi: 10.1021/am503375h
15. [15]
  K. Lu, B. Song, X. Gao, et al., J. Power Sources 303 (2016) 347-353. doi: 10.1016/j.jpowsour.2015.11.031
16. [16]
  N.K.A. Venugopal, J. Joseph, J. Power Sources 305 (2016) 249-258. doi: 10.1016/j.jpowsour.2015.11.088
17. [17]
  A.A. Ensafi, N. Ahmadi, B. Rezaei, RSC Adv. 5 (2015) 91448-91456. doi: 10.1039/C5RA17945A
18. [18]
  Y. Zou, Q. Wang, C. Xiang, et al., Electrochim. Acta 188 (2016) 126-134. doi: 10.1016/j.electacta.2015.11.123
19. [19]
  P. Díaz, Z. González, R. Santamaría, et al., Electrochim. Acta 212 (2016) 848-855. doi: 10.1016/j.electacta.2016.07.057
20. [20]
  D. Zhang, J. Zhang, Z. Yang, et al., Chem. Commun. 53 (2017) 10556-10559. doi: 10.1039/C7CC04914E
21. [21]
  X. Ma, X. Du, X. Li, et al., J. Alloys. Compd. 695 (2017) 294-301. doi: 10.1016/j.jallcom.2016.10.206
22. [22]
  Y. Yang, Y. Hao, X. Wang, et al., Electrochim. Acta 167 (2015) 364-371. doi: 10.1016/j.electacta.2015.03.174
23. [23]
  M. Sookhakian, W.J. Basirun, M.A.M. Teridi, et al., Electrochim. Acta 230 (2017) 316-323. doi: 10.1016/j.electacta.2017.02.022
24. [24]
  Y. Yang, Y. Hao, J. yuan, L. Niu, F. Xia, Carbon 84 (2015) 174-184. doi: 10.1016/j.carbon.2014.12.005
25. [25]
  J.G. Wang, Z. Zhang, X. Liu, B. Wei, Electrochim. Acta 235 (2017) 114-121. doi: 10.1016/j.electacta.2017.03.094
26. [26]
  X. Zhang, L. Tao, P. He, et al., Electrochim. Acta 259 (2018) 793-802. doi: 10.1016/j.electacta.2017.11.007
27. [27]
  L. Niu, L. Chen, J. Zhang, P. Jiang, Z. Liu, J. Power Sources 380 (2018) 135-141. doi: 10.1016/j.jpowsour.2018.01.083
28. [28]
  S.T. Senthilkumar, J. Kim, Y. Wang, H. Huang, Y. Kim, J. Mater. Chem. A 4 (2016) 4934-4940. doi: 10.1039/C6TA00093B
29. [29]
  P. Pazhamalai, K. Krishnamoorthy, S. Sahoo, S.J. Kim, J. Alloys. Compd. 765 (2018) 1041-1048. doi: 10.1016/j.jallcom.2018.06.249
30. [30]
  H. Yao, F. Zhang, G. Zhang, Y. Yang, Electrochim. Acta 294 (2019) 286-296. doi: 10.1016/j.electacta.2018.10.056
31. [31]
  M.S. Wu, L.J. Lyu, J.H. Syu, J. Power Sources 297 (2015) 75-82. doi: 10.1016/j.jpowsour.2015.07.101
32. [32]
  J. Li, H. Li, J. Li, et al., J. Power Sources 386 (2018) 96-105. doi: 10.1016/j.jpowsour.2018.03.046
33. [33]
  E. Targholi, M.S. Rahmanifar, S.M. Mousavi-Khoshdel, Appl. Organomet. Chem. 32 (2018) e4615. doi: 10.1002/aoc.4615
34. [34]
  H. Draouil, L. Alvarez, J. Causse, et al., New J. Chem. 41 (2017) 7705-7713. doi: 10.1039/C7NJ00879A
35. [35]
  J.G. Wang, Z. Zhang, X. Zhang, et al., Nano Energy 39 (2017) 647-653. doi: 10.1016/j.nanoen.2017.07.055
36. [36]
  K. Siuzdak, M. Szkoda, J. Karczewski, J. Ryl, A. Lisowska-Oleksiak, RSC Adv. 6 (2016) 76246-76250. doi: 10.1039/C6RA15113B
37. [37]
  P. Xiong, G. Zeng, L. Zeng, M. Wei, Dalton Trans. 44 (2015) 16746-16751. doi: 10.1039/C5DT03030G
38. [38]
  K.J. Westin, Å.C. Rasmuson, Desalination 159 (2003) 107-118. doi: 10.1016/S0011-9164(03)90063-4
39. [39]
  X. Wu, J.J. Hong, W. Shin, et al., Nat. Energy 4 (2019) 123-130. doi: 10.1038/s41560-018-0309-7
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